Simultaneous vertical measurements of in situ pH and CO2 in the sea using spectrophotometric profilers

We have developed new systems capable of profiling to >1000 m for measuring in situ pH and fugacity of CO₂ (fCO₂) in the ocean using spectrophotometric analysis (pH and CO₂ profilers). The in situ pH is determined by detecting the color change of the pH indicator (m-cresol purple). It can withstand ambient pressure to 1000 m depth. The CO₂ profiler analyzed in situ fCO₂ by detecting the change of pH in an inner solution, equilibrated with the seawater through a gas permeable membrane. It can be operated to 2500 m depth. We used an amorphous fluoropolymer tubing form of AF-2400 for the gas permeable membrane due to its high gas permeability coefficients. The inner solution was a mixture of 2 μM bromocresol purple (BCP) and 5 μM sodium hydroxide. This system gave us a response time of 1 minute, which is twice as fast as previous systems. The precisions of pH and CO₂ profilers were within 0.002 and 2.5% respectively. We have used these profilers to study the North Pacific, obtaining good agreement with the difference between the data from profilers and a discrete bottle of 0.002 ± 0.005 pH (SE, n = 25) and −0.4 ± 3 μatm (SE, n = 31).     

Simulation of long‐term consolidation behavior of soft sensitive clay using an elasto‐viscoplastic constitutive model

The phenomenon of excess pore water pressure increase or stagnation and continuing large ground deformation in soft sensitive clay following the completion of construction of embankment is simulated for a case study at Saint Alban, Quebec, Canada. The present model employs an updated Lagrangian finite element framework and is combined with an automatic time increment selection scheme. The simulation based on an elasto‐viscoplastic constitutive model considers soil‐structure degradation effect. It is shown that without consideration for the microstructural degradation effect, it is not possible to reproduce the field responses of soft sensitive clay even during the construction of the embankment. When the soil‐structure degradation effect is considered, the present model can offer reasonably accurate prediction for the consolidation behavior of soft sensitive clay, including the so‐called anomalous pore water pressure generation and continuing large deformation even after the end of construction, which has been posing numerous uncertainties on the long‐term performance of earth structures. Copyright © 2013 John Wiley & Sons, Ltd.     

The degree of Cl-loss for the particulate matter (PM) and fog water sampled at the same air mass at the Hachimantai mountain range in northern Japan

It is well known that sea-salt aerosols in particulate matter (PM) react with acids such as H₂SO₄ and HNO₃ during transportation and thereby lose chloride ions (Cl-loss). The PM and fog were sampled concurrently at different altitudes in the Hachimantai mountain range, northern Japan. The PM and fog sampled at different altitudes had nearly identical properties for the ion components. However, the PM was in a Cl-depleted state (more than 80% of all samples), but the fog water was not in so Cl-depleted state (less than 29%). As a result, it could be explained that this phenomenon caused because the fog droplets took up the gaseous state HCl other than sea-salt PM. After all Cl^- in the fog water recovered and was rather rich compared with the sea-salt or the PM by the uptake of the gaseous state HCl. Moreover, it was found that for PM_coarse(2.5 < D < 10), 86% of the acid (H₂SO₄ and HNO₃) was consumed for Cl-loss reactions and/or for dissolution of Ca and Mg in soil particles.     

New approach for optimal perturbation method in ensemble climate prediction with empirical singular vector

In this study, a new method is developed to generate optimal perturbations in ensemble climate prediction. In this method, the optimal perturbation in initial conditions is the 1st leading singular vector, calculated from an empirical linear operator based on a historical model integration. To verify this concept, this method is applied to a hybrid coupled model. It is demonstrated that the 1st leading singular vector from the empirical linear operator, to a large extent, represents the fast-growing mode in the nonlinear integration. Therefore, the forecast skill with the optimal perturbations is improved over most lead times and regions. In particular, the improvement of the forecast skill is significant where the signal-to-noise ratio is small, indicating that the optimal perturbation method is effective when the initial uncertainty is large. Therefore, the new optimal perturbation method has the potential to improve current seasonal prediction with state-of-the-art coupled GCMs.     

On the three-dimensional internal waves excited in the flow of a linearly stratified Boussinesq fluid

Three-dimensional flow of a linearly stratified Boussinesq fluid is studied numerically. The flow is assumed to be confined in a rectangular channel and internal waves are excited by bottom topography. Near resonance of the first vertical internal wave mode, it was found that the reflection of the internal wave at the sidewall is ‘abnormal’ in the sense that the reflection angle is larger than the incident angle and a third wave perpendicular to the sidewall is generated. The waves become straight crested (two-dimensional) as this third wave becomes longer. The whole mechanism is similar to the ‘Mach reflection’ observed in the general stratified fluid in which the usual solitary waves are generated. In the case of the linearly stratified Boussinesq fluid, the abnormal reflection occurs even though the wave near the sidewall has a sinusoidal profile and not a sech² profile. This suggests that the abnormal reflections similar to Mach reflection always occur when the wave amplitude is large enough, irrespective of the wave profile.     

