低分子质量褐藻寡糖的高效酶法制备及其抗氧化活性评价

褐藻寡糖具有多种生理活性,本研究通过酶解与分级条件的优化,获得了低分子质量褐藻寡糖的酶法制备工艺,并在体外模型上评价了不同分子质量组分的抗氧化活性。结果表明,优化后的褐藻寡糖制备条件为:底物浓度1.20%,酶底比4.35 U/mg,酶解时间4 h。进一步采用乙醇沉淀和超滤分离后,获得了重均分子质量分别为0.84、1.40、2.25和34.56 k Da的4种组分,其得率分别为50.82%、5.15%、11.48%和12.00%。各组分均具有一定的还原能力,可有效清除DPPH和羟自由基,其中低分子质量组分A的抗氧化活性最为显著,其清除羟自由基的能力与维生素C相近。     

大兴安岭扎兰屯地区晚奥陶世石英闪长岩体岩石地球化学特征及其地质意义

扎兰屯音河岩体被音河水系分为南、北两部分,研究发现南、北岩体形成年代不同,选取南部岩体(称为二村岩体)进行研究。二村岩体主要由石英闪长岩-英云闪长岩组成,石英闪长岩的LA-ICP-MS锆石U-Pb年龄为444.0±4.6Ma,时代为晚奥陶世。岩石化学组成相对富钠、贫钾,Na2O/K2O值大于1(1.73~3.17),属中钾钙碱性系列。岩石富含轻稀土元素、亏损重稀土元素,富集大离子亲石元素Rb、Ba、K,显著亏损Nb、Ta、P、Ti等高场强元素。矿物组成及岩石地球化学特征指示其为I型花岗岩。岩体的形成时代、构造背景与多宝山岛弧火成岩相似,为区域多宝山岛弧西南向延伸提供了新的制约。     

Effects of Wave–Current Interaction on Salt Intrusion During a Typhoon Event in a Highly Stratified Estuary

Wave–current interaction (WCI) is important in modulating hydrodynamics and water mixing in estuaries, and thereby the transport of water-borne materials. However, the effects of WCI on salt transport and salt intrusion in estuaries during storm events have been rarely examined. In the present study, we use a coupled atmosphere–ocean–wave–sediment transport (COAWST) modeling system to investigate the effects of WCI on salt intrusion in the highly stratified Modaomen Estuary during Typhoon Hagupit (2008). The model is validated by the measured wave, water elevation, and surface salinity data, and several diagnostic model experiments are conducted. WCI increases the storm surge by 0.8 m at the peak surge (25% of the total surge height). The wave-breaking-induced momentum flux and the Stokes drift increase the magnitude of the landward flow by 0.3 m s^?1 (30% of the total landward flow). In addition, the waves increase water mixing by 2–4 times compared with that without waves. Hence, WCI significantly increases the landward advective salt transport and decreases the steady shear transport. The net effect of the WCI is a significant increase of salt import and salt intrusion during the typhoon event. However, in the aftermath of the storm, the imported salt water is rapidly flushed out by the increased river discharge, and the estuary regains its stratification within one day.     

Numerical analysis of effect of baffle configuration on impact force exerted from rock avalanches

In mountainous areas, channelized rock avalanches swarm downslope leading to large impact forces on building structures in residential areas. Arrays of rock avalanche baffles are usually installed in front of rigid barriers to attenuate the flow energy of rock avalanches. However, previous studies have not sufficiently addressed the mechanisms of interaction between the rock avalanches and baffles. In addition, empirical design approaches such as debris flow (Tang et al., Quat Int 250:63–73, 2012), rockfall (Spang and Rautenstrauch, 1237–1243, 1988), snow avalanches (Favier et al., 14:3–15, 2012), and rock avalanches (Manzella and Labiouse, Landslides 10:23–36, 2013), which are applied in natural geo-disasters mitigation cannot met construction requirements. This study presents details of numerical modeling using the discrete element method (DEM) to investigate the effect of the configuration of baffles (number and spacing of baffle columns and rows) on the impact force that rock avalanches exert on baffles. The numerical modeling is firstly conducted to provide insights into the flow interaction between rock avalanches and an array of baffles. Then, a modeling analysis is made to investigate the change pattern of the impact force with respect to baffle configurations. The results demonstrate that three crucial influencing factors (baffle row numbers, baffle column spacing, and baffle row spacing) have close relationship with energy dissipation of baffles. Interestingly, it is found that capacity of energy dissipation of baffles increases with increasing baffle row numbers and baffle row spacing, while it decreases with increasing baffle column spacing. The results obtained from this study are useful for facilitating design of baffles against rock avalanches.     

