Impact of Geometric and Petrographic Characteristics on the Variability of LA Test Values for Railway Ballast

The Los Angeles test is one of the few mechanical test methods that provides information on the quality of railway ballast. However, the Los Angeles value is subject to large variability. Since important economic decisions depend on this value, the reasons for its variability are investigated. An extensive series of tests using four types of rock as well as an in-depth analysis of particle geometry and petrography are carried out. The impact of particle characteristics on the test results is investigated. The deviation of the petrographic composition within a given sample turns out to have a considerable impact on the Los Angeles test results, whereas the influence of the respective deviation of particle geometry is relatively small. The latter effect only comes into play in connection with petrographically homogeneous rock types. The distribution of the geometric features is similar in almost all of the rock types investigated. Due to the large deviation in particle shape and angularity, the sample mass of 10 kg (as provided in the standards EN 1097-2 and EN 13450) is not found to be representative. The necessary number of test repetitions in order to exclude the effect of deviation of particle geometry is estimated. The one result parameter according to the standard, the Los Angeles value, does not allow for discriminating between the amount of abrasion and the fragmentation occurring during the test. An additional result parameter for the estimation of the fragmentation rate is therefore proposed.     

Glacial lake depth and volume estimation based on a large bathymetric dataset from the Cordillera Blanca,Peru

Glacial lakes are most often located in remote places making it difficult to carry out detailed bathymetric surveys. Consequently, lake depths and volumes for unmeasured lakes are often estimated using empirical relationships developed mainly from small bathymetric datasets. In this study, we use the bathymetry dataset of the Cordillera Blanca, Peru comprising 121 detailed lake bathymetries, the most extensive dataset in the world. We assess the performance of the most commonly applied empirical relationships for lake mean depth and volume estimation, but also investigate relationships between different geometric lake variables. We find that lake volume estimation performs better when derived from lake mean depth, which in turn is estimated from lake width. The findings also reveal the extreme variability of lake geometry, which depends on glacio-geomorphological processes that empirical–statistical relationships cannot adequately represent. Such relationships involve characteristic uncertainty ranges of roughly ±50%. We also estimate potential peak discharges of outburst floods from these lakes by applying empirical relationships from the literature, which results in discharges varying by up to one-order of magnitude. Finally, the results are applied to the 860 lakes without bathymetric measurements from the inventory dataset of the Cordillera Blanca to estimate lake mean depth, volume and possible peak discharge for all unmeasured lakes. Estimations show that ca. 70% (610) of the lakes have a mean depth lower than 10 m and very few longer than 40 m. Lake volume of unmeasured lakes represent ca. 32% (5.18 × 10⁸ m³) of the total lake volume (1.15 × 10⁹ m³) in the Cordillera Blanca. Approximately, 50% of the lakes have potential peak discharges > 1000 m³/s in case of lake outburst floods, implying a need for additional studies for risk assessment. © 2020 John Wiley & Sons, Ltd.     

Petrographie und Diagenese des Stubensandsteines (mittlerer Keuper) aus Tiefbohrungen im Raum Memmingen (Bayern)

The “Stubensandstein” (Middle Keuper) of the Memmingen region (Southern Germany) — the detrital deposit of a nearby granitic red-soil area — was investigated sedimentologically, on the basis of three cores from 2,230, 1,930 and 1,420 metres depth. Shale- and marl-layers are intercalated in beds of coarse grained, immature sandstone. The rare carbonate is predominantly early diagenetic dolomite. The most exceptional result of the diagenesis is the formation of a variously composed claymineral association in the porous sandstones: Kaolinite, sudoite, sudoite/montmorillonitemixed-layers and tosudite (a regular 1∶1 sudoite/montm.-mixed-layer). The detrital component of the clay-minerals (illite and illite/montm.-mixed-layers) is preserved more or less unchanged in the shales, marls and argillaceous sandstones. Two main diagenetic phases can be distinguished:

1. The early diagenetic formation of kaolinite out of the solution-products of feldspars in acid environment. Quartz is precipitated in microcrystalline form in the pore space, garnet is partly dissolved.
2. In the course of the Neogen deep burial stage kaolinite becomes unstable and sudoite and sudoite/montm. are newformed; the intensity of this phenomenon depends on depth of burial and rock-permeability. Calcite sporadically crystallizes out of an environment that has become alkaline; adjacent feldspar becomes more or less dissolved and is pseudomorphically replaced by calcite. Al(OH)₃ is thereby released and is fixed in montmorillonite, thus forming the sudoite of the carbonatic horizons, which never contain kaolinite.

