Fog and rain water chemistry at Mt. Fuji: A case study during the September 2002 campaign

Measurements of fog and rain water chemistry at the summit of Mt. Fuji, the highest peak in Japan, as well as at Tarobo, the ESE slope of Mt. Fuji in September 2002. The pH of fog and rain water sampled at Mt. Fuji varied over a range of 4.0–6.8. Acidic fogs (pH < 5.0) were observed at the summit when the air mass came from the industrial regions on the Asian continent. The ratio of [SO₄²⁻]/[NO₃⁻] in the fog water was lower at Tarobo than at the summit. High concentrations of Na⁺ and Cl⁻ were determined in the rain water sampled at the summit, possibly because of the long-range transport of sea-salt particles raised by a typhoon through the middle troposphere. The vertical transport of sea-salt particles would influence the cloud microphysical properties in the middle troposphere. Significant loss of Mg²⁺ was seen in the rain water at the summit. The concentrations of peroxides in the fog and rain water were relatively large (10–105 μM). The potential capacity for SO₂ oxidation seems to be strong from summer to early autumn at Mt. Fuji. The fog water peroxide concentrations displayed diurnal variability. The peroxide concentrations in the nighttime were significantly higher than those in the daytime.     

Performance of a lithium fluoride bolometer for Tokyo dark matter search experiment

The performance of a 21-g lithium fluoride bolometer is presented. The background spectrum was measured in the surface laboratory. We derive an exclusion plot for the spin-dependent coupled Weakly Interacting Massive Particles (WIMPs) cross section.     

“Extreme boiling” model for variable salinity of the Hokko low-sulfidation epithermal Au prospect, southwestern Hokkaido, Japan

The Hokko prospect is located in the Minamikayabe area southwestern Hokkaido, Japan, where gold-bearing quartz veins of Pliocene age are exposed at the surface. The alteration mineral assemblage is typical of low-sulfidation epithermal systems, with the quartz veins associated with adularia alteration overprinted on Late Miocene propylitic alteration. Fluid inclusion studies of the vein quartz reveal mean homogenization temperatures of approximately 220 °C, and the co-existence of low-salinity (<2 wt.% NaCl equivalent) and moderate salinity (2 to 12 wt.% NaCl equivalent) fluid inclusions within the same veins. The moderate salinity fluid inclusions (2–12 wt.% NaCl equivalent) typically have relatively low homogenization temperatures between 150° to 200 °C. The results obtained from stable isotope analysis of  δ¹⁸O in quartz vein material showed a gradual decrease in  δ¹⁸O signatures with increasing depth. The majority of the samples have calculated fluid source signatures (δ¹⁸O_H2O) between −8.0 and −10.0‰, but there is a significant change in the composition above 185 m drill depth. The shallower samples in particular show a wide range of oxygen isotope signatures that are associated with the moderate salinity fluid inclusions. We interpret that low-salinity inclusions within the Hokko system represent the composition of the liquid phase of the fluid, before boiling, and that the moderate-salinity inclusions are representative of the residual liquid phase, after extensive non-adiabatic boiling and vapor loss in an open system. This mechanism resulted in the entrapment of fluids with variable salinities at the same time, and in close proximity to each other. This is also reflected in the  δ¹⁸O_H2O values which become more variable and heavier where the moderate-salinity inclusions occur. Deposition of ore minerals within the Hokko vein system also occurred at this time as a result of boiling and gas loss. Received: 30 May 1997 / Accepted: 6 January 1998     

Seismological significance of the 1977–1978 eruptions and the magma intrusion process of usu volcano, Hokkaido

An earthquake swarm, and the major pumice eruptions in August 1977 which followed, marked the start of the dacitic doming activity of Usu volcano in southwestern Hokkaido, Japan. The sequence of magma intrusion processes was investigated in detail by means of seismological and other geophysical data. The distribution of the abundant hypocenters shows clearly an earthquake-free zone beneath the summit crater. The hypocenters migrated in a manner consistent with the development of the observed asymmetrical surface deformations, considered due to magma intrusion into this earthquake-free zone. The earthquake mechanism solutions are mostly of dip-slip type and are interpreted in terms of the doming deformations. The existence of earthquake families (earthquakes with similar waveforms) is the main cause of the peculiar occurrence of earthquakes in space, time and magnitude. The concept of scattered barriers of different sizes and strengths can explain well the distinct characteristics of the occurrence of the swarm, and the observed episodic deformations.     

