Chemical, Isotopic, and Fluid Inclusion Evidence for the Hydrothermal Alteration of the Footwall Rocks of the BIF-Hosted Iron Ore Deposits in the Hamersley District, Western Australia

Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The δ¹⁸O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of ∼ 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale.     

Microearthquakes and faulting in the southern Okinawa Trough

Southern Okinawa Trough represents an early stage of back-arc rifting and is characterized by normal faulting and microearthquakes. Earthquake distribution and deep structure of fault was investigated to clarify active rifting in the southern Okinawa Trough, where two parallel grabens are located. A network of ocean bottom seismometers (OBSs) that displayed the hypocenters of 105 earthquakes were observed for a period of 4 days in southern-graben (SG). Most of the microearthquakes occurred in a cluster about 7 km wide, which on a cross-section striking N45°E dips 48° to the southwest. Relocated hypocenters, which are recorded by a local seismic network, show scattered distribution around the southern-graben. There are no remarkable surface faults in the southern-graben. On the other hand, the recalculation of hypocenter locations of 1996 earthquakes swarm recorded by a local seismic network suggests that the swarm is associated with normal faulting on the southern side of northern-graben (NG). Thus, the undeveloped southern-graben is located to the south of the developed northern-graben. Southward migration of rifting, which may be caused by migration of volcanism, could thus be occurring in the southern Okinawa Trough. The extension rate computed for the southern Okinawa Trough from the fault model of the northern-graben is 4.6 cm/year, which is 59–102% of the extension rate (GPS measurements). This result indicates that the majority of extensional deformation is concentrated within the center of the northern-graben in the Okinawa Trough.     

Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.     

Candidate precursors: pulse-like geoelectric signals possibly related to recent seismic activity in Japan

Telemetric network observations of pulse-like geoelectric charge signals using a vertical dipole buried under the ground were undertaken at various observation sites over a wide area in Japan from April 1996. From continuous records of the signals during the six months following that, we attempted to select anomalous signals, possibly related to seismic electric activity. Special attention was paid to the elimination of noise resulting from industrial and meteorological electric activity, comparison with other electromagnetic signals in the VLF band and the relation between the precursor period and the distance from the eventual main shock that occurred in Japan. Four candidate precursor electric signals, which were not contaminated by industrial and meteorological electric activity, were then selected, of which the second appeared before the Akita-ken Nairiku-nanbu earthquake swarm, for which the maximum M = 5.9 occurred on 1996 August 11, and the third and fourth before the Chiba-ken Toho-oki earthquake, M = 6.6, on 1996 September 11. A tentative qualitative model explaining why the candidate precursory signal is related to stress building up before an earthquake is presented in terms of the electrification of gases released from fracturing rocks immediately prior to the main shock.     

Simulation of normal distributed smooth fields by Karhunen-Loéve expansion in combination with kriging

Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.     

Interactive behavior of soil–pile-superstructure system in transient state to liquefaction by means of large shake table tests

Shaking table tests were conducted by means of a large-scale laminar box with 4 m in length, 2 m in width and 2 m in height in order to investigate behavior of a soil-pile-superstructure system in liquefiable ground. A model two-storey structure, supported by a pile group, was set in a saturated sand deposit, and subjected to a sinusoidal base motion with increasing amplitude. Discussions are focused on the transient behavior until soil liquefaction occurs. Main interests are characteristics of springs used in a sway-rocking model and a multi-freedom lumped mass (MFLM) model that are frequently used in soil–pile interaction analysis. The spring constant in the sway-rocking model is represented by restoring force characteristics at the pile head, and that in the MFLM system is represented by an interaction spring connecting the pile to the free field. The transient state prior to soil liquefaction is shown to be important in the design of a pile because dynamic earth pressure shows peak response in this state. The reduction of the stiffness due to excess porewater generation and strain dependent nonlinear behavior is evaluated.