Transformation dynamics and reactivity of dissolved and colloidal iron in coastal waters

We have investigated the chemical forms, reactivities and transformation kinetics of Fe(III) species present in coastal water with ion exchange and filtration methods. To simulate coastal water system, a mixture of ferric iron and fulvic acid was added to filtered seawater and incubated for a minute to a week. At each incubation time, the seawater sample was acidified with hydrochloric acid and then applied to anion exchange resin (AER) to separate negatively charged species (such as fulvic acid, its complexes with iron and iron oxyhydroxide coated with fulvic acid) from positively charged inorganic ferric iron (Fe(III)′). By monitoring the acid-induced Fe(III)′ over an hour, it was found that iron complexed by fulvic acid dissociated rapidly to a large extent (86–92% at pH 2), whereas amorphous ferric oxyhydroxide particles associated with fulvic acid (AFO-L) dissociated very slowly with the first-order dissociation rate constants ranging from 6.1 × 10^− 5 for pH 3 to 2.7 × 10^− 4 s^− 1 for pH 2. Therefore, a brief acidification followed by the AER treatment (acidification/AER method) was likely to be able to determine fulvic acid complexes and thus differentiate the complexes from the AFO-L particles (the dissolution of AFO-L was insignificant during the brief acidification). The acidification/AER method coupled with a simple filtration technique suggested that the iron–fulvic acid complexes exist in both the < 0.02 μm and 0.02–0.45 μm size fractions in our coastal water system. The truly dissolved iron (< 0.02 μm) was relatively long-lived with a life-time of 14 days, probably due to the complexation by strong ligands. Such an acid-labile iron may be an important source of bioavailable iron in coastal environments, as a significant relationship between the chemical lability and bioavailability of iron has been well recognised.     

基于GPS观测研究中国东北地区现今地壳形变特征

基于中国东北和俄罗斯远东东南部2012—2017年的GPS观测数据, 利用包含年周期、 半年周期、 线性项和阶跃项的函数模型拟合GPS站坐标时间序列, 得到ITRF2014下的速度场, 并进一步转换到欧亚参考框架下得到相对欧亚板块的速度场。 基于多尺度球面小波方法解算应变率场, 并分析了其空间分布特征, 同时研究了各GPS站对2011年日本东北M_W9.0大地震的震后松弛响应特征和背景形变场特征。 结果表明: ① 若不扣除日本东北大地震的松弛效应, 相对欧亚板块中国东北主体上表现为东南方向运动, 在依兰—伊通断裂和嫩江断裂带之间, 地壳表现为逆时针旋转, 其他区域向东南方向运动, 方向一致性较好, 在敦化—密山断裂东侧速度大小明显增加。 敦化—密山断裂和依兰—伊通断裂两侧拉张量分别为3.96±0.04 mm/a和0.71±0.05 mm/a, 两条断裂的剪切运动不明显。 总体上, 面应变率显示出NW—SE向的拉张和NE—SW向的挤压, 面应变率显示出依兰—伊通断裂南端、 嫩江断裂带北端和俄罗斯远东东南部呈挤压状态。 在依兰—伊通断裂、 敦化—密山断裂南侧以及俄罗斯远东东南部最大剪应变率相对较大。 ② 各GPS测站对2011年日本东北M_W9.0大地震震后松弛的响应整体上表现为东南向运动, 松弛形变量随震中距增加而减小。 松弛效应的面应变率总体上表现为NW—SE向的拉张和NE—SW向的挤压, 面应变率显示出依兰—伊通、 敦化—密山断裂南端、 嫩江断裂带北端以及俄罗斯远东地区具有挤压特征, 其他地区表现为拉张特征。 中国与俄罗斯远东边界南端存在一个明显的最大剪应变率高值区。 ③ 扣除日本东北M_W9.0大地震引起的松弛变形后, 总体上面应变率仍然表现为NW—SE向的拉张和NE—SW向的挤压, 面应变率最大值仍然位于依兰—伊通断裂和敦化—密山断裂南端、 第二松花江断裂带以及俄罗斯远东和中国边界最南段。 在依兰—伊通断裂、 敦化—密山断裂南端, 中国与俄罗斯远东边界南端的最大剪应变率高值区仍然存在, 表明这些地区应变积累较快, 并且一直在持续。     

