Rare-earth distribution in alkali rocks from Oki-Dogo Island,Japan

Rare-earth, Sr and Ba abundances were determined for three basalts, one mugearite, one trachyandesite and five trachytes from Dogo, Oki Islands, Japan and Ca-rich clinopyroxene and feldspar phenocryst samples separated from them. It is concluded that rareearth, Sr and Ba abundance patters for basalts and three trachytes could be explained by crystallization differentiation of olivine basalt magma, while those for other samples suggest more complicated process of magma production. Calculated Eu²⁺ to total Eu ratios in the magmas showed a increasing trend with differentiation. It is found that Yb and Lu partition coefficients were larger than those of lighter rare earths for clinopyroxenes in trachytes suggesting preferential substitution of the heavy rare-earth ions for Mg-site in the clinopyroxenes.     

Influence of shear speed and normal stress on the shear behavior and shear zone structure of granular materials in naturally drained ring shear tests

“Sliding Surface Liquefaction” is a process causing strength loss and consequent rapid motion and long runout of certain landslides. Using a new ring shear apparatus with a transparent shear-box and digital video camera system, shear-speed-controlled tests were conducted on mixed grains (mixture of three different sizes of sand and gravel) and mixed beads to study shear behavior and shear zone development process under the naturally drained condition in which pore pressure is allowed to dissipate through the opened upper drainage valve during shearing. Higher excess pore water pressure and lower minimum apparent friction were observed in the tests where grain crushing was more extensive under higher normal stress and higher shear speed. Along with the diffusion of silty water generated by grain crushing, smaller particles were transported upward and downward from the shear zone. Concentration of larger grains to the central and upper part of the shear zone was confirmed by means of visual observation together with grain size analysis of sliced samples from several layers after the test. On the other hand, smaller particles were accumulated mostly below the layer where larger grains were accumulated. The reason why larger grains were accumulated into the shear zone may be interpreted as follows: grains under shearing are also subjected to vertical movement, the penetration resistance of larger grains into a layer of moving particles is smaller than that into the static layer. Therefore, larger grains tend to move into the layer of moving grains. At the same time, smaller particles can drop into the pores of underlying larger grains downward due to gravity.     

Prototyping an experimental early warning system for rainfall-induced landslides in Indonesia using satellite remote sensing and geospatial datasets

An early warning system has been developed to predict rainfall-induced shallow landslides over Java Island, Indonesia. The prototyped early warning system integrates three major components: (1) a susceptibility mapping and hotspot identification component based on a land surface geospatial database (topographical information, maps of soil properties, and local landslide inventory, etc.); (2) a satellite-based precipitation monitoring system () and a precipitation forecasting model (i.e., Weather Research Forecast); and (3) a physically based, rainfall-induced landslide prediction model SLIDE. The system utilizes the modified physical model to calculate a factor of safety that accounts for the contribution of rainfall infiltration and partial saturation to the shear strength of the soil in topographically complex terrains. In use, the land-surface “where” information will be integrated with the “when” rainfall triggers by the landslide prediction model to predict potential slope failures as a function of time and location. In this system, geomorphologic data are primarily based on 30-m Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data, digital elevation model (DEM), and 1-km soil maps. Precipitation forcing comes from both satellite-based, real-time National Aeronautics and Space Administration (NASA) Tropical Rainfall Measuring Mission (TRMM), and Weather Research Forecasting (WRF) model forecasts. The system’s prediction performance has been evaluated using a local landslide inventory, and results show that the system successfully predicted landslides in correspondence to the time of occurrence of the real landslide events. Integration of spatially distributed remote sensing precipitation products and in-situ datasets in this prototype system enables us to further develop a regional, early warning tool in the future for predicting rainfall-induced landslides in Indonesia.     

