Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO4 and coexisting olivine: Implications for mantle evolution and dynamics

Wadsleyite (β-(Mg,Fe)₂SiO₄) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm^?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm^?1. OH concentrations range from 10000–65000 H/10⁶ Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H₂O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/10⁶ Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H₂ or H₂O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.     

Pahoehoe and aa in Hawaii: volumetric flow rate controls the lava structure

The historical records of Kilauea and Mauna Loa volcanoes reveal that the rough-surfaced variety of basalt lava called aa forms when lava flows at a high volumetric rate (>5–10 m³/s), and the smooth-surfaced variety called pahoehoe forms at a low volumetric rate (<5–10 m³/s). This relationship is well illustrated by the 1983–1990 and 1969–1974 eruptions of Kilauea and the recent eruptions of Mauna Loa. It is also illustrated by the eruptions that produced the remarkable paired flows of Mauna Loa, in which aa formed during an initial short period of high discharge rate (associated with high fountaining) and was followed by the eruption of pahoehoe over a sustained period at a low discharge rate (with little or no fountaining). The finest examples of paired lava flows are those of 1859 and 1880–1881. We attribute aa formation to rapid and concentrated flow in open channels. There, rapid heat loss causes an increase in viscosity to a threshold value (that varies depending on the actual flow velocity) at which, when surface crust is torn by differential flow, the underlying lava is unable to move sufficiently fast to heal the tear. We attribute pahoehoe formation to the flowage of lava at a low volumetric rate, commonly in tubes that minimize heat loss. Flow units of pahoehoe are small (usually <1 m thick), move slowly, develop a chilled skin, and become virtually static before the viscosity has risen, to the threshold value. We infer that the high-discharge-rate eruptions that generate aa flows result from the rapid emptying of major or subsidiary magma chambers. Rapid near-surface vesiculation of gas-rich magma leads to eruptions with high discharge rates, high lava fountains, and fast-moving channelized flows. We also infer that long periods of sustained flow at a low discharge rate, which favor pahoehoe, result from the development of a free and unimpeded pathway from the deep plumbing system of the volcano and the separation of gases from the magma before eruption. Achievement of this condition requires one or more episodes of rapid magma excursion through the rift zone to establish a stable magma pathway.     

Partitioning of siderophile elements in the FeNiS system: 1 bar to 80 kbar

Partition coefficients for Au, Ni, P and Ge between solid FeNi metal and sulfur-bearing metallic liquids have been measured at 7,27 and 80 kbar. To our knowledge, these are the only such data for Au, P and Ge at high pressure. Comparison of our partitioning results to those obtained at 1 bar indicate that only the 80 kbar Ge data differ significantly from the 1-bar experiments. Thus, many low-pressure partitioning experiments in the FeNiSP system may have applicability to the greater portion of the Earth's upper mantle or, alternatively, the entire mantle of Mars.     

THE NEW DECADE: DIGITS AND DIVERSITY

The President of the Photogrammetric Society, Mr. I Newton, chaired a panel discussion concerned with those developments in photogrammetry which may take place during the 1990s.     

A numerical investigation of the JASIN atmospheric boundary layer

A numerical model of the cloudy marine boundary layer is described and used to investigate the role of entrainment instability on the developing boundary layer. In general, previous studies have been limited to boundary layers capped by convectively stable inversions or have described only cumulus fields. Here we extend a stratus-capped boundary-layer model to consider the transition to a convectively unstable cloud layer capped by an inversion across which there is a rapid decrease in wet-bulb or equivalent potential temperature. In this case, the inversion is very active and the entrainment rate is determined by the active instability at the interface, in contrast to the mean turbulent motion within the boundary layer.The model is used to interpret the observed boundary layer from the JASIN experiment. Cool, dry air is modified by prolonged passage over increasingly warmer ocean which leads to the development of a convectively unstable cloud layer.     

Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.