Laboratory Study of O(1S) Formation Process in the Photolysis of O3 and its Atmospheric Implications

A high-sensitive technique to detect O(¹S) atoms using vacuum ultraviolet laser-induced fluorescence (VUV-LIF) spectroscopy has been applied to study the O(¹S) production process from the UV photodissociation of O₃, N₂O, and H₂O₂. The quantum yields for O(¹S) formation from O₃ photolysis at 215 and 220 nm are determined to be (1.4 ± 0.4) × 10⁻⁴ and (5 ± 3) × 10⁻⁵, respectively. Based on thermochemical considerations, the O(¹S) formation from O₃ photolysis at 215 and 220 nm is attributed to a spin-forbidden process of O(¹S)+O₂(X³Σ_g ⁻). Analysis of the Doppler profile of O(¹S) produced from O₃ photolysis at 193 nm also indicates that the O(¹S) atoms are produced from the spin-forbidden process. In the photolysis of N₂O and H₂O₂ at 193 nm, no discernible signal of O(¹S) atoms has been detected. The upper limit values of the quantum yields for O(¹S) production from N₂O and H₂O₂ photolysis at 193 nm are estimated to be 8 × 10⁻⁵ and 3 × 10⁻⁵, respectively. Using the experimental results, the impact of the O(¹S) formation from O₃ photolysis on the atmospheric OH radical formation through the reaction of O(¹S)+H₂O has been estimated. The calculated results show that the contribution of the O(¹S)+H₂O reaction to the OH production rate is ∼2% of that of the O(¹D)+H₂O reaction at 30 km altitude in mid-latitude. Implications of the present laboratory experimental results for the terrestrial airglow of O(¹S) at 557.7 nm have also been discussed.     

Analysis of suspended sediment yields after low impact forest harvesting

Disturbances to forest catchments have profound effects on the environment of headwater streams and have an impact on suspended sediment (SS) management. Forest harvesting is a dominant factor in increasing SS yields. Road construction, skidder activity and ploughing associated with harvesting cause serious soil disturbance that results in SS increases. However, few studies have shown whether harvesting itself increases SS yields. This study examined how harvesting influenced SS yields in a steep forested area. During harvesting, soil surface disturbance was prevented as much as possible by using skyline logging treatments and piling branches and leaves at selected locations in the watershed. Using these methods, the representative SS rating curve did not change significantly after harvesting. The results also show that the characteristics of SS transport were related to the SS source area, and reveal that the riparian zone/stream bank was a dominant SS source area at the study site. Annual SS yields did not increase despite increasing annual water yields after harvesting. The limited water capacity of the soil at the study site likely led to only slight differences in pre‐ and post‐harvest water discharge from heavy rainfall events. Most SS was transported during heavy rainfall events, and increases in SS yields were not detected after harvesting. We concluded that it is possible to prevent post‐harvest SS increases by performing careful, low‐impact harvesting procedures. Copyright © 2007 John Wiley & Sons, Ltd.     

Accretion process of the moon

Recent geochemical and geophysical data suggest that the initial temperature of the Moon was strongly peaked toward the lunar surface. To explain such an initial temperature distribution, a simple model of accretion process of the Moon is presented. The model assumes that the Moon was formed from the accumulation of the solid particles or gases in the isolated, closed cloud. Two equations are derived to calculate the accretion rate and surface temperature of the accreting Moon. Numerical calculations are made for a wide range of the parameters particle concentration and particle velocity in the cloud. A limited set of the parameters gives the initial temperature profiles as required by geochemical and geophysical data. These models of the proto-moon cloud indicate that the lunar outershell, about 400 km thick, was partially or completely molten just after the accretion of the Moon and that the Moon should have been formed in a period shorter than 1000 yr. If the Moon formed at a position nearer to the Earth than its present one, the Moon might have been formed in a period of less than one year.On leave from Geophysical Institute, University of Tokyo.Contribution No. 2104, Division of Geological and Planetary Sciences, California Institute of Technology.     

Sequentially sampled gas hydrate water,coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano,Lake Baikal: ambiguous deep-rooted source of hydrate-forming water

The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl^– and HCO₃ ^– remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl^– concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO₃ ^– concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO₃ ^–/Cl^– ratio of 305 differed markedly from downcore pore water HCO₃ ^–/Cl^– ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ¹⁸O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ¹⁸O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ¹⁸O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.     