Summertime land–sea thermal contrast and atmospheric circulation over East Asia in a warming climate—Part I: Past changes and future projections

Land–sea surface air temperature (SAT) contrast, an index of tropospheric thermodynamic structure and dynamical circulation, has shown a significant increase in recent decades over East Asia during the boreal summer. In Part I of this two-part paper, observational data and the results of transient warming experiments conducted using coupled atmosphere–ocean general circulation models (GCMs) are analyzed to examine changes in land–sea thermal contrast and the associated atmospheric circulation over East Asia from the past to the future. The interannual variability of the land–sea SAT contrast over the Far East for 1950–2012 was found to be tightly coupled with a characteristic tripolar pattern of tropospheric circulation over East Asia, which manifests as anticyclonic anomalies over the Okhotsk Sea and around the Philippines, and a cyclonic anomaly over Japan during a positive phase, and vice versa. In response to CO₂ increase, the cold northeasterly winds off the east coast of northern Japan and the East Asian rainband were strengthened with the circulation pattern well projected on the observed interannual variability. These results are commonly found in GCMs regardless of future forcing scenarios, indicating the robustness of the East Asian climate response to global warming. The physical mechanisms responsible for the increase of the land–sea contrast are examined in Part II.     

A diagnostic study of the impact of El Niño on the precipitation in China

The impact of El Niño on the precipitation in China for different seasons are investigated diagnostically. It is found that El Niño can influence the precipitation in China significantly during its mature phase. In the Northern winter, spring and autumn, the positive precipitation anomalies are found in the southern part of China during the El Niño mature phase. In the Northern summer, the patterns of the precipitation anomalies in the El Niño mature phase are different from those in the other seasons. The negative precipitation anomalies appear in both southern and northern parts of China, while in between around the lower reaches of the Yangtze River and the Huaihe River valleys the precipitation anomalies tend to be positive. In the Northern winter, spring and autumn, the physical process by which El Niño affects the precipitation in the southern part of China can be explained by the features of the circulation anomalies over East Asia during the El Niño mature phase (Zhang et al., 1996). The appearance of an anticyclonic anomaly to the north of the maritime continent in the lower troposphere during the El Niño mature phase intensifies the subtropical high in the western Pacific and makes it shift westward. The associated southwesterly flow is responsible for the positive precipitation anomalies in the southern part of China. In the Northern summer, the intensified western Pacific subtropical high covers the southeastern periphery of China so that the precipitation there becomes less. In addition, the weakening of the Indian monsoon provides less moisture inflow to the northern part of China.     

Temperature Profiles Within and Above an Urban Canopy

The seasonal trend of vertical temperature profiles within and above an urban canopy has been investigated. We measured air temperatures and wind velocities along a 29-m tower in a residential area of Tokyo, Japan continually for 14 months. The height of the daily maximum temperature Z_Tmax varied with the season; Z_Tmax was at the roof level in winter but near the ground in summer. The seasonal change of Z_Tmax is likely due to the change of height at which solar energy is absorbed. At the time of the maximum temperature, the atmosphere above the canopy is always unstable whereas the air within the canopy is unstable in summer but stable in winter.     

A large-scale excavation in soft Holocene deposit and its elasto-viscoplastic analysis

In the present study, the large-scale excavation in the construction is numerically back-analyzed using a soil–water-coupled finite element method with an elasto-viscoplastic model which considers the strain-induced degradation. The measurements of the deformation have been performed during the construction of a new railway station in Osaka, Japan, in which a large and deep excavation has been successfully carried out using a special deep mixing type of soil improvement method with earth retaining walls through the thick Holocene Osaka Umeda clay deposit. A comparison between the numerical results and the measurements of the excavation at Osaka shows that the simulation method can reproduce the overall deformation of the soft ground and the earth retaining walls including the time-dependent behaviour during the excavation and a deep mixing soil improvement method as an additional technique for stability are effective.     

Multi‐species diffusion analysis in porous media under various dry density and temperature conditions: molecular dynamics simulation,homogenization analysis,and finite element method

In porous media, chemical species that dissolve in pore water can be transported via diffusion mechanisms or advective fluxes, close to or far away from where precipitation occurs. In the case of a high‐level radioactive waste disposal system, compacted bentonite is used in a buffer material in an engineering barrier system to minimize the amount of specific nuclides that breach into the surrounding host rock. To minimize breaching, it is very important to understand the transport mechanism of multiple chemical species in porous media. In the following research, we introduced FEM analysis methods using the results of the molecular dynamics simulation and homogenization analysis (MD/HA) method. First, the diffusion coefficients of ions (Cl^?, I^?, and Na⁺) in different water layers of Na‐beidellite were calculated using the MD/HA procedure under various dry density (1.2, 1.6, and 2.0 Mg/m³) and temperature (293, 323, and 363 K) conditions. Next, using FEM analysis that used the MD/HA results as input parameters, the diffusion behaviors of ions in porous media were calculated. The results indicate that the diffusion coefficients of the interlayer water in Na‐beidellite are different from the diffusion coefficients under dry density conditions. Further, the concentration profiles (C_t/C₀) of iodine and chloride are proportional to temperature but inversely proportional to dry density. Copyright © 2014 John Wiley & Sons, Ltd.