Chemical fractionations in meteorites—IX. C3 chondrites

Four C3V chondrites (Grosnaja, Kaba, Mokoia, Vigarano) and three C3O chondrites (Felix, Kainsaz, and Lancé) were analyzed by radiochemical neutron activation for 17 trace elements. Both classes show a typical chondritic step pattern, reflecting loss of volatiles during chondrule formation. Elements condensing above 1300 K (U, Re, Ir, Ni) are present in essentially Cl chondrite proportions, while moderately volatile elements condensing between 1300 K and 800 K (Ge, Rb, Ag) are depleted by a factor of 0.44. However, elements condensing below 700 K (S, Cs, Bi, Tl, Br, Se, Te, In, Cd) are depleted to a still greater degree, and more so in the Ornans subclass (factor of 0.24, except Cd 0.007) than in the Vigarano subclass (factor of 0.29). This additional depletion may be due to a slight (less than 3-fold) dust-gas fractionation, by settling of dust to the median plane of the solar nebula. Among other chondrite classes, ordinary chondrites show a similar depletion, but C2 chondrites do not. Possibly the undepleted meteorites formed in one of the convection zones of the nebula predicted by Cameron and Pine, whereas the depleted meteorites formed in a quiescent region.The condensation of chalocophile elements as a function of H₂S partial pressure is discussed, in an attempt to explain the drastic difference in Cd abundance between the two subclasses. It appears that the $\text{H}{}_2\text{S}\text{H}{}_2$ ratio is the key variable. C3O's seem to have condensed in a region where enough metallic Fe was present to buffer the H₂S pressure, while C3V's condensed in a more oxidized region, where H₂S was in excess. Accretion temperatures, for an assumed nebular pressure of 10^?5 atm, were between 415 and 430 K for C3O's and less than 440 K for C3V's.Two slightly volatile elements, Sb and Au, show variable depletion, presumably reflecting variable loss during chondrule formation. Indeed, their depletion correlates with the abundance of iron-poor olivine, a measure of the peak temperature and time during chondrule formation.     

Enhanced chlorophyll associated with island-induced cyclonic eddies in the eastern channel of the Tsushima Straits

The relationship between island-induced cyclonic eddies and chlorophyll a (chl-a) was investigated using field data and satellite images in the eastern channel of the Tsushima Straits. The maximum chl-a concentration around the leeward eddy of the Tsushima Islands was two or three times greater than that of outside the eddy. Two different mechanisms of chl-a enhancement associated with island-induced cyclonic eddies were found in the post-bloom periods. In summer, when nutrients were depleted in the surface layer, eddy pumping increased the nutrient supply in the euphotic zone, resulting in enhanced chl-a around the shallow thermocline near the eddy core. In late autumn, when the mixed layer deepened over the euphotic zone, the mixed layer depth became shallow due to the doming effect of the cyclonic eddy, therefore, the improved irradiance condition led to an increase in the chl-a concentration in the surface mixed layer. Nighttime satellite visible images showed a number of fishing vessels in the lee region of the Tsushima Islands, implying that the enhanced phytoplankton biomass may have resulted in good feeding conditions for fishes and squids in the Tsushima Straits.     

Patterns in abundance and size of two deep-water gorgonian octocorals,in relation to depth and substrate features off Nova Scotia

Deep-water corals form unique ecosystems, yet very little is known about factors that regulate their distribution and growth. The abundance and size of two deep-water gorgonian coral species, Paragorgia arborea and Primnoa resedaeformis, and their relationship with depth and substratum cover, were investigated at Northeast Channel, off Nova Scotia, in July 2006. This is the first study to measure abundance and size of these two coral species at depths >500 m in the Canadian Atlantic region. A total of 5 transects between 500 and 1000 m depth were examined using video collected by the remotely operated vehicle ROPOS. Abundance of both species was patchy, but higher at these deeper depths than at <500 m. Abundance generally declined with depth, and was moderately correlated with cover of hard substratum (cobble, boulder, bedrock). These relationships were stronger and less variable for P. resedaeformis than for P. arborea, suggesting that factors such as topographic relief may play an additional role in regulating distributions of P. arborea. Maximum colony height was 125 and 240 cm for P. resedaeformis and P. arborea, respectively, and much greater than recorded for depths <500 m. Overall, colony height and depth relationships were strong for both species, but variable among transects. P. resedaeformis showed a negative relationship with depth, while the opposite was observed for P. arborea, suggesting that the two species are affected differently by factors that vary with depth (e.g. temperature, fishing disturbance). Relationships between colony size and size of attachment stone were stronger for P. arborea, especially for overturned colonies, than for P. resedaeformis, suggesting that availability of suitably coarse substrate may be more important for the long-term persistence of P. arborea colonies.     

