The Rio Dell Formation: a Plio-Pleistocene basin slope deposit in Northern California

The Rio Dell Formation (Pleistocene and Pliocene), exposed south of Eureka, California, is a prograded sequence of basinal turbidites overlain by basin slope and shelf deposits. The slope deposits studied in the Centerville Beach section accumulated in a steadily shallowing environment delineated by analysis of palaeobathymetrically significant benthonic foraminiferal biofacies in turn suggesting deposition at depths of 1000–100 m. Lower slope deposits interfinger with basinal turbidites derived from the Eel River delta to the north. Slumped blocks of silty mudstone, and associated silt and mud beds, are common. The middle slope deposits are mudstones; coarser sediments bypassed this zone. Mudstones and muddy siltstones alternate on the upper slope. Shallow depressions, probably slump scars, that have been rapidly filled by upper slope sediment are common. The transition to shelf deposits is marked by an increase in sediment grain size, in the degree of oxidation, and in the abundance of megafossils. High percentages of benthonic foraminifera displaced from shelf depths indicate that resedimentation processes are most important on the upper slope.     

Oxygen and Carbon Isotope Studies of Contact Metamorphism of Carbonate Rocks

O¹⁸/O¹⁶ and C¹²/C¹³ ratios have been determined for carbonaterocks and coexisting minerals from two contact metamorphic aureolesat Birch Creek, California and Marble Canyon, Texas. The peliticmetasediments and granitic intrusions of the Birth Creek localitywere also analyzed for their O¹⁸/¹⁶ and D/H ratios. Oxygen andcarbon isotope fractionations in coexisting dolomite and calciteare interrelated but show no obvious correlation with sampledistance from the intrusive contact. Small-scale oxygen isotopicexchange effects between rock units are observed within a fewfeet of the intrusive-country rock contacts and the marble-schistcontacts at Birch Creek. Oxygen isotopic temperatures obtainedfrom quartz—biotite fractionations in the biotite schistsof Birch Creek show a systematic decrease with increasing distanceaway from the intrusive contact; the isotopic contact temperatureis calculated to be 535–45°C. Low O¹⁸/¹⁶ and C¹³/¹²ratiosof the contact metamorphic marbles generally correlate wellwith presence of calc-silicate minerals, indicating that theCO₂ liberated during metamorphic decarbonation reactions isenriched in both O¹⁸and C¹² relative to the carbonates. Materialbalance calculations indicate that the liberated CO₂ is about5 per mille richer in O¹⁸ and about 6 per mille richer in C¹³than coexisting calcite.     

Size Selective Predation by the Asteroid Pisaster ochraceus on the Bivalve Mytilus calif ornianus: A Cost-Benefit Analysis

Abstract. When simultaneously presented with equal numbers of four sizes of clumped Mytilus californianus (20, 35, 55 and 85 mm shell length), Pisaster ochraceus (arm length of 70-110mm R) showed a preference for the medium sizes (35 and 55mm length). Prey-size preference was positively correlated with predator size. Mean prey-digestion times (insertion of the stomach, opening of the valves and digestive period) decreased significantly following fiiing of an artificial gape between the valves of mussels. When presented with different sizes of clumped filed mussels, starfish still chose medium mussels, indicating that stomach insertion, valve opening, and digestion rate may not be important constraints determining size selective predation. Measurements of the force required to dislodge mussels from the substratum and conspecifics showed an increasing exponential relationship with mussel size. Size selective feeding may be an energy maximizing and time minimizing strategy, where energy gained from choosing larger mussels is balanced against disproportionately increased costs in energy and time of removing large mussels from the substratum.     

A combined IR and XRD study of natural well crystalline goethites (α-FeOOH)

Acta Geochimica - Goethite (α-FeOOH) is one of the most abundant minerals on the Earth surface, occurring in temperate, tropical and equatorial climates. Fe in goethite can be substituted by...     

