The application of δ13C and C/N ratios as indicators of organic carbon sources and paleoenvironmental change of the mangrove ecosystem from Ba Lat Estuary, Red River, Vietnam

In this study, two sediment cores (~70 cm) were collected from separate mangrove forests straddling the Ba Lat Estuary, Red River of northern Vietnam, to examine the origins of sedimentary organic carbon (SOC) and reconstruct the paleoenvironment. In addition, mangrove leaves and particulate organic matter were collected and measured for δ¹³C to trace the origins of SOC. The cores were analyzed by high-resolution sections for δ¹³C, TOC, C/N ratios, sediment grain size, water content, and porosity, with values of δ¹³C, TOC, and C/N ratios ranging from −28.19 to −22.5‰, 2.14–30.94 mg/g, and 10.29–18.32, respectively. The δ¹³C and TOC relationship indicated that there were some small residual effects of diagenetic processes on TOC and δ¹³C values in mangrove sediments. However, the shifts of δ¹³C and C/N ratios from the bottom to the surface sediment of the cores explained the change in organic matter sources, with values of C/N > 12 and δ¹³C < −25‰, and C/N < 12 and δ¹³C > −25‰ indicated terrestrial (e.g., mangrove litter) and marine phytoplankton sources, respectively. The covarying δ¹³C, C/N ratios, and sediment grain sizes during the past 100 years in sediment cores showed that the paleoenvironment may be reconstructed into three environments (subtidal, tidal flat, and intertidal mangrove). General trends in δ¹³C and C/N followed a gradual increase in the C/N ratio and a concomitant decrease in δ¹³C from the subtidal, through to tidal flat, and to the intertidal mangrove. δ¹³C and C/N ratios are therefore effective in measuring the continuum of environmental change in mangrove ecosystem.     

Adsorption Characteristics of Reactive Black 5 from Aqueous Solution onto Chitosan

Adsorption of reactive black 5 (RB5) from aqueous solution onto chitosan was investigated in a batch system. The effects of solution pH, initial dye concentration, and temperature were studied. Adsorption data obtained from different batch experiments were modeled using both pseudo first‐ and second‐order kinetic equations. The equilibrium adsorption data were fitted to the Freundlich, Tempkin, and Langmuir isotherms over a dye concentration range of 45–100 µmol/L. The best results were achieved with the pseudo second‐order kinetic and Langmuir isotherm equilibrium models, respectively. The equilibrium adsorption capacity (q_e) was increased with increasing the initial dye concentration and solution temperature, and decreasing solution pH. The chitosan flakes for the adsorption of the dye was regenerated efficiently through the alkaline solution and was then reused for dye removal. The activation energy (E_a) of sorption kinetics was estimated to be 13.88 kJ/mol. Thermodynamic parameters such as changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) were evaluated by applying the van't Hoff equation. The thermodynamics of reactive dye adsorption by chitosan indicates its spontaneous and endothermic nature.     

Pacific climate variability and the possible impact on global surface CO2 flux

Background  

Climate variability modifies both oceanic and terrestrial surface CO2 flux. Using observed/assimilated data sets, earlier studies have shown that tropical oceanic climate variability has strong impacts on the land surface temperature and soil moisture, and that there is a negative correlation between the oceanic and terrestrial CO2 fluxes. However, these data sets only cover less than the most recent 20 years and are insufficient for identifying decadal and longer periodic variabilities. To investigate possible impacts of interannual to interdecadal climate variability on CO2 flux exchange, the last 125 years of an earth system model (ESM) control run are examined.     

http://www.sciencedirect.com/science/article/pii/S1674987112001302

We present relative sea level （RSL） curves in Antarctica derived from glacial isostatic adjustment （GIA）predictions based on the melting scenarios of the Antarctic ice sheet since the Last Glacial Maximum （LGM）given in previous works.Simultaneously,Holocene-age RSL observations obtained at the raised beaches along the coast of Antarctica are shown to be in agreement with the GIA predictions.The differences from previously published ice-loading models regarding the spatial distribution and total mass change of the melted ice are significant.These models were also derived from GIA modelling; the variations can be attributed to the lack of geological and geographical evidence regarding the history of crustal movement due to ice sheet evolution.Next,we summarise the previously published ice load models and demonstrate the RSL curves based on combinations of different ice and earth models.The RSL curves calculated by GIA models indicate that the model dependence of both the ice and earth models is significantly large at several sites where RSL observations were obtained.In particular,GIA predictions based on the thin lithospheric thickness show the spatial distributions that are dependent on the melted ice thickness at each sites.These characteristics result from the short-wavelength deformation of the Earth.However,our predictions strongly suggest that it is possible to find the average ice model despite the use of the different models of lithospheric thickness.By sea level and crustal movement observations,we can deduce the geometry of the post-LGM ice sheets in detail and remove the GIA contribution from the crustal deformation and gravity change observed by space geodetic techniques,such as GPS and GRACE,for the estimation of the Antarctic ice mass change associated with recent global warming.     

