The distribution and relative toxic potential of organic chemicals in a PCB contaminated bay

For reliable monitoring of environmental improvement, the PCB contaminated bay Orserumsviken on Sweden's Baltic coast was investigated prior to remediation. We examined PCB congener patterns and the relative toxic potential of PCBs in extracts of three matrices: bottom sediment, settling particulate matter and the dissolved phase (obtained from semi-permeable membrane devices). Congener patterns were similar in all matrices. Three fractions were isolated from the extracts: (1) aliphatic and monocyclic aromatic compounds (MAC-fraction), (2) dicyclic aromatic compounds (DAC-fraction), including PCBs, and (3) polycyclic aromatic compounds (PAC-fraction), including PAHs. Total extracts and fractions were injected into newly fertilised rainbow trout eggs. At larval stage, hepatic EROD activities were quantified. Though high, the PCB contamination could explain only an estimated 1-5% of the total EROD induction. The order of EROD induction potential was: total extract > PAC-fraction > DAC-fraction > MAC-fraction in all matrices, suggesting that in Orserumsviken PACs made a larger contribution to the EROD induction potential than PCBs and other DACs.     

Hydrogen incorporation in orthopyroxene: interaction of different trivalent cations

The incorporation of hydrogen into ferrosilite, Fe-bearing enstatite and orthopyroxene containing different trivalent cations (Cr³⁺ and Al³⁺, Cr³⁺ and Fe³⁺) was investigated experimentally at 25 kbar. Hydrogen concentration was determined by FTIR-spectroscopy on oriented crystal sections and by secondary ion mass spectroscopy, whereas Mößbauer spectroscopy and optical spectroscopy were used to characterise the valence state of Fe in orthopyroxene. Results suggest that hydrogen incorporation in ferrosilite is achieved by a similar mechanism as in pure enstatite. In Cr-bearing samples, however, hydrogen incorporation is reduced by the presence of other trivalent cations by an increased tendency to form Tschermaks substitutions, e.g. Si _T ⁴⁺ + Mg _M1 ²⁺ ? Al _T ³⁺ + Cr _M1 ³⁺ . Thus, hydrogen solubility in natural orthopyroxenes from the Earth’s mantle, containing significant amounts of Cr³⁺, Al³⁺, and Fe³⁺, may be much more limited than expected from their trivalent cation content, as a large fraction of the trivalent cations does not participate in H-incorporating reactions as 2 Mg _M1 ²⁺ ? M _M1 ³⁺ + V_M1 + H _i ⁺ .     

Seep carbonate formation controlled by hydrothermal vent complexes: a case study from the Vøring Basin, the Norwegian Sea

Several hundred hydrothermal vent complexes were formed in the Vøring Basin as a consequence of magmatic sill emplacement in the late Palaeocene. The 6607/12-1 exploration well was drilled through a 220-m-thick sequence of Eocene–Miocene diatomites with carbonate nodules above the apex of one of these vent complexes. Analysed calcites and dolomites from this interval have isotopic signatures typical for methane seep carbonates, with low ¹³C signatures of –28 to –54 PDB. The data suggest that the vent complex acted as a fluid migration pathway for about 50×10⁶ years after its formation, leading to near-surface microbial activity and seep carbonate formation.     

Entrepreneurial advantages and disadvantages of belonging

The article analyzes the influence of religious network structures on entrepreneurial success. Members of the religious community of the Bohras in Tanga, Tanzania, are contrasted with entrepreneurs of other ethnic origins. It is shown that the religious network provides, through a loan scheme, the opportunities to start and run a business successfully. In this respect, the importance of the Islamic business ethic is underlined. Finally, the macro-economic effects of the network are outlined. This revised version was published online in July 2006 with corrections to the Cover Date.     

International fisheries regime effectiveness—Activities and resources of key actors in the Southern Ocean

Many contemporary environmental challenges are truly global and span several organizational and geographical borders. Research on international environmental regimes has, over the last couple of decades, identified several important factors that contribute to a more effective governance of global ecological resources, but few studies have addressed the different roles certain influential individual organizations play in determining regime effectiveness. Here we address this question by studying a relatively successful fishery governance system in the Southern Ocean. By drawing on insights from the research fields of common-pool resource management and international environmental regimes, we demonstrate that organizations engaged in certain combinations of activities, and that have access to certain combinations of resources stand out as important for regime effectiveness. In particular, collaboration with other flag states and being politically well-connected stand out as important explanatory factors. However, access to advanced technology, engagement in public campaigns, and being active in the field are other factors that, in different combinations, also seem to explain organizational importance. Furthermore, governmental and non-governmental organizations tend to perform different sets of activities and possess different resources, thereby complementing each other. Also, organizations doing similar things are often of different types with different mandates and objectives. This could contribute to improved adaptability and responsiveness to change at the larger regime level. Finally, we discuss some potential implications of our results for capacity-building in international environmental governance.