Chemical fractionation of zinc versus cadmium among other metals nickel, copper and lead in the northern North Sea

Concentrations of dissolved Ni, Cu, Zn, Cd and Pb were measured in water samples collected during a cruise with R.V Pelagia (29-6/14-7-1993) in the northern North Sea and N.E. Atlantic Ocean. At least six depths (0–90 m) were sampled with modified Go-Flo samplers from a rubber zodiac. In the study area, the first 25 m were well mixed and stratification occurred below this depth. The local bloom of Emiliania huxleyi hardly affected the trace metals concentration, except for some removal of Cd as seen from its correlation with nitrate. The mean dissolved concentrations were for Ni (3.66 nM), Cu (1.61 nM), Zn (4.5 nM), Cd (48 pM) and Pb (108 pM). These concentrations are among the lowest reported for the North Sea and are of similar magnitude to those found in the eastern North Atlantic at the same latitude. Zn was the only exception with values 10 times higher compared to those in the Atlantic Ocean, suggesting external inputs, mainly atmospheric and possibly from surrounding land masses. The observed ratio Zn:Cd in the North Sea and estuaries is in between the high ratio 600–900 for continental sources and the low ratio 5–10 for oceanic waters. Latter low ratio is consistent with the 21-fold stronger inorganic complexation of Cd in seawater which, in combination with the preferential biological uptake of Zn, may lead to the observed about hundredfold fractionation of Zn versus Cd in the marine system. Other processes may play a role but would need further investigation. The dissolved Pb values tend to be lower than found before in the North Sea, indicating decreasing inventories due to reduced anthropogenic emissions.     

Gold mineralization in the Mazowe area, Harare-Bindura-Shamva greenstone belt, Zimbabwe: II. Genetic relationships deduced from mineralogical, fluid inclusion and stable isotope studies, and the Sm-Nd isotopic composition of scheelites

In the Mazowe area some 40 km NW of Harare in Zimbabwe, gold mineralization is hosted in a variety of lithologies of the Archean Harare-Bindura-Shamva greenstone belt, in structures related to the late Archean regional D2/3 event. Conspicuous mineralzogical differences exist between the mines; the mainly granodiorite-hosted workings at Mazowe mine are on pyrite-rich reefs, mines of the Bernheim group have metabasalt host rocks and are characterized by arsenopyrite-rich ores, and Stori's Golden Shaft and Alice mine, both in metabasalts, work sulfide-poor quartz veins. In contrast to the mineralogical diversity, near-identical fluid inventories were found at the different mines. Both H₂O-CO₂-CH₄ fluids of low salinity, and highly saline fluids are present and are regarded to indicate fluid mixing during the formation of the deposits. Notably, these fluid compositions in the Mazowe gold field markedly contrast to ore fluids “typical” of Archean mesothermal gold deposits on other cratons. Stable isotope compositions of quartz from the various deposits (δ¹⁸O=10.8 to 13.2‰ SMOW), calcite (δ¹⁸O=9.5 to 11.9‰ SMOW and δ¹³C=−3.2 to −8.0‰ PDB), inclusion water (δD=−28 to −40‰ SMOW) and sulfides (δ³⁴S=1.3 to 3.2‰ CDT) are uniform within the range typical for Archean lode gold deposits worldwide. The fluid and stable isotope compositions support the statement that the mineralization in the Mazowe gold field formed from relatively reduced fluids with a “metamorphic” signature during a single event of gold mineralization. Microthermometric data further indicate that the deposits formed in the PT range of 1.65–2.3 kbar and 250–380 °C. Ages obtained by using the Sm/Nd and Rb/Sr isotope systems on scheelites are 2604 ± 84 Ma for the mineralization at Stori's Golden Shaft mine, and 2.40 ± 0.20 Ga for Mazowe mine. The Archean age at Stori's is regarded as close to the true age of gold mineralization in the area, whereas the Proterozoic age at Mazowe mine probably reflects later resetting. Received: 30 September 1998 / Accepted: 17 August 1999     

