Victoria Carbonate-Base Metal Gold Deposit and Its Significance in the Mankayan Mineral District, Luzon, Philippines

Abstract. The Victoria gold deposit is a low-sulfidation style epithermal carbonate-base metal gold deposit discovered in 1995 in the Mankayan mineral district, northern Luzon, Philippines. It occurs just south of a high-sulfidation copper-gold orebody (Lepanto enargite deposit) and a porphyry copper-gold orebody (Far Southeast (FSE) deposit). Radiometric dating of the Victoria mineralization yields ages from 1.6 to 1.1 Ma, similar to ages of the Lepanto enargite deposit. Mineralogical, geochemical, fluid inclusion and sulfur isotope studies suggest that the Victoria deposit is not directly related to the late stage of hydrothermal activity that produced the FSE porphyry copper-gold and the Lepanto enargite deposits. The hydrothermal fluids from which Victoria was formed appear to have been derived from the south, and not from the FSE intrusive center to the northeast. This would suggest a regional south to north hydrothermal gradient, consistent with the similar flow within the FSE porphyry-Lepanto enargite system. On a district scale, structures similar to those of the Victoria deposit in trend and nature would be highly prospective, especially if they occur north of identified plutons and volcanic centers.     

Fluctuations of snow accumulation in the Antarctic and sea level pressure in the Southern Hemisphere in the last 100 years

This paper summarizes the long-term fluctuations of snow accumulation in the Antarctic and analyzes its correlation with the sea level pressure (SLP) in the middle latitude (40°–50° S) of the Southern Hemisphere. Stratigraphic data which were compiled from studies on ice cores and snow-pits at eight stations in the Antarctic were used in the present study. It was found that the data concerning fluctuations in snow accumulation for East Antarctica showed correlations, whereas no such correlation was observed for the data from West Antarctica.This study shows possible relationships between snow accumulation in the Antarctic and SLP in the middle latitudes. The fluctuations of accumulation at South Pole, Dome C, Wilkes and South Ice Point show correlations with SLP over a large area in the 40°–50° S latitudinal zone. For the long-term fluctuations of SLP in the 40°–50 ° S latitudinal zone, a zonal fluctuation with wave number zero structure and a longitudinal variation of SLP anomalies due to their out-of-phase-fluctuation between the Pacific and the Indian Oceans were observed. The temporal scales for these fluctuations were found to be in the order of 20–30 years and 40–60 years, respectively. The influences of these two modes on the behaviour of snow accumulation in the Antarctic is also discussed.Now at Kitami Institute of Technology, Kitami, Hokkaido, Japan.     

Radiometric ages of Alpine metamorphic rocks in the western and central Alps

Abstract The chronological characteristics of Alpine metamorphic rocks are described and Alpine metamorphic events are reinterpreted on the basis of chronological data for the western and central Alps from 1960 to 1992. Metamorphic rocks of the Lepontine, Gran San Bernardo, Piemonte, Internal Crystalline Massifs and Sesia-Lanzo mostly date Alpine metamorphic events, but some (along with granitoids and gneisses from the Helvetic and Southern Alps) result from the Variscan, Caledonian or older events and thus predate the Alpine events. Radiometric age data from the Lepontine area show systematic age relations: U-Pb monazite (23-29 Ma), Rb-Sr muscovite (15–40 Ma) and biotite (15–30 Ma), K-Ar biotite (10-30 Ma), muscovite (15–25 Ma) and hornblende (25-35 Ma), and FT zircon (10-20 Ma) and apatite (5-15 Ma), which can be explained by the different closure temperatures of the isotopic systems. A 121 Ma U-Pb zircon age for a coesite-bearing whiteschist (metaquartzite) from the Dora-Maira represents the peak of ultra-high pressure metamorphism. Coesite-free eclogites and blueschists related to ultra-high pressure rocks in the Penninic crystalline massifs yield an ⁴⁰Ar-³⁹Ar plateau age of about 100 Ma for phengites, interpreted as the cooling age. From about 50 Ma, eclogites and glaucophane schists have also been reported from the Piemonte ophiolites and calcschists, suggesting the existence of a second high P/T metamorphic event. Alpine rocks therefore record three major metamorphic events: (i) ultra-high and related high P/T metamorphism in the early Cretaceous, which is well preserved in continental material such as the Sesia-Lanzo and the Penninic Internal Crystalline Massifs; (ii) a second high P/T metamorphic event in the Eocene, which is recognized in the ophiolites and calcschists of the Mesozoic Tethys; and (iii) medium P/T metamorphism, in which both types of high P/T metamorphic rocks were variably reset by Oligocene thermal events. Due to the mixture of minerals formed in the three metamorphic events, there is a possibility that almost all geochronological data reported from the Alpine metamorphic belt show mixed ages. Early Cretaceous subduction of a Tethyan mid-ocean ridge and Eocene continental collision triggered off the exhumation of the high pressure rocks.     