Magma discharge variations during the 2011 eruptions of Shinmoe-dake volcano, Japan, revealed by geodetic and satellite observations

We present precise geodetic and satellite observation-based estimations of the erupted volume and discharge rate of magma during the 2011 eruptions of Kirishima-Shinmoe-dake volcano, Japan. During these events, the type and intensity of eruption drastically changed within a week, with three major sub-Plinian eruptions on January 26 and 27, and a continuous lava extrusion from January 29 to 31. In response to each eruptive event, borehole-type tiltmeters detected deflation of a magma chamber caused by migration of magma to the surface. These measurements enabled us to estimate the geodetic volume change in the magma chamber caused by each eruptive event. Erupted volumes and discharge rates were constrained during lava extrusion using synthetic aperture radar satellite imaging of lava accumulation inside the summit crater. Combining the geodetic volume change and the volume of lava extrusion enabled the determination of the erupted volume and discharge rate during each sub-Plinian event. These precise estimates provide important information about magma storage conditions in magma chambers and eruption column dynamics, and indicate that the Shinmoe-dake eruptions occurred in a critical state between explosive and effusive eruption.     

Field measurements of absolute gravity in East Antarctica

Abstract This paper reports the results of field-based absolute gravity measurements aimed at detecting gravity change and crustal displacement caused by glacial isostatic adjustment. The project was initiated within the framework of the 53rd Japanese Antarctic Research Expedition （JARE53）. Absolute gravity measurements, together with GPS measurements, were planned at several outcrops along the Prince Olav Coast and S6ya Coast of East Antarctica, including at Syowa Station. Since the icebreaker Shirase （AGB 5003） was unable to moor alongside Syowa Station, operations were somewhat restricted during JARE53. However, despite this setback, we were able to complete measurements at two sites： Syowa Station and Langhovde. The absolute gravity value at the Syowa Station IAGBN （A） site, observed using an FG-5 absolute gravimeter （serial number 210; FG-5 #210）, was 982 524 322.7＋0.1 ktGal, and the gravity change rate at the beginning of 2012 was -0.26 gGal.a-1. An absolute gravity value of 982 535 584.2~0.7 ktGal was obtained using a portable A-10 absolute gravimeter （serial number 017; A-10 #017） at the newly located site AGS01 in Langhovde.     

Tectonic reconstruction of batholith formation based on the spatiotemporal distribution of Cretaceous–Paleogene granitic rocks in southwestern Japan

The spatiotemporal distribution of Cretaceous–Paleogene granitic rocks in southwestern Japan is investigated to understand the origin of the granitic batholith belt and to reconstruct the tectonic setting of emplacement. New U–Pb zircon ages for 92 samples collected from a region measuring 50 km (E–W) by 200 km (N–S) reveals a stepwise northward younging of granitic rocks aged between 95 and 30 Ma with an age‐data gap between 60 and 48 Ma. Based on the spatiotemporal distribution of granite ages, we examine two plausible models to explain the pattern of magmatic activity: (i) subduction of a segmented spreading ridge and subsequent slab melting (ridge‐subduction model), and (ii) subduction with a temporally variable subduction angle and corresponding spatial distribution of normal arc magmatism (subduction angle model). We optimize the model parameters to fit the observed magmatism in time and space, and compare the best‐fit models. As to ridge subduction model, the best‐fit solution indicates that the spreading ridge started to subduct at approximately 100 Ma, and involved a 45‐km‐wide section of the ridge segment, a subduction obliquity of 30°, and a slow migration velocity (～1.6 cm/y) of the ridge. These values are within the ranges of velocities observed for present‐day ridge subduction at the Chile trench. On the other hand, the best‐fit solution of subduction angle model indicates that the subduction angle decreases stepwise from 37° at 95 Ma, 32° at 87 Ma, 22° at 72 Ma, to 20° at 65 Ma, shifting magmatic region towards the continental side. These results and comparison, together with constraints on the geometry of the tectonic setting provided by previous studies, suggest that the ridge subduction model better explains the limited duration of magmatism, although both models broadly fit the data and cannot be ruled out.     

Comparison of different methods for estimating soil surface evaporation in a bare field

In this paper, three methods for estimating soil evaporation in a bare field were evaluated: evaporation ratio method (k ratio), complementary relationship and bulk equation. Micro-lysimeters were used to measure the actual evaporation for validation of the three methods. For the k ratio method, pan evaporation was used as the reference evaporation instead of the value obtained from the Penman–Monteith equation. This result is important for areas where meteorological data are unavailable. The results showed that, for daytime evaporation, the k ratio and bulk equation produced a good fit with the observation data, while the complementary relationship generated a larger deviation from the measured data. We recommend that the k ratio method and bulk equation could be used to calculate daytime soil evaporation with high accuracy when soil water content and pan evaporation data or meteorological data are available, while the complementary relationship could be used for a rough estimation when pan evaporation is available. All the methods could be applied to calculate cumulative evaporation.