The Megadeltas of Asia: interlinkage of land and sea,and human development

This special issue describes research arising from the megadelta project of the Asia‐Pacific‐Networks (APN), undertaken between 2004 and 2009 ( www.megadelta.ecnu.edu.cn ). Numerous delta‐coast scientists from more than 20 countries were involved in the project concerned with developing our knowledge of land–estuarine–coastal interactions in megadeltas, and with fusing this knowledge with societal development and management. Project workshops were held in Bangkok (2004), Ho Chi Minh City (2005), Dhaka (2007) and Shanghai (2008) with over 500 participants. The main objectives of the project were: (1) development of regional databases; (2) understanding of delta formation and associated fluxes between land and sea; (3) knowledge transfer and building research capacity; and (4) understanding how better social management might follow. Copyright © 2011 John Wiley & Sons, Ltd.     

Strong ground motion simulation during the November 1759 Earthquake along Serghaya Fault in the metropolitan of Damascus, Syria

The seismic hazard potential for metropolitan of Damascus, Syria is mainly controlled by earthquakes along Serghaya Fault which is a branch of Dead Sea Fault System. In this study, strong ground motion due to the November 1759 Earthquake along the fault of Serghaya was estimated with a numerical simulation technique. In the simulation, the Kostrov-like slip-velocity function was used as an input to the discrete wave number method to simulate the strong ground motions in a broadband frequency range. In order to model the incoherent rupture propagation which can excite large high-frequency waves, random numbers are added to arrival time of circular rupture front. MMI intensities calculated from the synthetic ground motions are compared with the observed values by Ambraseys and Barazangi (J Geophys Res 94:4007-4013, 1989). The calculated intensities are in good agreement with the observed ones at the most sites that validate appropriateness of the proposed source model. The PGA and PGV in the eastern region of Damascus city are higher than those in the western region due to the effects of local site amplification. The simulated high-frequency (1.0–6.0 Hz) ground motions for the sites in the Damascus city are higher than the design requirements defined by the Syrian building code. Furthermore, the simulated high-frequency ground motions for sites in the focal region are bigger than the design requirements in the case of the near-fault factors and are not considered. That demonstrates the appropriateness of considering the near-fault factors for a site near the focal region as introduced by the new building code.     

Ground motion characteristics and shaking damage of the 11th March 2011 M w9.0 Great East Japan earthquake

A catastrophic M _w9.0 earthquake and subsequent giant tsunami struck the Tōhoku and Kanto regions of Japan on 11th March 2011, causing tremendous casualties, massive damage to structures and infrastructure, and huge economic loss. This event has revealed weakness and vulnerability of urban cities and modern society in Japan, which were thought to be one of the most earthquake-prepared nations in the world. Nevertheless, recorded ground motion data from this event offer invaluable information and opportunity; their unique features include very strong short-period spectral content, long duration, and effects due to local asperities as well as direction of rupture/wave propagation. Aiming at gaining useful experience from this tragic event, Earthquake Engineering Field Investigation Team (EEFIT) organised and dispatched a team to the Tōhoku region of Japan. During the EEFIT mission, ground shaking damage surveys were conducted in Sendai, Shirakawa, and Sukagawa, where the Japan Meteorological Agency intensity of 6+ was observed and instrumentally recorded ground motion data were available. The damage survey results identify the key factors for severe shaking damage, such as insufficient lateral reinforcement and detailing in structural columns from structural capacity viewpoint and rich spectral content of ground shaking in the intermediate vibration period range from seismic demand viewpoint. Importantly, inclusion of several ground motion parameters, such as nonlinear structural response, in shaking damage surveys, can improve the correlation of observed ground motion with shaking damage and therefore enhance existing indicators of potential damage.     