White mica K-Ar ages of blueschist-facies rocks from the Piemonte 'calc-schists' of the western Italian Alps

Abstract Fifty calc-schists have been systematically collected from the Piemonte zone of the western Italian Alps and examined in terms of petrology, X-ray powder diffractometer (XRD) analysis of carbonaceous materials, and K-Ar ages of white mica separates. The petrological study and XRD analysis of carbonaceous materials have shown that calc-schists have suffered blueschist-facies metamorphism in the subduction zone of the convergent margin between the Apulian (African) continental and Tethyan oceanic plates. The metamorphic sequence is divided into three mineral zones based on increasing metamorphic temperature: chlorite (lower than 300°C), chloritoid, and rutile (higher than 450°C). The chlorite zone has dispersed ages of white mica separates, ranging from 115 to 44 Ma, whereas the rutile zone has a comparatively uniform age distribution from 60 to 40 Ma. The chloritoid zone has an intermediate age variation. The large variation in the chlorite zone is attributed to mixing of variable amounts of detrital mica derived from older high temperature metamorphic rocks in the separates, which have not been completely reset during Alpine metamorphism. The uniform age (average ca 50 Ma) in the rutile zone is the cooling age of blueschist-facies calc-schists, which have been episodically exhumed at the collision event of the European and Apulian continents in the Paleocene-Eocene.     

Measuring hydraulic permeability in a streambed using the packer test

Permeability of a streambed is an important factor regulating nutrient and oxygen availability for aquatic biota. In order to investigate the relationship, an accurate permeability should be measured. However, it is difficult to measure permeability in a coarse gravel bed using a conventional permeability test. Moreover, turbulent flow may occur in coarse bed material, and then deviations from Darcy's law do occur. Thus, permeability calculated following Darcy's law may be overestimated under turbulent flow conditions and should be corrected. The packer test can be used in highly permeable gravel beds. We developed a field method applicable to a gravel bed using the packer test and derived an equation adopting a law of turbulent flow to study the problems under any type of flow condition. The accuracy of the equation was examined using a laboratory flume with a gravel bed. The results suggested that permeability calculated from Hvorslev's equation is overestimated for turbulent flow. In contrast, our equation, developed here, could evaluate permeability accurately under any type of flow condition. Copyright © 2005 John Wiley & Sons, Ltd.     

Dating of Dissolved Iodine in Pore Waters from the Gas Hydrate Occurrence Offshore Shimokita Peninsula,Japan: 129I Results from the D/V Chikyu Shakedown Cruise

