Quartz dissolution experiments at various pH, temperature and stress conditions: CLSM and ICP-AES investigations

To understand the effects of temperature, pH and mechanical stress on the pressure dissolution of quartz, two experiments using monocrystalline quartz samples were conducted. The first was a closed-fluid experiment to investigate the effect of pH, and the second was a flow-through experiment to investigate stress and temperature effects. To initiate the pressure dissolution, a pair of samples was immersed in a solution with a prescribed pH. The samples were stressed mechanically by pressing one sample against the other. In the closed-fluid experiments, the pH of the solution was fixed to 7, 9, 11 and 13, the applied stress was approximately 200 MPa and temperature 25°C. The flow-through experiments were conducted at three different temperatures (35, 50 and 75°C) at the same pH 11.7. The value of the applied stress was 7.32, 13.72, 21.42 or 25.27 MPa. During each of these dissolution tests, the solution was regularly sampled and analyzed by an Inductively Coupled Plasma-Atomic Emission Spectrometry technique to measure Si-concentration. With the measured Si-concentration, a dissolution rate constant was computed the different pH, stress and temperature conditions. The rate constant is proportional to pH, stress and temperature, as indicated in the literature. It should be noted that the rate constant for the highest stress (200 MPa) was considerably greater than for the other cases. In addition, island-channel patterns characterized by micro-cracks a few nanometers in length were seen on the dissolved parts of the samples. The findings and the measured data in this paper may be useful for the future development of theoretical models for pressure dissolution and its validation.     

Upper ocean warming pattern in the past 50 years

A long-term warming pattern of global subsurface ocean was detected separately from other natural variations. Three dominant modes were extracted: a long-term warming mode, a mode related to the El Niño/Southern Oscillation, and a mode related to the Atlantic Multidecadal Oscillation. The long-term warming mode explained 78 % of the global mean temperature variance from the surface to a depth of 300 m, and the other two modes could explain most of the residual variance. Subsurface warming associated with the long-term warming mode was strong in the subtropics. In contrast, there was a local minimum of warming in the northern hemisphere subarctic ocean, and warming was suppressed in subsurface waters south of the equator. Atmospheric changes associated with the long-term warming mode showed negative (positive) sea level pressure anomalies at high (middle) latitudes in both hemispheres, and an intensification and/or a poleward expansion of mid-latitude westerlies. Wind stress curl changes were negative in the subtropics and positive in the subarctic of the northern hemisphere; changes that were consistent with the strong warming in the subtropics and the local minimum of warming in the subarctic. Warming of Southern Ocean subsurface waters coincided with southward migration and intensification of westerly winds, whereas surface warming to the south of 50°S was suppressed, probably by strengthened northward Ekman transport. Positive wind stress curl off the equator with weakening of the tropical easterly winds in the Pacific and Indian Oceans was consistent with the subsurface negative temperature anomaly there.     

Multi‐year tracking of sediment sources in a small agricultural watershed using rare earth elements

Rare earth elements (REEs) have been successfully used as a sediment tracer, but the REE technique has never been used for studying sediment sources for a multi‐year period. A nearly four‐year field experiment was conducted on a small agricultural watershed near Coshocton, OH, USA, to assess the applicability of the REE technique for a multi‐year period and to evaluate the relative contributions of sediment sources in the watershed. Tracer depletion and tracer enrichment ratio (ratio of the tracer concentrations in sediment to the concentrations in the soil in the areas of application) were evaluated to examine the applicability and accuracy of the technique. A minimum of 91 per cent of the mass of the applied elements was still available on any individual morphological element at the end of the experimental period. The tracer enrichment ratio varied from 0·4 to 2·3, and it was not significantly related to time. The relative contributions of six morphological elements within the watershed were evaluated as proportions to total sediment yield. The relative contribution of the lower channel was significantly increased as a function of the amount of sediment yield, while that of the lower backslope was significantly decreased. The relative contribution of the lower channel significantly decreased as a function of cumulative sediment yield, while the contributions of the shoulder and the upper backslope significantly increased. Our results showed that the REE technique can be used to track sediment sources for a relatively long period with two limitations or potential sources of error associated with a selective depletion of tracers and a contamination of downslope areas with tagged sediments from upslope areas. Copyright © 2006 John Wiley & Sons, Ltd.     