Compound chondrule formation in the shock-wave heating model: Three-dimensional hydrodynamics simulation of the disruption of a partially-molten dust particle

We carried out three-dimensional hydrodynamics simulations of the disruption of a partially-molten dust particle exposed to high-speed gas flow to examine the compound chondrule formation due to mutual collisions between the fragments (fragment-collision model; [Miura, H., Yasuda, S., Nakamoto, T., 2008a. Icarus194, 811-821]).In the shock-wave heating model, which is one of the most plausible models for chondrule formation, the gas friction heats and melts the surface of the cm-sized dust particle (parent particle) and then the strong gas ram pressure causes the disruption of the molten surface layer. The hydrodynamics simulation shows details of the disruptive motion of the molten surface, production of many fragments and their trajectories parting from the parent particle, and mutual collisions among them. In our simulation, we identified 32 isolated fragments extracted from the parent particle. The size distribution of the fragments was similar to that obtained from the aerodynamic experiment in which a liquid layer was attached to a solid core and it was exposed to a gas flow. We detected 12 collisions between the fragments, which may result in the compound chondrule formation. We also analyzed the paths of all the fragments in detail and found the importance of the shadow effect in which a fragment extracted later blocks the gas flow toward a fragment extracted earlier. We examined the collision velocity and impact parameter of each collision and found that 11 collisions should result in coalescence. It means that the ratio of coalescent bodies to single bodies formed in this disruption of a parent particle is R_coa=11/(32-11)=0.52. We concluded that compound chondrule formation can occur just after the disruption of a cm-sized molten dust particle in shock-wave heating.     

Topography of the Moho and Conrad discontinuities in the Kyushu district,Southwest Japan

The first P-arrival time data from local earthquakes are inverted for two-dimensional variation of the depths to the Conrad and Moho discontinuities in the Kyushu district, southwest Japan. At the same time, earthquake hypocenters and station corrections are determined from the data. The depths to the discontinuities are estimated by minimizing the travel time residuals of first P-arrival phases for 608 earthquakes observed at 57 seismic stations. In the land area of Kyushu, the Conrad and Moho discontinuities are located within the depth ranges of 16–18 and 34–40 km, respectively. The Conrad discontinuity is not as largely undulated as the Moho discontinuity. The depth to the Moho is deep along the east coast of Kyushu, and the deepest Moho is closely related to markedly low velocity of P wave. We regard the deepest Moho as reflecting the Kyushu–Palau ridge subducting beneath the Kyushu district, together with the Philippine Sea slab. In western Kyushu, the shallow Moho is spreading in the north–northeast–south–southwest direction in the Okinawa trough region. Based on the presence of low-velocity anomaly in three-dimensional velocity structure and seismogenic stress field of shallow crustal earthquakes, the shallow Moho is interpreted as being due to lower crustal erosion associated with a small-scale mantle upwelling in the Okinawa trough region. The velocity discontinuity undulation basically has insignificant effect on hypocenter determination of the local earthquakes, but the Moho topography makes changes in focal depths of some upper mantle earthquakes. The depth variation of the Moho discontinuity has a good correlation with the Bouguer gravity anomaly map; i.e., the shallow Moho of western Kyushu and the deep Moho of eastern Kyushu closely correlate with the positive and negative Bouguer gravity anomalies, respectively.     

Jovian magnetosphere-ionosphere current system characterized by diurnal variation of ionospheric conductance

We developed a new numerical model of the Jovian magnetosphere-ionosphere coupling current system in order to investigate the effects of diurnal variation of ionospheric conductance. The conductance is determined by ion chemical processes that include the generation of hydrogen and hydrocarbon ions by solar EUV radiation and auroral electrons precipitation. The model solves the torque equations for magnetospheric plasma accelerated by the radial currents flowing along the magnetospheric equator. The conductance and magnetospheric plasma then change the field-aligned currents (FACs) and the intensity of the electric field projected onto the ionosphere. Because of the positive feedback of the ionospheric conductance on the FAC, the FAC is the maximum on the dayside and minimum just before sunrise. The power transferred from the planetary rotation is mainly consumed in the upper atmosphere on the dayside, while it is used for magnetospheric plasma acceleration in other local time (LT) sectors. Further, our simulations show that the magnetospheric plasma density and mass flux affect the temporal variation in the peak FAC density. The enhancement of the solar EUV flux by a factor of 2.4 increases the FAC density by 30%. The maximum density of the FAC is determined not only by the relationship between the precipitating electron flux and ionospheric conductance, but also by the system inertia, i.e., the inertia of the magnetospheric plasma. A theoretical analysis and numerical simulations reveal that the FAC density is in proportion to the planetary angular velocity on the dayside and to the square of the planetary angular velocity on the nightside. When the radial current at the outer boundary is fixed at values above 30 MA, as assumed in previous model studies, the peak FAC density determined at latitude 73°-74° is larger than the diurnal variable component. This result suggests large effects of this assumed radial current at the outer boundary on the system.     

