Ar–Ar age determinations of eclogitic clinopyroxene and garnet inclusions in diamonds from the Venetia and Orapa kimberlites

Ar–Ar age measurements are reported for selected eclogitic clinopyroxene and garnet inclusions in Orapa diamonds and clinopyroxene inclusions in Venetia diamonds. Laser drilling of encapsulated clinopyroxene inclusions within Venetia diamonds released a maximum of 3% of the total ⁴⁰Ar, indicating little diffusive transfer and storage of radiogenic ⁴⁰Ar at the diamond–inclusion boundary. Apparent ages obtained during stepped heating of three diamonds are consistent with diamond crystallisation occurring just prior to the kimberlite eruption 520 Ma ago. Stepped heating of three clinopyroxene-bearing Orapa diamonds gave ages of 906–1032 Ma, significantly above the eruption age, but consistent with previously determined isotopic ages. A few higher apparent ages hint at the presence an older generation of Orapa diamonds that formed >2500 Ma ago. Orapa garnets also contain measurable K contents, and record a range of ages between 1000 and 2500 Ma. The old apparent ages and lack of significant interface ⁴⁰Ar released by the laser probe, suggests that pre-eruption radiogenic ⁴⁰Ar and mantle-derived ⁴⁰Ar components are trapped in microinclusions within the pyroxene and garnet inclusions.     

Genesis and evolution of the lithospheric mantle beneath the Buffalo Head Terrane, Alberta (Canada)

Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m². The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.

A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.

Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic ¹⁸⁷Os/¹⁸⁸Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.

A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.

If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events.     

Focal mechanism dependence of static stress triggering of earthquakes

We perform a global statistical investigation into the problem of Coulomb stress triggering of earthquakes by using the Harvard CMT catalogue of shallow earthquakes from 1976 to 2001. We consider ‘earthquake pairs’, i.e., pairs of successive earthquakes occurring near each other with similar focal mechanisms, and address the problem of whether or not the change of the Coulomb failure stress (CFS) produced by the first earthquake of the pair ‘encourages’ the occurrence of the second one. An interesting feature is that such a Coulomb stress-triggering phenomenon has an apparent focal mechanism dependence: for thrust earthquakes, a more evident triggering effect can be observed.     

Erratum: Revisiting the Geometry of a Ternary Diagram with the Half-Taxi Metric

Mathematical Geosciences -     

Viruses as potential regulators of regional brown tide blooms caused by the alga,Aureococcus anophagefferens

Blooms of the brown tide organismAureccoccus anophagefferens have recurred in the coastal bays in New Jersey since 1995 and in the coastal bays of Long Island since 1985. Intracellular viral-like particles (VLPs) were documented during 1999–2000 brown tide blooms in Little Egg Harbor, New Jersey, but it was not determined whether cells were infected during the termination of the bloom. The objective of this study was to determine if VLPs infected and lysed natural populations ofA. anophagefferens in coastal bays of New Jersey and New York in 2002 with the same frequency as in 1999–2000 and especially at the termination of the bloom. Our results confirmed that the highest percentage (37.5%) of VLP-infected cells occurred at the termination of the brown tide bloom in New Jersey in 2002. Intracellular VLPs were present throughout the bloom event. The percentage of visibly infected cells was higher at the beginning of the bloom than during the peak of the bloom. The intracellular VLPs in natural populations ofA. anophagefferens were consistent in size and shape (approximately 140 nm in diameter) and comparable to those in previous studies. Concentrated viral isolates, prepared from waters during brown tide blooms in New York and New Jersey in 2002, infected healthy laboratoryA. anophagefferens cultures in vitro. The viral isolates associated with the highest laboratory viral activity (lysis positive) were concentrated from water samples having the highest viral and bacteria concentrations. The intracellular viruses in these virally infected laboratory cultures ofA. anophagefferens were similar in size and shape to those found in natural populations. The successful isolation of a virus specific toA. anophagefferens from a brown tide bloom in the field, the similarity of ultrastructure of VLPs infecting both natural populations and laboratory infected cultures, and the pattern of VLP infection during bloom activity in combination with the observed high percentage of VLP-infected cells during bloom termination, supports, the hypothesis that viruses may be a major source of mortality for brown tide blooms in regional coastal bays of New Jersey and New York.     

Crustal thickening in an extensional regime: application to the mid-Norwegian Vøring margin

The structure of the mid-Norwegian volcanic Vøring margin at the onset of the Maastrichtian–Paleocene extension phase reflects the cumulative effect of earlier consecutive rifting events. Lateral structural differences present on the margin at that time are a consequence of migration of the location of maximum extension in time between Norway and Greenland. The most important imprints (Moho depth, thermal structure) of these events on the lithosphere are incorporated in a numerical simulation of the final extension phase. We focus on a possible mechanism of formation of the Vøring Marginal High and address the relationship between spatial and temporal evolution of crustal thinning and thickening, uplift of the surface and strength of the lithosphere.It is found that the Vøring Basin formed the strongest part of the margin which explains why the Maastrichtian–Paleocene rift axis was not located here but instead jumped westward with respect to the earlier rift axes locations. The modeling study predicts that local crustal thickening during extension can be expected when large lateral thermal variations are present in the lithosphere at the onset of extension. Negative buoyancy induced by lateral temperature differences increases downwelling adjacent to the rifting zone; convergence of material at the particular part of the margin is mainly taken up by the lower crust. The model shows that during the final phase of extension, the crust in the Vøring Marginal High area was thickened and the surface uplifted. It is likely that this dynamic process and the effects of magmatic intrusions both acted in concert to form the Marginal High.     

