The mobility of thorium in natural waters at low temperatures

Thermodynamic properties of 32 dissolved thorium species and 9 thorium-bearing solid phases have been collected from the literature, critically evaluated and estimated where necessary for 25°C and 1 atm pressure. Although the data are incomplete, especially for thorium minerals and organic complexes, some tentative conclusions can be drawn. Dissolved thorium is almost invariably complexed in natural waters. For example, based on ligand concentrations typical of ground water (ΣCl = 10 ppm, ΣF = 0.3 ppm, ΣSO₄ = 100 ppm, andΣPO₄ = 0.1 ppm), the predominant thorium species are Th(SO₄)⁰₂, ThF²⁺₂, and Th(HPO₄)₂⁰below pH ≈ 4.5; Th(HPO₄)^2?₃ from about pH 4.5 to 7.5; and Th(OH)⁰₄ above pH 7.5. Based on stability constants for thorium citrate, oxalate and EDTA complexes, it seems likely that organic complexes predominate over inorganic complexes of thorium in organic-rich stream waters, swamp waters, soil horizons, and waterlogged recent sediments. The thorium dissolved in seawater is probably present in organic complexes and as Th(OH)⁰₄. The tendency for thorium to form strong complexes enhances its potential for transport in natural waters by many orders of magnitude below pH 7 in the case of inorganic complexing, and below about pH 8 when organic complexing is important. The existence of complexes in addition to those formed with hydroxyl, is apparent from the fact that measured dissolved thorium in fresh surface waters (pH values generally 5–8) usually ranges from about 0.01 to 1 ppb and in surface seawater (pH = 8.1) is about 0.00064 ppb. This may be contrasted with the computed solubility of thorianite in pure water which is only 0.00001 ppb Th as Th(OH)⁰₄ above pH 5. Although complexing increases the solubility of thorium-bearing heavy minerals below pH 8, maximum thorium concentrations in natural waters are probably limited in general by the paucity and slow solution rate of these minerals and by sorption processes, rather than by mineral-solution equilibria.     

Decoupled PD set-point controller for underwater vehicles

A set-point controller for autonomous underwater vehicles (AUVs) is proposed in this paper. The controller is expressed in transformed equations of motion with a diagonal inertia matrix. It takes into account the dynamics of the system and it can be applied for fully actuated AUVs. The stability of the designed control law is demonstrated by means of a Lyapunov-based argument. Some advantages arising from the use of the controller are considered too. The performance of the proposed controller is validated via simulation on a 6-DOF underwater vehicle.     

Temporal, geomagnetic and related attributes of kimberlite magmatism at Ekati, Northwest Territories, Canada

This paper outlines the development of a multi-disciplinary strategy to focus exploration for economic kimberlites on the Ekati property. High-resolution aeromagnetic data provide an over-arching spatial and magnetostratigraphic framework for exploration and kimberlite discovery at Ekati, and hence also for this investigation. The temporal, geomagnetic, spatial and related attributes of kimberlites with variable diamond content have been constrained by judiciously augmenting the information gathered during routine exploration with detailed, laboratory-based or field-based investigations. The natural remanent magnetisation of 36 Ekati kimberlites has been correlated with their age as determined by isotopic dating techniques, and placed in the context of a well-constrained geomagnetic polarity timescale. Kimberlite magmatism occurred over the period 75 to 45 Ma, in at least five temporally discrete intrusive episodes. Based on current evidence, the older kimberlites (75 to 59 Ma) have low diamond contents and are distributed throughout the property. Younger kimberlites (56 to 45 Ma) have moderate to high diamond contents and occur in three distinct intrusive corridors with NNE to NE orientations. Economic kimberlite pipes erupted at 55.4±0.4 Ma along the A154-Lynx intrusive corridor, which is 7 km wide and oriented at 015°, and at 53.2±0.3 Ma along the Panda intrusive corridor, which is 1 km wide and oriented at 038°. The intrusion ages straddle a paleopole reversal at Chron C24n, consistent with the observation that the older economic kimberlites present as aeromagnetic “low” anomalies while the younger economic pipes are characterised as aeromagnetic “highs”. The aeromagnetic responses for these kimberlites are generally muted because they contain volcaniclastic rock types with low magnetic susceptibility. Kimberlites throughout the Ekati property carry a primary natural magnetic remanence (NRM) vector in Ti-bearing groundmass magnetite, and it dominates over vectors related to induced magnetisation. Magnetostratigraphic correlation of Ekati kimberlites may therefore present a powerful adjunct to existing exploration techniques, mainly because the diamond content of Ekati kimberlites apparently is related more to the age of eruption than to any other parameter investigated in this work.     