River Water Pollution in Developed and Developing Countries: Judge and Assessment of Physicochemical Characteristics and Selected Dissolved Metal Concentration

To compare water quality in rivers of developed and developing countries, a study based on physicochemical parameters and dissolved metals levels was conducted. Water samples were collected from selected sites in Dhaka, Bangladesh; Hokkaido and Osaka, Japan; Erdenet, Mongolia and West Java, Indonesia. Analysis of least significant differences revealed that most water quality parameters were within comparable low levels in both developed and developing countries. The dissolved metals concentrations were found to be similar and below those of water standards except for manganese and cadmium at every sampling point, and lead in Erdenet, Mongolia. Some metals showed high enrichment factors in the rivers of Osaka, Japan and Erdenet, Mongolia, indicating accumulation possibility of metals in the river‐bed sediments. High concentrations of dissolved organic carbon, Escherichia coli and dissolved metals suggested greater water pollution in some rivers of developing countries than in the rivers of Japan. Principal component analysis showed strong correlations between “dissolved organic carbon and chemical oxygen demand” and “conductivity and total dissolved solids” at each sampling point, and E. coli, nitrate (NO), nitrite (NO), and pH levels were found to be higher in the rivers of Dhaka and Erdenet. In addition, there were high levels of Al and Zn in West Java, Pb in Erdenet, and Mn, Fe, and Cr in the rivers of Dhaka and Japan. Based on pressures and impacts, it is evident that dissolved metal, organic, and fecal pollution in the rivers of developing countries are in somewhat dreadful condition in comparison with the rivers of developed country.     

On the X-ray image of the Crab nebula: comparison with Chandra observations

An axisymmetric model for the Crab nebula is constructed to examine the flow dynamics in the nebula. The model is based on that of Kennel & Coroniti, although we assume that the kinetic-energy-dominant wind is confined to an equatorial region. The evolution of the distribution function of the electron–positron plasma flowing out in the nebula is calculated. Given viewing angles, we reproduce an image of the nebula and compare it with the Chandra observation.
The reproduced image is not ring-like, but is rather 'lip-shaped'. It is found that the assumption of a toroidal field does not reproduce the Chandra image. We must assume that there is a disordered magnetic field with an amplitude as large as the mean toroidal field. In addition, the brightness contrast between the front and back sides of the ring cannot be reproduced if we assume that the magnetization parameter σ is as small as ∼10⁻³. The brightness profile along the semimajor axis of the torus is also examined. The non-dissipative, ideal-magnetohydrodynamic approximation in the nebula appears to break down.
We speculate that if the magnetic energy is released by some process that produces a turbulent field in the nebula flow and causes heating and acceleration – for example, by magnetic reconnection – then the present difficulties may be resolved (i.e. we can reproduce a ring image and a higher brightness contrast). Thus, the magnetization parameter σ can be larger than previously expected.     

Superoxide-mediated Fe(II) formation from organically complexed Fe(III) in coastal waters

Fe(III) complexed by organic ligands (Fe(III)L) is the primary form of dissolved Fe in marine and coastal environments. Superoxide, typically produced in biological and photochemical processes, is one of the reducing agents that contributes to transformation of Fe(III)L to bioavailable, free dissolved Fe(II) (Fe(II)′). In this work, the kinetics of superoxide-mediated Fe(II)′ formation from Fe(III)L in a simulated coastal water system were investigated and a comprehensive kinetic model was developed using citrate and fulvic acid as exemplar Fe-binding ligands. To simulate a coastal environment in laboratory experiments, Fe(III)L samples with various ligand/Fe ratios were incubated for 5 min to 1 week in seawater medium. At each ratio and incubation time, the rate of superoxide-mediated Fe(II)′ formation was determined in the presence of the strong Fe(II) binding ligand ferrozine by spectrophotometrically measuring the ferrous-ferrozine complex generated at a constant concentration of superoxide. The Fe(II)′ formation rate generally decreased with incubation time, as Fe(III)L gradually dissociated to form less reactive Fe(III) oxyhydroxide. However, when the ligand/Fe ratio was sufficiently high, the dissociation of Fe(III)L (and subsequent Fe precipitation) was suppressed and Fe(II)′ was formed at a higher rate. The rate of Fe(II)′ produced during the experiment was explained by the kinetic model. The model confirmed that both the ligand/Fe ratio and incubation time have a significant effect on the pathway via which Fe(II)′ is formed from Fe(III)-fulvic acid complexes.