     

A new approach to interpreting Rock-Eval S2 and TOC data for kerogen quality assessment

A simple method for application in source potential mapping is used to assess the original oil and gas potentials in source rock horizons based upon Rock-Eval potential (S₂) and total organic carbon (TOC) values. The method assumes that kerogens consist of mixtures of end-members with assigned hydrogen index values. Based on suggested algorithms, the average amounts of oil-prone, gas-prone and inert organic material over source rock intervals are determined in TOC units. The method uses regression lines from plots of remaining hydrocarbon potentials (S₂) versus total organic carbon (TOC), and “quick-look” transparent overlays are used to read the appropriate kerogen mixture.Mineral matrix effects during pyrolysis, when strong, can cause erroneous results. This effect which occurs for oil-prone kerogens and adsorptive minerals can cause problems particularly for lean samples (S₂ = 0–3 mg HC/g rock) whilst the errors for richer samples are less.The method is applied on three sections of Upper Jurassic organic-rich rocks from the Danish North Sea sector, which are at different maturity stages. One of these sections is dominated by gas-prone material, one is dominated by oil-prone material and the third section contains a mixture of oil- and gas-prone material.The method has been compared with other methods that split kerogens in oil and gas generating potential and has given reasonable results.Experience using the method and a presented example suggest that sedimentological, system tract information may be derived from S₂ to TOC cross-plots. A constructed modelling example suggests that the end-member concept used in this approach may be used in forward type source rock prediction models when combined with sedimentological models. The resulting S₂–TOC plots can be used in order to check the forward modelling results against observed values.     

Syndeformational recrystallization – dynamic or compositionally induced?

Dynamic recrystallization in the strict sense of the term is the reconstitution of crystalline material without a change in chemical composition, driven by strain energy in the form of dislocations. Driving potentials additional to internal strain energy may contribute to the recrystallization of naturally deformed minerals, which form solid solutions such as feldspar, amphiboles and pyroxenes, if they change their composition during recrystallization. To estimate the relative importance of these driving potentials, the chemical composition of porphyroclasts and recrystallized grains of plagioclase, clinopyroxene and hornblende have been investigated in samples from a high grade shear zone of the Ivrea Zone, Italy. The plagioclases show two different recrystallization microstructures: bulging recrystallization at grain boundaries and discrete zones of recrystallized grains across porphyroclasts probably involving fracturing. Deformation took place under amphibolite facies conditions on a retrograde P,T-path. Porphyroclast and recrystallized compositions from bulging recrystallization microstructures differ only in their Or-content and yield a ΔG between mean host grain and mean recrystallized grain composition at fixed P,T-conditions of approximately 5 Joules/10⁻⁴ m³. Extreme compositional variations yield approximately 60 J/10⁻⁴m³. The increase of free energy due to dislocations calculated for common glide systems in plagioclase are on the order of 100 Joules/10⁻⁴m³ for high values of dislocation densities of 10¹⁴m⁻². Thus, the effect of chemically induced driving energies on grain boundary velocity appears small for mean compositions but may be as great as that of deformational energies for larger chemical differences. In the other type of microstructure, porphyroclasts and recrystallized grains in discrete zones differ in their anorthite content. The maximum ΔG induced by the compositional disequilibrium is on the order of 100 J/10⁻⁴m³. This maximum value is of the same magnitude as the ΔG derived from high dislocation densities of 10¹⁴ m⁻². The resulting combined ΔG is approximately twice as high as for deformational ΔG alone, and heterogeneous nucleation may become a feasible recrystallization mechanism which is evident from the microstructures. The recrystallization mechanism depends on the nature of the driving potential. Grain boundary migration (GBM) and heterogeneous nucleation can release Gibbs free energy induced by compositional disequilibrium, whereas this is not likely for subgrain rotation. Therefore, only GBM and heterogeneous nucleation may link metamorphism and deformation, so that syndeformational recrystallization may represent a transitional process ranging from dynamic recrystallization to metamorphic reaction. Received: 8 July 1996 / Accepted: 17 November 1997     

Zur Geologie und Mineralogie der Kalk- und Gipskrusten Algeriens

Caliches: Large areas of the northern Sahara and the Algerian High Planes are covered by mostly 1–5 m thick caliches. Their age (Pliocene in the Sahara) decreases to the north and their precipitation is generally independent of groundwater. Their profile is composed (from top to base) as follows:

Upper soil, loose and mostly of eolian origin.

Upper part of caliche, with very characteristic, dense, partly layered-knobby texture, formed slowly by solutional and reprecipitational processes of ± freely outcropping caliches under addition of eolian material.

Under part of caliche, highly porous, somewhat chalky and greyish-white; precipitated mainly by capillar rise of solutions in permeable and calcareous rocks.

Substratum, preferentially calcareous sandstones, alluvial deposits and marls.

The mineralogy of the caliches (whose main components are represented in fig. 4 A-C) is rather monotonous: in addition to relicts of the substratum (partly dissolved or pushed aside by precipitation of calcite), there are only newly formed low-Mg-calcite and some quarzine (length-slow quartz). Sr-contents of calcite rise clearly from substratum to upper part of caliche. Gypsiferous Crusts (or Cementations): They are found mainly in the surroundings of Chotts (flat, ± saline lakes) and in oases of the NE-Algerian Sahara. Their formation began — mostly caused climatically — after the period of caliche formation and is still continuing in some places. Most of these gypsum-crusts are formed by evaporation of near-surface groundwaters in sandy soils. Water saturated in gypsum precipitates large crystals of gypsum (relatively low in Sr), partly filled by sand, at groundwater-surface. Fine crystalline crusts (relatively high in Sr) are formed by ascendent waters with lower gypsum content ± directly under the landsurface.