Liver lesions in winter flounder (Pseudopleuronectes americanus) from Jamaica Bay,New York: Indications of environmental degradation

Liver sections of winter flounder (Pseudopleuronectes americanus) collected from Jamaica Bay and Shinnecock Bay, New York, in 1989, were examined microscopically to determine the pervasiveness of liver lesions observed previously in Jamaica Bay winter flounder. Neoplastic lesions were not detected in fish from Jamaica Bay or the Shinnecock Bay reference site. Twenty-two percent of Jamaica Bay winter flounder examined (n=103) had unusual vacuolization of hepatocytes and biliary pre-ductal and ductal cells (referred to hereafter as the vacuolated cell lesion). The lesion, identical to that found in 25% of Jamaica Bay winter flounder examined in 1988, has previously been identified in fishes taken from highly polluted regions of the Atlantic coast (e.g., Boston Harbor, Massachusetts, and Black Rock Harbor, Connecticut). Prevalence of the vacuolated cell lesion in winter flounder from Jamaica Bay was significantly greater (p<0.0001) than in 102 specimens collected from Shinnecock Bay. Current scientific literature indicates vacuolated hepatocytes and cholangiocytes are chronically injured and that the extent of their deformity is consistent with the action of a hepatotoxicant. The high prevalence of vacuolated hepatocytes in Jamaica Bay winter flounder and absence of the lesion in flounder from reference sites strongly supports the hypothesis that this impairment is a manifestation of a toxic condition in at least some portions of Jamaica Bay.     

Modelling of a medium-term dynamics in a shallow tidal sea, based on combined physical and neural network methods

The paper presents an approach towards a medium-term (decades) modelling of water levels and currents in a shallow tidal sea by means of combined hydrodynamic and neural network models. The two-dimensional version of the hydrodynamic model Delft3D, forced with realistic water level and wind fields, is used to produce a two-year-database of water levels and currents in the study area. The linear principal component analysis (PCA) of the results is performed to reveal dominating spatial patterns in the analyzed dataset and to significantly reduce the dimensionality of the data. It is shown that only a few principal components (PCs) are necessary to reconstruct the data with high accuracy (over 95% of the original variance). Feed-forward neural networks are set up and trained to effectively simulate the leading PCs based on water level and wind speed and direction time series in a single, arbitrarily chosen point in the study area. Assuming that the spatial modes resulting from the PCA are ‘universally’ applicable to the data from time periods not modelled with Delft3D, the trained neural networks can be used to very effectively and reliably simulate temporal and spatial variability of water levels and currents in the study area. The approach is shown to be able to accurately reproduce statistical distribution of water levels and currents in various locations inside the study area and thus can be viewed as a reliable complementary tool e.g., for computationally expensive hydrodynamic modelling. Finally, a detailed analysis of the leading PCs is performed to estimate the role of tidal forcing and wind (including its seasonal and annual variability) in shaping the water level and current climate in the study area.     

Light scattering in cometary dust comae

Detailed single and multiple scattering calculations were carried out for a spherically symmetric cometary atmosphere irradiated by a plane parallel source. Using simplifying assumptions in the single scattering approximation, analytical expressions were derived for the total flux impinging the cometary nucleus, which was shown to be a decreasing function of the coma opacity. Moreover, while highly anisotropic phase functions resulted in more light reaching the nucleus than was the case for isotropic phase functions, the net energy flux at the nucleus surface was still found to be smaller in the presence of a coma than in the no coma case. This increased flux due to the anisotropic phase functions was attributed mostly to the effect of directional scattering in the forward Sun-comet axis. The isotropic multiply scattered flux at the surface was found tobe an increasing function of the opacity, , for 2.5. At larger values of , the maximum in the downward directed scattered flux was still seen to increase, but occurred at a height of several radii above the nucleus, resulting in a reduction at the surface. On the other hand, the total flux at the surface was again shown to be a decreasing function of and always less than in the no coma case. Finally, on comparing the multiply scattered flux with that obtained in the plane parallel approximation, it was quite apparent that except in the vicinity of the Sun-comet axis, the plane parallel geometry tends to underestimate the degree of scattering.NRC Resident Research Associate.     

Sediment segregation by biodiffusing bivalves

The selective processing of sediment fractions (sand and mud; >63 μm and ≤63 μm median grain size) by macrofauna was assessed using two size classes of inert, UV-fluorescent sediment fraction tracers (luminophores). The luminophores were applied to the sediment surface in 16 m² replicated plots, defaunated and control, and left to be reworked by infauna for 32 days. As the macrofaunal assemblage in the ambient sediment and the control plots was dominated by the common cockle Cerastoderma edule, this species was used in an additional mesocosm experiment. The diversity, abundance and biomass of the defaunated macrobenthic assemblage did not return to control values within the experimental period. Both erosion threshold and bed elevation increased in the defaunated plots as a response to the absence of macrofauna and an increase in microphytobenthos growth. In the absence of macrobenthos, we observed an accretion of 7 mm sediment, containing ca. 60% mud. Image analysis of the vertical distribution of the different luminophore size classes showed that the cockles preferentially mobilised fine material from the sediment, thereby rendering it less muddy and effectively increasing the sand:mud ratio. Luminophore profiles and budgets of the mesocosm experiment under “no waves–no current” conditions support the field data very well.     

Dictators and their capital cities: Moscow and Berlin in the 1930s

Stalin and Hitler planned major changes in the townscapes of their capital cities. These plans were part of their effort to install highly mobilized despotic regimes that needed a wide-ranging set of symbols to focus allegiance and to impress awe. These plans remained to some extent paper exercises but part of it left significant traces in the contemporary cities, particularly in Moscow. The intended changes showed similarities in their megalomania expressed in plans for a gigantic dome surrounded by a huge public square in the core of the city. There were also differences as regards the type of symbols used due to both dictotors' different roles within their regimes, the degree of didactic intent due to the nature of the commanding ideologies and the level of modernization of both countries, and the diverging versions of antimodernist building style (which they shared with many others elsewhere at the time).