Diverse mineralogical and oxygen isotopic signatures recorded in CV3 carbonaceous chondrites

We describe the petrography and mineralogy of six CV3 carbonaceous chondrites. LAP02206, LAP02228, LAP04843, and GRA06101 are classified as oxidized Allende-like chondrites (CV3_oxA). RBT04143 and QUE97186 are classified as members of the reduced subtype (CV3_red). Chondrules in the CV3_oxA chondrites show extensive Fe–Mg zoning. Fe-rich olivine in the rims of the CV3_oxA chondrules are ¹⁶O-poor relative to Mg-rich olivine in the cores, suggesting that in addition to Fe and Mg, oxygen was exchanged between chondrules and matrix during weak thermal metamorphism. The CV3_red chondrites appear to have formed through various processes. QUE97186 shows chondrule flattening with a preferred orientation, which is interpreted to have resulted from shock impact at a pressure of ～20 GPa. The post-shock residual heat (～1000 °C) is likely to be responsible for the restricted Fe/Mg ratios of matrix olivine. Based on the degree of Fe–Mg homogenization of matrix olivines, we estimate the spatial scale of the shock-heated region to be ～1 m. RBT04143 is a breccia containing many clasts of two types of lithologies: reduced-type material and very weakly altered material.     

Fragment-collision model for compound chondrule formation: Estimation of collision probability

We propose a new scenario for compound chondrule formation named as “fragment-collision model,” in the framework of the shock-wave heating model. A molten cm-sized dust particle (parent) is disrupted in the high-velocity gas flow. The extracted fragments (ejectors) are scattered behind the parent and the mutual collisions between them will occur. We modeled the disruption event by analytic considerations in order to estimate the probability of the mutual collisions assuming that all ejectors have the same radius. In the typical case, the molten thin () layer of the parent surface will be stripped by the gas flow. The stripped layer is divided into about 200 molten ejectors (assuming that the radius of ejectors is 300 μm) and then they are blown away by the gas flow in a short period of time (). The stripped layer is leaving from the parent with the velocity of depending on the viscosity, and we assumed that the extracted ejectors have a random velocity Δv of the same order of magnitude. Using above values, we can estimate the number density of ejectors behind the parent as . These ejectors occupy ∼9% of the space behind the parent in volume. Considering that the collision rate (number of collisions per unit time experienced by an ejector) is given by Rcoll=σcollneΔv, where σcoll is the cross-section of collision [e.g., Gooding, J.K., Keil, K., 1981. Meteoritics 16, 17-43], we obtain by substituting above values. Since most collisions occur within the short duration () before the ejectors are blown away, we obtain the collision probability of Pcoll∼0.36, which is the probability of collisions experienced by an ejector in one disruption event. The estimated collision probability is about one order of magnitude larger than the observed fraction of compound chondrules. In addition, the model predictions are qualitatively consistent with other observational data (oxygen isotopic composition, textural types, and size ratios of constituents). Based on these results, we concluded that this new model can be one of the strongest candidates for the compound chondrule formation. It should be noted that all collisions do not necessarily lead to the compound chondrule formation. The formation efficiency and the future works which should be investigated in the forthcoming paper are also discussed.     

D/H fractionation factors between serpentine and water at 100° to 500°C and 2000 bar water pressure,and the D/H ratios of natural serpentines

D/H fractionation factors between serpentine (clinochrysotile) and water were experimentally determined to be: 1000 In α_ser-w = 2.75 × 10 ⁷/T² ? 7.69 × 10⁴/T + 40.8 in the temperature range from 100 to 500°C. The present results do not support the semi-empirical fractionation factors employed by Wenner and Taylor [1] for the interpretation of δD values of natural serpentines. About 100 serpentines from the Japanese Islands have δD values from ?110 to ?40‰ SMOW, with antigorite being from ?40 to ?60‰. The results are in accord with the two conclusions by Wenner and Taylor [1,2], that is, the presence of a latitude ?δD correlation and the more uniform and higher δD values of antigorite than chrysotile and lizardite.According to the present fractionation factors, almost none of the continental lizardite-chrysotile serpentines could have formed at a temperature below 500°C under equilibrium with fluids of δD values similar to the present-day local meteoric waters. The fluid responsible for oceanic serpentinization could be either a mixture of oceanic and magmatic water or oceanic water alone. However, full interpretation of the δD values of natural serpentines should wait until kinetic behaviors of hydrogen isotopes in serpentinization are better understood.