Experimental Study Assessing the Role of Sedimentary Organic Materials to Control the Redox State of Ground Materials to Control the Redox State of Groundwater: Consumption of Dissolved Oxygen by Humic Acid

Abstract: A total of 189 runs were completed to determine the rate of dissolved oxygen consumption in water by the reaction humic acid at 25°, 45°, and 65°C. Glass vial bottles were used as reaction vessels, and humic aicd and pure water of different intitial O₂ concentration was loaded with humic acid/water weight of 0.008 and 0.009. Vials were opened periodically to measure O₂ concentrations. The pH of the solution fluctuated in the early stages of the experiments and gradually decreased to a constant value. Dissolved oxygen concentration decreased, for example, from initial value of 12 mg/l to 9 mg/l at 25°C, to 5 mg/l at 45°C, and to 2 mg/l at 65°C after the reaction of 500 hours. Analyses of rates suggest that the reaction is first order, and rate constants are 8.42 × 10^-9 at 25°C, 2.22 × 10^-8 at 45°C, and 1.28 × 10^-7 moles m^-2 s^-1 at 65°C.     

Unusually abundant refractory inclusions from Sahara 97159 (EH3): a comparative study with other groups of chondrites

Sixty-eight refractory inclusions and fragments were found in two polished thin sections of the Sahara 97159 EH3 chondrite, indicative of the highest abundance of refractory inclusions (22/cm², or 0.06 vol.%) in enstatite chondrites studied to date. All of the inclusions are intensely altered, mainly producing feldspathoids and albite, CaO depletion and minor Ti-rich compounds, such as Ti-sulfides. The alteration assemblages and FeO-poor spinel suggest that the reactions took place under reducing and SiO₂-rich conditions. This is consistent with the redox state of the host enstatite chondrite. The presence of Ti sulfides and low FeO alteration phases distinguishes alteration of E chondrite refractory inclusions from that of carbonaceous and ordinary chondrites.Most of the inclusions are referred to as Type A-like (35) and spinel-rich (26), respectively. Assuming melilite has been altered, these inclusions could be analogues of individual concentrically zoned objects of fluffy melilite-spinel-rich (Type A) and spinel-pyroxene-rich inclusions from carbonaceous chondrites such as the Ningqiang (CV anomalous) and Y 81020 (CO3) chondrites. Two inclusions consist mainly of Ca-pyroxene, fine-grained alteration products (feldspathoids and albite) and spinel. They are probably altered fragments of Ca-pyroxene-plagioclase-rich (Type C) inclusions, assuming all plagioclase has been altered to produce the fine-grained groundmass. Five other inclusions are hibonite and/or corundum bearing, similar to those reported in carbonaceous chondrites. Abundance ratios of various types of the inclusions from Sahara 97159 are similar to those from Ningqiang and Y 81020.Most of the observations, including mineral assemblages, mineral chemistry, texture, bulk compositions, O isotopic compositions and REE patterns, of the Sahara inclusions suggest a common reservoir of refractory inclusions in enstatite, ordinary and carbonaceous chondrites. The apparent differences, such as absence of melilite and anorthite, rare Wark-Lovering rim and small size, can be explained by intense alteration due to large change of postformation environment of these inclusions, size sorting and collision during transfer. Hence, these differences are not inconsistent with the common reservoir model. Refractory inclusions in non-carbonaceous chondrites may put additional constraints on origins of refractory inclusions, and provide hints for a spatial relationship of their host meteorites.     

Formation of the Yakuno ophiolite; accretionary subduction under medium-pressure-type metamorphic conditions