Distribution of <Emphasis Type="Italic">Nemopilema nomurai</Emphasis> in the southwestern Sea of Japan related to meandering of the Tsushima Warm Current

We investigated the horizontal distribution of Nemopilema nomurai medusae using a midwater trawl in the southwestern Sea of Japan from September to October of each year from 2006 to 2012. Numerous medusae of this species found in 2006, 2007, and 2009 were mainly distributed far (>40 km) from the mainland of Japan in the western part of the survey area, but were distributed in the stations closest (<25 km) to the mainland in the eastern part, particularly in 2006 and 2009. These distribution patterns were associated with the path of the second branch of the Tsushima Warm Current (TWC) that flows offshore to the west of Oki Islands and usually approaches the mainland of Japan to the east of Oki Islands. Differences in jellyfish distribution across the survey periods were related to the distribution of the second branch being associated with types, position and intensity of eddies in the eastern part of the survey area. Hence, the formations of eddies and consequent variation in the path of the TWC would be responsible for transporting medusae from offshore to near the mainland to the east of Oki Islands. Individuals with large bells accumulated in the northwestern part of the survey area, where a cyclonic eddy was present downstream of the third branch of the TWC. This variation in bell size distribution may be ascribed to differences in the physical and/or biological factors among the three branches of the TWC.     

Temporal Evolution of a Rapidly-Moving Umbral Dot

We performed two-dimensional spectroscopic observations of the preceding sunspot of NOAA 10905 located off disk center (S8 E36, μ≈0.81) by using the Interferometric BI-dimensional Spectrometer (IBIS) operated at the Dunn Solar Telescope (DST) of the National Solar Observatory, New Mexico. The magnetically insensitive Fe I line at 709.04 nm was scanned in wavelength repetitively at an interval of 37 s to calculate sequences of maps of the line-wing and line-core intensity, and the line-of-sight Doppler velocity at different line depths (3% to 80%). Visual inspection of movies based on speckle reconstructions computed from simultaneous broadband data and the local continuum intensity at 709.04 nm revealed an umbral dot (UD) intruding rapidly from the umbral boundary to the center of the umbra. The apparent motion of this object was particularly fast (1.3 km s⁻¹) when compared to typical UDs. The lifetime and size of the UD was 8.7 min and 240 km, respectively. The rapid UD was visible even in the line-core intensity map of Fe I 709.04 nm and was accompanied by a persistent blueshift of about 0.06 km s⁻¹.     

Correlation between electron paramagnetic resonance and thermoluminescence in natural sodalite

Samples of natural sodalite, Na₈Al₆Si₆O₂₄Cl₂, submitted to gamma irradiation and to thermal treatments, have been investigated using the thermoluminescence (TL) and electron paramagnetic resonance (EPR) techniques. Both, natural and heat-treated samples at 500°C in air for 30 min, present an EPR signal around g = 2.01132 attributed to oxygen hole centers. The EPR spectra of irradiated samples show an intense line at g = 2.0008 superimposed by a hyperfine multiplet of 11 lines due to an O⁻ ion in an intermediate position with respect to two adjacent Al nuclei. In the TL measurements, the samples were annealed at 500°C for 30 min and then irradiated with γ doses varying from 0.001 to 20 kGy. All the samples have shown TL peaks at 110, 230, 270, 365, and 445°C. A correlation between the EPR g = 2.01132 line and the 365°C TL peak was observed. A TL model is proposed in which a Na⁺ ion acts as a charge compensator when an Al³⁺ ion replaces a Si⁴⁺ lattice ion. The γ ray destruction of the Al–Na complex provides an electron trapped at the Na and a hole trapped at a non-bridging oxygen ion adjacent to the Al³⁺ ion.