Platinum group elements and gold in ferromanganese crusts from Afanasiy-Nikitin seamount,equatorial Indian Ocean: Sources and fractionation

The major element relationships in ferromanganese (Fe-Mn) crusts from Afanasiy-Nikitin seamount (ANS), eastern equatorial Indian Ocean, appear to be atypical. High positive correlations (r = 0.99) between Mn/Co and Fe/Co ratios, and lack of correlation of those ratios with Co, Ce, and Ce/Co, indicate that the ANS Fe-Mn crusts are distinct from Pacific seamount Fe-Mn crusts, and reflect region-specific chemical characteristics. The platinum group elements (PGE: Ir, Ru, Rh, Pt, and Pd) and Au in ANS Fe-Mn crusts are derived from seawater and are mainly of terrestrial origin, with a minor cosmogenic component. The Ru/Rh (0.5–2) and Pt/Ru ratios (7–28) are closely comparable to ratios in continental basalts, whereas Pd/Ir ratios exhibit values (<2) similar to CI-chondrite (∼1). The chondrite-normalized PGE patterns are similar to those of igneous rocks, except that Pd is relatively depleted. The water depth of Fe-Mn crust formation appears to have a first-order control on both major element and PGE enrichments. These relationships are defined statistically by significant (r > 0.75) correlations between water depth and Mn/Co, Fe/Co, Ce/Co, Co, and the PGEs. Fractionation of the PGE-Au from seawater during colloidal precipitation of the major-oxide phases is indicated by well-defined linear positive correlations (r > 0.8) of Co and Ce with Ir, Ru, Rh, and Pt; Au/Co with Mn/Co; and by weak or no correlations of Pd with water depth, Co-normalized major-element ratios, and with the other PGE (r < 0.5). The strong enrichment of Pt (up to 1 ppm) relative to the other PGE and its positive correlations with Ce and Co demonstrate a common link for the high concentrations of all three elements, which likely involves an oxidation reaction on the Mn-oxide and Fe-oxyhydroxide surfaces. The documented fractionation of PGE-Au and their positive association with redox sensitive Co and Ce may have applications in reconstructing past-ocean redox conditions and water masses.     

The local impacts of climate change in the Ferlo, Western Sahel

Recent increases in the accuracy of climate models have enhanced the possibilities for analyzing the impacts of climate change on society. This paper explores how the local, economic impacts of climate change can be modeled for a specific eco-region, the Western Sahel. The people in the Sahel are highly dependent on their natural resource base, and these resources are highly vulnerable to climate change, in particular to changes in rainfall. Climate models project substantial changes in rainfall in the Sahel in the coming 50 years, with most models predicting a reduction in rainfall. To connect climate change to changes in ecosystem productivity and local income, we construct an ecological–economic model that incorporates rangeland dynamics, grazing and livestock prices. The model shows that decreased rainfall in the Sahel will considerably reduce local incomes, in particular if combined with increases in rainfall variability. Adaptation to these climate change projections is possible if reductions in rainfall are followed by destocking to reach efficient grazing levels. However, while such a strategy is optimal from the perspective of society, the stocking rate is determined by individual pastoralists that face few incentives to destock.     

THE DRIVING FORCES OF LAND CHANGE IN THE NORTHERN PIEDMONT OF THE UNITED STATES

Driving forces facilitate or inhibit land‐use / land‐cover change. Human driving forces include political, economic, cultural, and social attributes that often change across time and space. Remotely sensed imagery provides regional land‐change data for the Northern Piedmont, an ecoregion of the United States that continued to urbanize after 1970 through conversion of agricultural and forest land covers to developed uses. Eight major driving forces facilitated most of the land conversion; other drivers inhibited or slowed change. A synergistic web of drivers may be more important in understanding land change than individual drivers by themselves.