准格尔煤田黑岱沟露天矿煤中稀土及微量元素的分配规律

对准格尔煤田黑岱沟露天矿煤的主量元素、稀土元素和微量元素含量和矿物组成进行了研究。结果表明,黑岱沟露天矿煤中稀土元素平均含量为248.12×10-6,约为中国煤平均值的2.83倍。LREE平均含量为236.66×10-6,HREE平均含量为11.46×10-6,LREE/HREE平均值为20.81,(La/Yb)N平均值为1.59,表明煤中LREE相对HREE富集。煤中部分稀土元素可能富集在勃姆石和黏土矿物中。稀土元素分配曲线δCeS变化区间(0.89～2.21)和δEuS中度亏损(0.46～0.86),验证了沉积环境在煤层形成演化过程中对煤中稀土元素输入的稳定性。黑岱沟煤层中微量元素明显偏高的有Ga、Pb、Se、Sr、Th 和Zr,这些元素的含量高于中国、中国华北晚古生代和美国煤的算术均值,也高于地壳克拉克值。     

基于小波分析与Mann-Kendall法的岩溶大泉动态研究

研究地下水动态是认识地下水资源的有效手段。根据1956－2013年济南岩溶泉域大气降水及地下水水位动态监测资料,采用小波分析法、Mann-Kendall趋势检验、突变检验法研究了58个水文年泉水位对大气降水的响应,可以看出:（1）大气降水和泉水位呈现出多尺度的变化特征,长时间尺度上两者的变化周期基本相同,变化周期为16年和12年,说明大气降水对泉水位有直接影响;（2）在1956—2013年,济南泉域地下水水位具有0.65 m·（10a）-1的年际显著下降趋势,但降水具有12.65 mm·（10a）-1的不显著上升趋势,说明在人为因素影响下泉水动态的影响因素的权重发生了变化;（3）大气降水在1999年发生突变,1999年之后年降水为增加趋势;而地下水水位突变年份为1967年,1967年以后水位持续降低,2004年以后水位快速上升,泉水位未来趋势应与降水保持一致,呈上升趋势,说明大气降水并非泉水动态的唯一影响因素;（4）通过建立不同时段的多元回归模型,表明近58年来地下水水位的主要影响因素由大气降水到人工开采之间的转换,同时验证了小波分析和Mann-Kendall法研究地下水动态的适宜性和可靠性,也为济南市的保泉提供了参考依据。      

一种选取补偿最小二乘正则化参数的改进方法

为了改进半参数模型补偿最小二乘估计中的正则化参数选取方法,该文设计了3种方案:L-曲线法、虚拟观测法以及该文提出的改进方法以比较正则化参数的优劣。模拟算例表明,该文提出的改进方法可以有效评价正则化参数,得到的参数估值精度更高,是一种较为有效的选取补偿最小二乘最佳正则化参数的方法。     

铀矿勘查中MT数据提取极化信息可行性研究

铀矿勘查中大地电磁测深法(以下简称MT法)的应用十分广泛,而频率域电磁勘探中激电效应切实存在。激电参数作为反映岩、矿石电化学性质的参数,在地质解译过程中常常被认为是金属硫化物的局部富集。为了充分利用铀矿床MT数据辅助地质解译,需要从中提取具有多属性特征的激电参数,能否成功提取该参数一直以来备受关注。文章从激电异常识别和二维反演试算两方面来论述成功提取的可行性。结果表明,仪器能够采集到含矿岩体所产生的激电异常,反演试算结果能够还原理论模型的地下空间展布情况。从而论证了从铀矿床MT数据中提取极化率是可行的。