Synthetic Fluid Inclusions in the Systems NaCl-H2O and NaCl-CO2-H2O: Dissolution Temperatures of Halite

Abstract. This study examined the effect of CO₂ on NaCl solubility in hydrothermal fluid, with the synthetic fluid inclusion technique. Fluid inclusions of 30–40 wt% NaCl and 5 mol % CO₂ were synthesized, and their halite dissolution temperatures, T_m(halite), were measured. The solubilities of NaCl in CO₂-bearing aqueous fluid were obtained at 160–320C under vapor-saturated pressures. The T_m(halite) value in aqueous fluid with 5 mol % CO₂ obtained in this study agrees with that of Schmidt et al. (1995), showing that 5 mol % CO₂ reduces the solubility of NaCl by about 1 wt%.
Calculation of magnetite solubility suggests that 5–10 mol % CO2 decreases magnetite solubility by 4.5–8.9 % relative to the magnetite solubility in CO2-free solution. Therefore, an increase of CO2 content in ore-forming solutions may cause deposition of iron minerals and produce ore deposits.     

Seismic experiments on Showa-Shinzan lava dome using firework shots

Seismic experiments were conducted on Showa-Shinzan, a parasitic lava dome of volcano Usu, Hokkaido, which was formed during 1943–1945 activity. Since we found that firework shots fired on the ground can effectively produce seismic waves, we placed many seismometers on and around the dome during the summer festivals in 1984 and 1985. The internal structure had been previously studied using a prospecting technique employing dynamite blasts in 1954. The measured interval velocity across the dome in 1984 ranges 1.8–2.2 km/s drastically low compared to the results (3.0–4.0 km/s) in 1954; in addition, the velocity is 0.3–0.5 km/s higher than that in the surrounding area. The variation of the observed first arrival amplitudes can be explained by geometrical spreading in the high velocity lava dome. These observations show a marked change in the internal physical state of the dome corresponding to a drop in the measured highest temperature at fumaroles on the dome from 800°C in 1947 to 310°C in 1986.     

Partitioning Eddy-Covariance Methane Fluxes from a Shallow Lake into Diffusive and Ebullitive Fluxes

Methane (\(\mathrm {CH}_{4}\)) is known to be emitted from lakes to the atmosphere via processes such as diffusion and ebullition (i.e., bubble emission). We developed a practical method for partitioning eddy-covariance \(\mathrm {CH}_{4}\) fluxes from a shallow lake into diffusive and ebullitive fluxes using a wavelet analysis based on local scalar similarity between the \(\mathrm {CH}_{4}\) concentration and other reference scalars, such as the air temperature or water vapour concentration, in the wavelet time-scale domain, with the hypothesis that similar and dissimilar fluctuation components are related to diffusive and ebullitive \(\mathrm {CH}_{4}\) fluxes, respectively. Our method is applied to approximately two weeks of data obtained at a shallow mid-latitude lake. The partitioned diffusive flux has a physically sound relationship with wind speed, supporting the validity of the method. The ratio of the diffusive flux to the total flux is typically 0.11 with flow from an area of steady bubble emission, but otherwise 0.36. Further validation is required using a larger dataset and data from other lakes. The proposed method can be easily applied to historical data because it requires only 10-Hz data of \(\mathrm {CH}_{4}\) concentration and other reference scalars, along with an empirical parameter.