Deposition rates of polysilicic acid with up to 10 M calcium ions

Cementitious materials used for radioactive waste repository construction complicate the performance assessment of radioactive waste systems because the use of cement may greatly alter the pH (8–13) of groundwater and release constituents such as calcium ions. Under such conditions, it is important to clarify also the dynamic behavior of silica (silicic acid), in order to evaluate the alteration in the chemical and physical properties of the fractured layer or the host rock surrounding the repository. Since silica undergoes polymerization, precipitation or dissolution depending on the pH and/or temperature, the behavior of silica would be greatly complicated in the presence of other ions. This study is focused on the deposition rates of polysilicic acid and soluble silicic acid with up to 10⁻³ M Ca ions. In the experiment, Na₂SiO₃ solution (250 mL, pH > 10, 298 K) was poured into a polyethylene vessel containing amorphous silica powder (0.5 g), and a buffer solution, HNO₃, and CaNO₃ as Ca ions were sequentially added into the vessel. The pH of the solution was set to 8. The silica, initially in a soluble form at pH > 10 (1.4 × 10⁻² M), became supersaturated and either deposited on the solid surface or changed into the polymeric form. Then the concentrations of both poly- and soluble silicic acid were monitored over a 40-day period. The decrease of polysilicic acid became slow with an increase in the concentration of Ca ions in the range of up to 10⁻³ M. In general, the addition of electrolytes to a supersaturated solution accelerates the aggregation and precipitation of polymeric species. However, the experimental result showed that polysilicic acid in the presence of Ca ions is apparently stable in solution, compared with that under a Ca-free condition. On the other hand, the concentration of soluble silicic acid in the presence of Ca ions immediately became metastable, that is, slightly higher than the solubility of soluble silicic acid. Its dynamic behavior was similar to that in the Ca-free condition.     

Geochemical Process of Gas Hydrate Formation in the Nankai Trough Based on Chloride and Isotopic Anomalies in Interstitial Water

Abstract: Interstitial water expelled from gas hydrate-bearing and -free sediments in the Nankai Trough are analyzed in terms of Cl-, SO₄²-, δ¹⁸O and δD. The baselines for the Cl- concentration and δ¹⁸O value are close to seawater values (530 mM and 0%), indicating that the interstitial water is of seawater origin. The δD values decrease with depth, implying isotopic exchange of hydrogen between upwelling biogenic methane depleted in D and interstitial water. The Cl- concentrations in gas hydrate-bearing sediments are anomalously low, while the δ¹⁸O and δD values are both high, suggesting that the water forming these gas hydrates was poor in Cl- and enriched in ¹⁸O and D during gas hydrate formation. Calculation of the gas hydrate saturations using Cl "and δ¹⁸O anomalies gives results of up to 80 % in sand, and shows that the δ¹⁸O baseline is not consistent with the Cl" baseline. The δ¹⁸O baseline increases by +1% in gas hydrate-free clay and silt. This is considered to be caused by clustering of water molecules after gas hydrate dissociation in response to the upward migration of the base of gas hydrate stability, as indicated by the presence of a double bottom-simulating reflector at this site. The water clusters enriched in ¹⁸O are responsible for the increase in the δ¹⁸O baseline with normal Cl". The abrupt shallowing of the base of gas hydrate stability may induce the dissociation of gas hydrates and the accumulation of gases in the new stability zone, representing a geological process that increases gas hydrate saturation.     

