Graphitization of carbonaceous matter during metamorphism with references to carbonate and pelitic rocks of contact and regional metamorphisms,Japan

This study is an attempt to correlate the graphitization process of carbonaceous matter during metamorphism with metamorphic grade. Graphitization can be parameterized using crystal structure and chemical and isotopic compositions. The extent of graphitization could be characterized mainly by temperature, duration of metamorphism and rock composition. We compared the graphitization trends for two metamorphic terrains, a contact aureole of the Kasuga area and a regional metamorphic terrain of high-temperature/low pressure type of the Ryoke metamorphic terrain in Northern Kiso area, Central Japan, and for two different lithologies (carbonate and pelite), using X-ray diffractogram, DTA-TG analysis, and chemical and stable isotope analyses. During contact metamorphism, graphitization and carbon isotopic exchange reactions proceeded simultaneously in pelitic and carbonate rocks. The decreases in basal spacing d(002) of the carbonaceous matter in carbonate rocks is greatly accelerated at temperatures higher than about 400° C. Furthermore, carbon isotopic ratios of graphite in carbonate rocks also change to ¹³C-enriched values implying exchange with carbonates. The beginning of this enrichment of ¹³C in the carbonaceous matter coincides with an abrupt increase of the graphitization processes. Carbon isotopic shifting up to 5 in pelites could be observed as metamorphic temperature increased probably by about 400° C. Carbonaceous matter in pelitic rocks is sometimes a mixture of poorly crystallized organic matter and well-crystallized graphite detritus. DTA-TG analysis is an effective tool for the distinction of detrital graphitic material. Two sources for the original carbon isotopic composition of carbonaceous matter in pelites in the Kasuga contact aureole can be distinguished, about-28 and-24 regardless of the presence of detrital graphite, and were mainly controlled by depositional environment of the sediments. Graphitization in limestones and pelitic rocks in regional metamorphism proceeds further than in a contact aureole. In the low-temperature range, the differences in extent of graphitization between the two metamorphic regions is large. However, at temperatures higher than 600° C, the extent of graphitization in both regions is indistinguishable. The degree of graphitization is different in limestones and pelitic rocks from the Ryoke metamorphic terrain. We demonstrate that the graphitization involves a progressive re-construction process of the crystal structure. The sequence of the first appearance of crystal inter planar spacing correlates with the metamorphic grade and indicates the crystal growth of three-dimensional structured graphite.     

The role of the grain boundary at chemical and isotopic fronts in marble during contact metamorphism

Carbon and oxygen isotopic profiles around a low pressure metasomatic wollastonite reaction front in a marble of the Hida metamorphic terrain, central Japan, display typical metamorphic fluid-enhanced isotopic zonations. Isotopic profiles obtained from detailed microscale analyses perpendicular to the chemical reaction front in calcite marble show that diffusion-enhanced isotopic exchange may control these profiles. Carbon and oxygen isotopic behaviour in grain boundaries is remarkably different. Oxygen isotopic troughs (¹⁸O depleted rims) around the calcite-grain boundaries are widely observed in this contact aureole, demonstrating that diffusion of oxygen in calcite grain boundary dominates over lattice diffusion in calcite. In contrast, no difference is observed in carbon isotopic profiles obtained from grain cores and rims. There is thus no specific role of the grain boundary for diffusion of carbonic species in the metamorphic fluid during transportation. Carbon chemical species such as CO₂ and CO₃ ions in metamorphic fluid migrate mainly through lattice diffusion. The carbon and oxygen isotope profiles may be modelled by diffusion into a semi-infinite medium. Empirically lattice diffusion of oxygen isotopes is almost six times faster than that of carbon isotopes, and oxygen grain-boundary diffusion is ten times faster than oxygen lattice diffusion. Oxygen isotopic results around the wollastonite vein indicate that migration of the metamorphic fluid into calcite marble was small and was parallel to the aquifer. From the stability of wollastonite and the attainment of oxygen isotopic equilibrium, we suggest that diffusion of oxygen occurred through an aqueous fluid phase. The timescale of formation of the oxygen isotopic profile around the wollastonite vein is calculated to be about 0.76 × 10⁶ years using the experimentally determined diffusion constant. Received: 14 January 1997 / Accepted: 23 April 1998     

Stability of goaf-side entry driving in 800-m-deep island longwall coal face in underground coal mine

Goaf-side entry driving in underground coal mines could greatly improve coal recovery rates. However, it becomes more difficult to maintain stability, especially in deep coal mines. Pillar width plays a pivotal role in the stability of goaf-side entry driving. To obtain a reasonable and appropriate narrow pillar width, theoretical calculations of the widths of mining-damaged zone and limit equilibrium zone in the pillar are derived according to limit equilibrium theory. Based on the stability issues of goaf-side entry driving in the first island longwall coal face (LCF) at a depth of 800 m below the surface in Guqiao Coal Mine in China, a numerical model is established by FLAC software to analyze the stability of the surrounding rock of goaf-side entry driving during excavation, using various coal pillar widths and support schemes. The results obtained from theoretical calculations, numerical simulation, and engineering practice indicate that an 8-m-wide coal pillar is relatively reasonable, appropriate, and feasible. Field measurements show that deformations of the surrounding rock could be efficiently controlled 31 days after the support schemes were implemented in goaf-side entry driving with an 8-m-wide narrow pillar along the adjacent goaf side with a compaction duration of 10 months. The mining influence range of the overlying LCF on the stability of goaf-side entry driving is found to be the area from 50 m ahead of the LCF to 70 m behind the LCF as it passes over the measurement point.     