Iodine concentration and radioisotopic composition (¹²⁹I/I) were measured in the pore waters from the gas hydrate occurrence in the forearc basin offshore Shimokita Peninsula, north-eastern Japan, to determine the source formation of I and accompanying hydrocarbons. Iodine concentrations correlate well with the alkalinity and SO₄ patterns, reflecting degradation stages of I-rich buried organic matter, rapidly increasing in the sulfate reduction interval, and becoming constant below 250 meters below the seafloor with an upwelling flux of 1.5 × 10⁻¹¹ µmol cm⁻² year⁻¹. The ¹²⁹I/I ratios of 300 × 10⁻¹⁵–400 × 10⁻¹⁵ in deep pore waters suggest ages for iodine and hydrocarbon sources as old as 40 Ma. These ages correlate well with the coaly source formations of the Eocene age thought to be responsible for the conventional natural gas deposits underlying the gas hydrate stability zone. Similar profiles are observed in ¹²⁹I/I ratios of pore waters in the gas hydrate stability zone from the forearc basin in the eastern Nankai Trough, offshore central Japan, where pore waters are enriched in I and reach ages as old as ∼50 Ma through the sediment column. At the outer ridge site along the trough, on the other hand, relatively younger I are more frequently delivered probably through thrusts/faults associated with subduction. The nature of source formations of I and hydrocarbons in the offshore Shimokita Peninsula has a more terrestrial contribution compared with those in the Nankai Trough, but these formations are also considerably older than the host sediments, suggesting long-term transport of I and hydrocarbons for the accumulation of gas hydrates in both locations.     

Evaluation of the resistance of coastal Pinus thunbergii Parlat. forests to the tsunami fluid force in Japan

Natural Hazards - Coastal forests can protect coastal areas from the effects of tsunamis. However, the coastal forests of Tohoku were destroyed by the Great East Japan Tsunami, which was triggered...     

AMS analysis of I in Japanese soil samples collected from background areas far from nuclear facilities

Analytical procedures in the determination of iodine-129 (half-life: 1.6×10⁷ y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the ¹²⁹I/¹²⁷I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10⁻¹³. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10⁻¹¹ as the ratio of stable iodine (¹²⁹I/¹²⁷I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine ¹²⁹I in soil samples with low ¹²⁹I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the ¹²⁹I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10⁻⁵−4.5×10⁻³ Bq/kg as ¹²⁹I concentrations and 3.9×10⁻¹¹−2.2×10⁻⁸ as ¹²⁹I/¹²⁷I ratios. These values are useful in understanding the ¹²⁹I levels in Japanese environments. Higher ¹²⁹I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric ¹²⁹I due to tree canopies. Relatively high ¹²⁹I/¹²⁷I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation.     

Transition of solar cycle length in association with the occurrence of grand solar minima indicated by radiocarbon content in tree-rings

In this paper, we review the variation of the 11-year solar cycle since the 15th century revealed by the measurement of radiocarbon content in single-year tree-rings of Japanese cedar trees. Measurements of radiocarbon content in absolutely dated tree-rings provide a calibration curve for accurate dating of archaeological matters, but at the same time, enable us to examine the variations of solar magnetic activity in the pre-historical period. The Sun holds several long-term quasi-cyclic variations in addition to the fundamental 11-year sunspot activity cycle and the 22-year polarity reversal cycle, and it is speculated that the property of the 11-year and the 22-year solar cycle varies in association with such long-term quasi-cycles. It is essential to reveal the details of solar variations around the transition time of solar dynamo for illuminating the mechanisms of the long-term solar variations. We therefore have investigated the property of the 11-year and 22-year cycles around the two grand solar minima; the Maunder Minimum (1645–1715 AD) and the Spoerer Minimum (1415–1534 AD), the periods of prolonged sunspot minima. As a result, slight stretching of the “11-year” and the “22-year” solar cycles was found during these two grand solar activity minima; continuously during the Maunder Minimum and only intermittently during the Spoerer Minimum. On the contrary, normal or slightly shortened 11-year cycles were detected during the interval period of these two minima. It suggests the inverse correlation between the solar cycle length and solar magnetic activity level, and also the change of meridional flow during the grand solar activity minima. Further measurements for the beginning of the grand solar minima will provide a clue to the occurrence of such prolonged sunspot disappearance. We also discuss the effect of solar variations to radiocarbon dating.