Assessing natural and cultural influence on soil in remnant tropical woodlands

Rural Hong Kong contains culturally protected enclaves of remnant woodlands that provide sanctuary for vegetation, wildlife and soil. This study focuses on the influence of natural and cultural factors on soil properties in woodlands with different human activities. At each of the nine selected sites, two pits were dug to collect soil samples for analysis of 24 physical and chemical properties. Analyses of variance between soil attributes and site factors suggest the prominence of woodland size, and important contribution of topography, aspect and parent material. Soil indicators of human impacts and the tenacity of woodland soil towards anthropogenic disturbance were demonstrated.     

Regional three-dimensional gravity modelling of the NE Atlantic margin

A series of three‐dimensional models has been constructed for the structure of the crust and upper mantle over a large region spanning the NE Atlantic passive margin. These incorporate isostatic and flexural principles, together with gravity modelling and integration with seismic interpretations. An initial isostatic model was based on known bathymetric/topographic variations, an estimate of the thickness and density of the sedimentary cover, and upper mantle densities based on thermal modelling. The thickness of the crystalline crust in this model was adjusted to equalise the load at a compensation depth lying below the zone of lateral mantle density variations. Flexural backstripping was used to derive alternative models which tested the effect of varying the strength of the lithosphere during sediment loading. The models were analysed by comparing calculated and observed gravity fields and by calibrating the predicted geometries against independent (primarily seismic) evidence. Further models were generated in which the thickness of the sedimentary layer and the crystalline crust were modified in order to improve the fit to observed gravity anomalies. The potential effects of igneous underplating and variable upper mantle depletion were explored by a series of sensitivity trials. The results provide a new regional lithospheric framework for the margin and a means of setting more detailed, local investigations in their regional context. The flexural modelling suggests lateral variations in the strength of the lithosphere, with much of the margin being relatively weak but areas such as the Porcupine Basin and parts of the Rockall Basin having greater strength. Observed differences between the model Moho and seismic Moho along the continental margin can be interpreted in terms of underplating. A Moho discrepancy to the northwest of Scotland is ascribed to uplift caused by a region of upper mantle with anomalously low density, which may be associated with depletion or with a temperature anomaly.     

Detrital thermochronology – a new perspective on hinterland tectonics, an example from the Andean Amazon Basin, Ecuador

In order to understand the significance of detrital grain ages in sedimentary basins, a new approach is presented. Five characteristic paths, identified by the change in age of detrital grain populations combined with the change in lagtime over time, can be related to different geodynamic settings in the source regions. When lagtime and grain age increase over time, a change in source must be invoked – this is usually a direct response to a geological event. A constant cooling age, a vertical path, associated implicitly with increasing lagtime, implies erosion of materials that had passed through the closure temperature rapidly – exhuming sufficient rock to supply detritus over the time of the path. Constant lagtimes, regardless of the lagtime itself, are indicative of thermochronological stability in the source region. This can involve fast or slow cooling. Finally, decreasing lagtimes support the notion of increasing cooling rates in the source regions over time. A test study is presented from sediments of the northern Ecuadorian Sub‐Andean Zone where geological events had previously been identified using alternative methods. The addition of heavy‐mineral studies increased the precision in the interpretation. At 90 Ma, rapidly decreasing lagtimes point to a phase of tectonic activity. From about 85 Ma until about 60 Ma the lagtimes were approximately zero. This represents a phase of rapid exhumation of the source regions correlating with the previously identified Pallatanga event. An associated increase of metamorphic minerals occurs over this time span, pointing to increased erosion from deeper horizons. At about 70 Ma, the oldest source region, the shield to the east, was switched off. This timing correlates with a change from marine to continental conditions in the basin, a change in palaeocurrent directions from the east to the west, as well as an associated influx of material from the growing Cordillera Real. At about 55 Ma, a change in source is identified by a change in slope of the lagtime curve together with a change in heavy minerals. From 50 to 35 Ma a renewed period of tectonism in the source region is correlated with the docking of the Macuchi terrane which clearly had an effect of increased erosion in the Cordillera Real bringing in higher grade metamorphic minerals. From about 32 Ma onwards the lagtime has been somewhat constant at about 30 Myr. This does not imply, however, a steady‐state environment as it is well known from other geological evidence that there have been other events within this time frame. One must be cautious about over‐interpreting the lagtime as a method to determine steady state in any region. It is a matter of scale.