Reflection and breaking of internal waves on a sloping beach

The reflection and breaking of internal waves on a sloping beach were studied in a small wavetank filled with water and petroleum. The dependence of the reflection coefficient of the internal waves on wave steepness and on beach slope is found to be very similar to that of surface waves. The reflection coefficient is small for the very gentle slope, increases rapidly as the slope increases, and becomes almost constant for the steep slope. The reflection coefficient decreases with increase of the wave steepness. Also, the transition slope at which the coefficient curve has the maximum gradient increases with increase of the wave steepness. Breaking pattern of the internal waves is classified into four types; breaking, semi-breaking, wrinkle-generating, and non-breaking. Their dependence on beach slope and wave steepness is examined. The regular sequence of the four breaking types from breaking to non-breaking is observed with decrease of wave steepness or with increase of beach slope.     

The application of δ13C and C/N ratios as indicators of organic carbon sources and paleoenvironmental change of the mangrove ecosystem from Ba Lat Estuary, Red River, Vietnam

In this study, two sediment cores (~70 cm) were collected from separate mangrove forests straddling the Ba Lat Estuary, Red River of northern Vietnam, to examine the origins of sedimentary organic carbon (SOC) and reconstruct the paleoenvironment. In addition, mangrove leaves and particulate organic matter were collected and measured for δ¹³C to trace the origins of SOC. The cores were analyzed by high-resolution sections for δ¹³C, TOC, C/N ratios, sediment grain size, water content, and porosity, with values of δ¹³C, TOC, and C/N ratios ranging from −28.19 to −22.5‰, 2.14–30.94 mg/g, and 10.29–18.32, respectively. The δ¹³C and TOC relationship indicated that there were some small residual effects of diagenetic processes on TOC and δ¹³C values in mangrove sediments. However, the shifts of δ¹³C and C/N ratios from the bottom to the surface sediment of the cores explained the change in organic matter sources, with values of C/N > 12 and δ¹³C < −25‰, and C/N < 12 and δ¹³C > −25‰ indicated terrestrial (e.g., mangrove litter) and marine phytoplankton sources, respectively. The covarying δ¹³C, C/N ratios, and sediment grain sizes during the past 100 years in sediment cores showed that the paleoenvironment may be reconstructed into three environments (subtidal, tidal flat, and intertidal mangrove). General trends in δ¹³C and C/N followed a gradual increase in the C/N ratio and a concomitant decrease in δ¹³C from the subtidal, through to tidal flat, and to the intertidal mangrove. δ¹³C and C/N ratios are therefore effective in measuring the continuum of environmental change in mangrove ecosystem.     

Near-Infrared Colors of the Binary Kuiper Belt Object 1998 WW 31

We have measured near-infrared colorsof the binary Kuiper Belt object (KBO)1998 WW₃₁ using the Subaru Telescope withadaptive optics. The satellite was detectednear its perigee and apogee(0.18“ and 1.2” apart from the primary).The primary and the satellite have similar H–Kcolors, while the satellite is redder thanthe primary in J–H. Combined with the Rband magnitude previously published byVeillet et al., 2002, the color of the primaryis consistent with that of optically red KBOs. Thesatellite's R-, J-, H-colors suggest thepresence of ～1 μm absorption band dueto rock-forming minerals. If the surface of thesatellite is mainly composed by olivine, thesatellite's albedo is higher value than the canonicallyassumed value of 4%.     

Investigation on the Performance of Pipe Roof Method Adjacent to the Underground Construction

In this paper, the behaviour of the pipe roof method with different pipe roofs disposition schemes including the pipe roof gate system and L-shaped system is discussed in terms of ground settlement reduction in the condition of underground space construction adjacent to the existing structure by using numerical simulation method. Considering the construction sequences of parallel underground tunnels with rectangular cross sections, the appropriate parameters and ground response characteristics of the corresponding pipe roof methods are evaluated by the ground surface displacement. The results indicated that the construction impacts from new buildings can be reduced by the pipe roof method. However, the theoretical performance of pipe roofs is highly dependent on the spacing between two structures. Generally, the L-shaped system is more effective in case of the distance (D) that is less than or equal to 1/2 width of box culvert (R) under the condition of a new structure constructed nearby the existing building. When two structures are constructed simultaneously, the excavation and the construction of structures influence each other reciprocally. The conclusions could provide a reference for the pipe roof method with the application scenario of adjacent building protection.