Geochemical Features of Vein Anhydrite from the Kakkonda Geothermal System, Northeast Japan

Abstract. Cathodoluminescence (CL) color, rare earth element (REE) content, sulfur and oxygen isotopes and fluid inclusions of anhydrite, which frequently filled in hydrothermal veins in the Kakkonda geothermal system, were investigated to elucidate the spatial, temporal and genetical evolution of fluids in the deep reservoir. The anhydrite samples studied are classified into four types based on CL colors and REE contents: type-N (no color), type-G (green color), type-T (tan color) and type-S (tan color with a high REE content). In the shallow reservoir, only type-N anhydrite is observed. In the deep reservoir, type-G anhydrite occurs in vertical veins whereas type-T and -N in lateral veins. Type-S anhydrite occurs in the heat-source Kakkonda Granite. The CL textures revealed that type-G anhydrite deposited earlier than type-T in the deep reservoir, implying that fracture system was changed from predominantly vertical to lateral.
Studies of fluid inclusions and δ³⁴S and δ¹⁸O values of the samples indicate that type-N anhydrite deposited from diluted fluids derived from meteoric water, whereas type-G, -T and -S anhydrites deposited from magmatic brines derived from the Kakkonda Granite with the exception of some of type-G with recrystallization texture and no primary fluid inclusion, which deposited from fossil seawater preserved in the sedimentary rocks. Type-G, -T and -S anhydrites exhibit remarkably different chondrite-normalized REE patterns with a positive Eu anomaly, with a convex shape (peak at Sm or Eu) and with a negative Eu anomaly, respectively. The difference in the patterns might result from the different extent of hydrothermal alteration of the reservoir rocks and contribution of the magmatic fluids.     

Developing a hybrid multi‐model for peak flood forecasting

The present study aims to develop a hybrid multi‐model using the soft computing approach. The model is a combination of a fuzzy logic, artificial neural network (ANN) and genetic algorithm (GA). While neural networks are low‐level computational structures that perform well dealing with raw data, fuzzy logic deal with reasoning on a higher level by using linguistic information acquired from domain experts. However, fuzzy systems lack the ability to learn and cannot adjust themselves to a new environment. Moreover, experts occasionally make mistakes and thus some rules used in a system may be false. A network type structure of the present hybrid model is a multi‐layer feed‐forward network, the main part is a fuzzy system based on the first‐order Sugeno fuzzy model with a fuzzification and a defuzzification processes. The consequent parameters are determined by least square method. The back‐propagation is applied to adjust weights of network. Then, the antecedent parameters of the membership function are updated accordingly by the gradient descent method. The GA was applied to select the fuzzy rule. The hybrid multi‐model was used to forecast the flood level at Chiang Mai (under the big flood 2005) and the Koriyama flood (2003) in Japan. The forecasting results are evaluated using standard global goodness of fit statistic, efficient index (EI), the root mean square error (RMSE) and the peak flood error. Moreover, the results are compared to the results of a neuro‐genetic model (NGO) and ANFIS model using the same input and output variables. It was found that the hybrid multi‐model can be used successfully with an efficiency index (EI) more than 0·95 (for Chiang Mai flood up to 12 h ahead forecasting) and more than 0·90 (for Koriyama flood up to 8 h ahead forecasting). In general, all of three models can predict the water level with satisfactory results. However, the hybrid model gave the best flood peak estimation among the three models. Therefore, the use of fuzzy rule base, which is selected by GA in the hybrid multi‐model helps to improve the accuracy of flood peak. Copyright © 2009 John Wiley & Sons, Ltd.     

Spatial periodicity of galaxy number counts, CMB anisotropy, and SNIa Hubble diagram based on the universe accompanied by a non-minimally coupled scalar field

We have succeeded in establishing a cosmological model with a non-minimally coupled scalar field φ that can account not only for the spatial periodicity or the picket-fence structure exhibited by the galaxy N-z relation of the 2dF survey but also for the spatial power spectrum of the cosmic microwave background radiation (CMB) temperature anisotropy observed by the WMAP satellite. The Hubble diagram of our model also compares well with the observation of Type Ia supernovae. The scalar field of our model universe starts from an extremely small value at around the nucleosynthesis epoch, remains in that state for sufficiently long periods, allowing sufficient time for the CMB temperature anisotropy to form, and then starts to grow in magnitude at the redshift z of ～1, followed by a damping oscillation which is required to reproduce the observed picket-fence structure of the N-z relation. To realize such behavior of the scalar field, we have found it necessary to introduce a new form of potential V(φ)∝ φ ²exp?(?q φ ²), with q being a constant. Through this parameter q, we can control the epoch at which the scalar field starts growing.     

