Fluid–rock interactions associated with regional tectonics and basin evolution

An integrated approach consisting of fracture analysis, petrography, carbon, oxygen and strontium‐isotope analyses, as well as fluid‐inclusion micro‐thermometry, led to a better understanding of the evolution of fluid–rock interactions and diagenesis of the Upper Permian to Upper Triassic carbonates of the United Arab Emirates. The deposited carbonates were first marked by extensive early dolomitization. During progressive burial, the carbonates were affected by dolomite recrystallization as well as precipitation of vug and fracture‐filling dolomite, quartz and calcite cements. After considerable burial during the Middle Cretaceous, sub‐vertical north–south oriented fractures (F1) were cemented by dolomite derived from mesosaline to hypersaline fluids. Upon the Late Cretaceous maximum burial and ophiolite obduction, sub‐vertical east–west fractures (F2) were cemented by dolomite (Dc2) and saddle dolomite (Ds) derived from hot, highly saline fluids. Then, minor quartz cement has precipitated in fractures from hydrothermal brines. Fluid‐inclusion analyses of the various diagenetic phases imply the involvement of increasingly hot (200°C) saline brines (20 to 23% NaCl eq.). Through one‐dimensional burial history numerical modelling, the maximum temperatures reached by the studied rocks are estimated to be in the range of 160 to 200°C. Tectonically‐driven flux of hot fluids and associated diagenetic products are interpreted to have initiated during the Late Cretaceous maximum burial and lasted until the Oligocene–Miocene compressional tectonics and related uplift. The circulation of such hydrothermal brines led to partial dissolution of dolomites (Dc2 and Ds) and to precipitation of hydrothermal calcite C1 in new (mainly oriented north–south; F3) and pre‐existing, reactivated fractures. The integration of the obtained data confirms that the diagenetic evolution was controlled primarily by the interplay of the burial thermal evolution of the basin and the regional tectonic history. Hence, this contribution highlights the impacts of regional tectonics and basin history on diagenetic processes, which may subsequently affect reservoir properties.     

Experimental validation of a simplified model for rolling isolation systems

Rolling isolation systems (RISs) protect mission‐critical equipment and valuable property from earthquake hazards by decoupling the dynamic responses of vibration‐sensitive objects from horizontal floor motions. These responses involve the constrained rolling of steel balls between bowl‐shaped surfaces. The light damping of steel balls rolling between steel plates can be augmented by adhering thin rubber sheets to the plates, thereby increasing the rolling resistance and decreasing the displacement demand on the RIS. An assessment of the ability of lightly‐ and heavily‐damped RISs to mitigate the hazard of seismically induced failures requires high‐fidelity models that can adequately capture the systems' intrinsic nonlinear behavior. The simplified model presented in this paper is applicable to RISs with any potential energy function, is amenable to both lightly‐ and heavily‐damped RISs, and is validated through the successful prediction of peak responses for a wide range of disturbance frequencies and intensities. The validated model can therefore be used to compute the spectra of peak floor motions for which displacement demands equal capacity. These spectra are compared with representative floor motion spectra provided by the American Society of Civil Engineers 7–10. The damping provided by rolling between thin viscoelastic sheets increases the allowable floor motion intensity by a factor of 2–3, depending on the period of motion. Acceleration responses of isolation systems with damping supplied in this fashion do not grow with increased damping, even for short‐period excitations. Copyright © 2013 John Wiley & Sons, Ltd.     

Experimental evidence of the double-porosity effects in geomaterials

Double-porosity is an important characteristic of microstructure in a large range of geomaterials. It designs porous media with connected fissures/fractures or aggregated soils. The origin of double-porosity can be natural or/and it can result from mechanical, chemical or biological damage. The presence of double-porosity can significantly affect the behaviour of geomaterials. In this paper we provide an experimental evidence of the double-porosity effects by performing laboratory experiments. Series of tracer dispersion experiments (in saturated and unsaturated steady-state water flow conditions) in a physical model of double-porosity geomaterial were carried out. For the comparative purposes, experiments of the same type were also performed in a singleporosity model medium. The results clearly showed that the double-porosity microstructure leads to the non-Fickian behaviour of the tracer (early breakthrough and long tail) in both saturated and unsaturated cases.     

The value of technology and of its evolution towards a low carbon economy

This paper assesses the economic value associated with the development of various low-carbon technologies in the context of climate stabilization. We analyze the impact of restrictions on the development of specific mitigation technologies, comparing three integrated assessment models used in the RECIPE comparison exercise. Our results indicate that the diversification of the carbon mitigation portfolio is an important determinant of the feasibility of climate policy. Foregoing specific low carbon technologies raises the cost of achieving the climate policy, though at different rates. CCS and renewables are shown to have the highest value, given their flexibility and wide coverage. The costs associated with technology failure are shown to be related to the role that each technology plays in the stabilization scenario, but also to the expectations about their technological progress. In particular, the costs of restriction of mature technologies can be partly compensated by more innovation and technological advancement.     

Distribution and transport of sedimentary trace metals in the tidal portions of the Kennebec/Androscoggin River system, Maine, USA

Previous investigations suggest that contaminant transport from the large Kennebec/Androscoggin watershed is an important large-scale process in mid-coast Maine. To investigate this phenomenon, we determined the concentrations of Cd, Cr, Cu, Ni, Pb, Sn and Zn in the surface sediments of 47 stations in the tidal Kennebec/Androscoggin system. Most stations exhibited elevated metal concentrations. Highest levels were found in the main stem of the system. Distribution patterns lead to the conclusion that metals enter the system from the watershed and are transported to the nearshore Gulf of Maine. The coarse-grained, ebb tide dominated flow prevents the accumulation of contaminants in the estuary. This supports the hypothesis of Larsen and Gaudette (1995) that the Kennebec and Androscoggin watersheds are sources for contaminants observed in the nearshore Gulf of Maine.     

Magnetic resonance sounding applied to aquifer characterization

Magnetic resonance sounding (MRS) is distinguished from other geophysical tools used for ground water investigation by the fact that it measures a magnetic resonance signal generated directly from subsurface water molecules. An alternating current pulse energizes a wire loop on the ground surface and the MRS signal is generated; subsurface water is indicated, with a high degree of reliability, by nonzero amplitude readings. Measurements with varied pulse magnitudes then reveal the depth and thickness of water saturated layers. The hydraulic conductivity of aquifers can also be estimated using boreholes for calibration. MRS can be used for both predicting the yield of water supply wells and for interpolation between boreholes, thereby reducing the number of holes required for hydrogeological modeling. An example of the practical application of MRS combined with two-dimensional electrical imaging, in the Kerbernez and Kerien catchments area of France, demonstrates the efficiency of the technique.     

Analysis of two-decade meteorological and air quality trends in Rome (Italy)

Theoretical and Applied Climatology - The extreme temperature events are a concern in recent years due to climate variability particularly in India as there is an increase in the temperature...