The notion that the Yakuno ophiolite and overlying Maizuru Group represents an accretionary prism formed during the Permian evolution of Japan on the Yakuno eruptive sequence, association of hemipelagic mudstone with silicic tuff, exotic fossiliferous limestones derived from previously accreted sea-mounts, upward coarsening of sequences terrigenous sandstone and conglomerate, and mildly deformed Permian and Triassic forearc basin formations. The most important indicator, however, is the seaward imbrication and repetition observed in both the Maizuru Group and the ophiolite itself. D1 deformation structures include axial–planar foliations (pressure-solution cleavage for the Maizuru Group and granulite–amphibolite metamorphic layering in the ophiolite), flattening type strain, symmetric pressure shadows and fringes, and isoclinal folds showing axial–planar foliations and thrust faulting at their overturned limb. The exceptional asymmetry observed indicates seaward-directed shearing near the thrust, while D1 structures in the Maizuru zone are explained by off-scraping, above the basal decollement. The later Jurassic D2 kink fold structure includes a first-order asymmetric kink with a brittle thrust at its overturned limb, more-or-less coeval with M2 retrograde metamorphism. Medium-pressure M1 prograde metamorphism in the Yakuno ophiolite produced layering of granulite and amphibolite, and in the Maizuru Group, formation of illite along pressure-solution cleavage of mudstones. The metamorphic grade is controlled by the stratigraphic relationships and appears typical of that in ocean floor regions. However, there was only one episode of M1 prograde metamorphism which occurred contemporaneously with D1 off-scraping. Given that subduction zones are normally characterized by high P/T metamorphic regimes, the observed P/T history appears to reflect relatively unusual conditions. Such high thermal gradients may plausibly reflect the approach of a young, hot oceanic plate which continued subducting beneath the Japanese arc. Accordingly, the Yakuno ophiolite was probably formed at the trench–trench–ridge triple junction.     

云南东部上新元古界-下寒武统地层碳同位素变化

云南东部上新元古界-下寒武统沉积序列中碳酸盐岩较多，本文研究的三条剖面上厚约500m，包括：东龙潭组、渔户村组及筇竹寺组底部，覆于海相冰水沉积之上，反映了从潮上蒸发至浅水相环境。已获得的δ^13C和δ^18O值显示出较大的变化范围，分别是-7．33～ 2．64(‰)和-14．98～ 0．78(‰)。依靠δ^13C测试，结合岩矿鉴定，发现梅树村震旦系．寒武系界线层型剖面岩石成岩作用中有改造现象。显然，δ^13C总的变化范围及变化模式比世界其它地区小，但却包含一个δ^13C负异常，直接位于古生物学上的前寒武系-寒武系界线之下。     

Crystal structure of magnetite under pressure

The crystal structure and the unit-cell parameters of magnetite have been studied at room temperature up to a pressure of 4.5 GPa using a diamond anvil cell and a four-circle X-ray diffractometer. The isothermal bulk modulus (K _T ) and its pressure derivative (K' _T ) determined by fitting the pressure-volume data to the Murnaghan equation of state are 181(2) GPa and 5.5(15), respectively. The positional parameter u does not vary significantly over the pressure range of this study. The linear compressibilities of the interatomic distances and the bulk moduli of the polyhedra have been calculated from the pressure dependences of the unit-cell edge a and the u parameter. The Bloch equation has been modified to derive a relationship between the Néel temperature and the parameter u. The modified Bloch equation gives a closer agreement with the experimental results than the Weisz equation.     

Runoff and water budget of the Liudaogou Catchment at the wind–water erosion crisscross region on the Loess Plateau of China

The objectives of this study were to examine the runoff characteristics and to estimate water budget at the wind–water erosion crisscross region on the Loess Plateau of China. A small catchment known as Liudaogou that has representative meteorological and hydrological conditions of the wind–water erosion crisscross region was chosen as the study location. A numerical model for rainfall-runoff was developed and verified; rainfall-runoff calculation for 5 years (2005–2009) was performed. The observed data and numerical result of the surface runoff were used for evaluating runoff characteristics and estimating the annual water budget. Runoff rate was proportional to average intensity of rain. Even though rainfall duration was for few minutes, surface runoff was generated by intensity of more than 2.6 mm × 5 min^?1, when rainfall duration exceeded 10 h; surface runoff was generated by an intensity of 0.6 mm × 5 min^?1, while annual runoff rate was 10–15 %. The unit area of 1 km² was adopted as the index area for estimating annual water budget. Runoff, evapotranspiration, variation of water storage, and habitant water consumption accounted for 20.4, 75.6, 0, and 4 % of the total annual precipitation, respectively. Results of this study provide the basis for further research on hydrology, water resources, and sustainable water development and utilization at the wind–water erosion crisscross region on the northern Loess Plateau where annual water resources are relatively deficient.