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.     

An overview of decadal climate predictability in a multi-model ensemble by climate model MIROC

Decadal climate predictability is examined in hindcast experiments by a multi-model ensemble using three versions of the coupled atmosphere-ocean model MIROC. In these hindcast experiments, initial conditions are obtained from an anomaly assimilation procedure using the observed oceanic temperature and salinity with prescribed natural and anthropogenic forcings on the basis of the historical data and future emission scenarios in the Intergovernmental Panel of Climate Change. Results of the multi-model ensemble in our hindcast experiments show that predictability of surface air temperature (SAT) anomalies on decadal timescales mostly originates from externally forced variability. Although the predictable component of internally generated variability has considerably smaller SAT variance than that of externally forced variability, ocean subsurface temperature variability has predictive skills over almost a decade, particularly in the North Pacific and the North Atlantic where dominant signals associated with Pacific decadal oscillation (PDO) and the Atlantic multidecadal oscillation (AMO) are observed. Initialization enhances the predictive skills of AMO and PDO indices and slightly improves those of global mean temperature anomalies. Improvement of these predictive skills in the multi-model ensemble is higher than that in a single-model ensemble.     

ENSIP: the El Niño simulation intercomparison project

An ensemble of twenty four coupled ocean-atmosphere models has been compared with respect to their performance in the tropical Pacific. The coupled models span a large portion of the parameter space and differ in many respects. The intercomparison includes TOGA (Tropical Ocean Global Atmosphere)-type models consisting of high-resolution tropical ocean models and coarse-resolution global atmosphere models, coarse-resolution global coupled models, and a few global coupled models with high resolution in the equatorial region in their ocean components. The performance of the annual mean state, the seasonal cycle and the interannual variability are investigated. The primary quantity analysed is sea surface temperature (SST). Additionally, the evolution of interannual heat content variations in the tropical Pacific and the relationship between the interannual SST variations in the equatorial Pacific to fluctuations in the strength of the Indian summer monsoon are investigated. The results can be summarised as follows: almost all models (even those employing flux corrections) still have problems in simulating the SST climatology, although some improvements are found relative to earlier intercomparison studies. Only a few of the coupled models simulate the El Niño/Southern Oscillation (ENSO) in terms of gross equatorial SST anomalies realistically. In particular, many models overestimate the variability in the western equatorial Pacific and underestimate the SST variability in the east. The evolution of interannual heat content variations is similar to that observed in almost all models. Finally, the majority of the models show a strong connection between ENSO and the strength of the Indian summer monsoon.     

春季欧亚大陆地表气温变化特征的气候意义

研究了春季欧亚大陆地表气温的年际变化及其相联系的环流场特征,发现春季欧亚大陆地表气温年际变化呈现为大陆尺度的南北跷跷板式的空间分布特征, 即当中高纬度地表气温为正距平时,副热带地区则为负距平,反之亦然。这种空间分布型代表了欧亚大陆中高纬度地表气温年际变化的主要特征。进一步的研究表明,这种变化与前期冬季北大西洋涛动（NAO）有着显著的正相关,而与同期的NAO无关。同时,欧亚大陆地表气温异常存在着明显的从冬到夏的持续性。与东亚初夏气候变化关系的研究表明,春季欧亚大陆地表气温的变化通过影响鄂霍次克高压的变化进一步影响初夏梅雨的变化。当春季欧亚大陆中高纬度地表气温为正距平时,鄂霍次克高压偏强,初夏梅雨较活跃,反之亦然。