Validation of a new generation system for bottom boundary layer beneath solitary wave

Understanding of sea bottom boundary layer characteristics, especially bottom shear stress acting on the sea bed, is an important step needed in sediment transport modeling for practical application purposes. In the present study, a new generation system for bottom boundary layer under solitary wave is proposed. Applicability of this system is examined by comparing measured and numerical solution velocities. Moreover, transitional behavior from laminar to turbulence was investigated. It is concluded that the critical Reynolds number in the experiments shows good agreement with DNS result of Vittori and Blondeaux (2008) and laboratory data of Sumer et al. (2010), indicating validity of the generation system. Since the present generation system enables continuous measurement to obtain ensemble averaged quantities, it can be effectively utilized for future experimental studies on solitary wave boundary layers, including sediment transport experiments with movable bed.     

Estimation of inner-core rotation rate by using the Earth’s free oscillation

We estimate a rate of inner-core differential rotation from time variations of splitting functions of seven core modes of the Earth’s free oscillations excited by eight large earthquakes in a period of 1994–2003. The splitting functions and moment tensor elements are simultaneously determined for each core mode by a spectral fitting technique. The estimated moment tensor well agrees with Harvard CMT solution. The splitting functions are corrected for the effect of mantle heterogeneity using a 3D mantle velocity model. Inner-core rotation angle about the Earth’s spin axis is determined for each core mode as a function of event year by comparison of the corrected and reference splitting functions. Mean rotation rate of six core modes is estimated at 0.03±0.18° per year westward, and this value is insignificantly different from zero. Therefore, the inner core is not rotating at a significant rate relatively to the crust and mantle.     

Evolution of West Rota Volcano, an extinct submarine volcano in the southern Mariana Arc: Evidence from sea floor morphology, remotely operated vehicle observations and 40Ar–39Ar geochronological studies

Abstract West Rota Volcano (WRV) is a recently discovered extinct submarine volcano in the southern Mariana Arc. It is large (25 km diameter base), shallow (up to 300 m below sealevel), and contains a large caldera (6 × 10 km, with up to 1 km relief). The WRV lies near the northern termination of a major NNE‐trending normal fault. This and a second, parallel fault just west of the volcano separate uplifted, thick frontal arc crust to the east from subsiding, thin back‐arc basin crust to the west. The WRV is distinct from other Mariana Arc volcanoes: (i) it consists of a lower, predominantly andesite section overlain by a bimodal rhyolite‐basalt layered sequence; (ii) andesitic rocks are locally intensely altered and mineralized; (iii) it has a large caldera; and (iv) WRV is built on a major fault. Submarine felsic calderas are common in the Izu and Kermadec Arcs but are otherwise unknown from the Marianas and other primitive, intraoceanic arcs. ⁴⁰Ar–³⁹Ar dating indicates that andesitic volcanism comprising the lower volcanic section occurred 0.33–0.55 my ago, whereas eruption of the upper rhyolites and basalts occurred 37–51 thousand years ago. Four sequences of rhyolite pyroclastics each are 20–75 m thick, unwelded and show reverse grading, indicating submarine eruption. The youngest unit consists of 1–2 m diameter spheroids of rhyolite pumice, interpreted as magmatic balloons, formed by relatively quiet effusion and inflation of rhyolite into the overlying seawater. Geochemical studies indicate that felsic magmas were generated by anatexis of amphibolite‐facies meta‐andesites, perhaps in the middle arc crust. The presence of a large felsic volcano and caldera in the southern Marianas might indicate interaction of large normal faults with a mid‐crustal magma body at depth, providing a way for viscous felsic melts to reach the surface.