A combined IR and XRD study of natural well crystalline goethites (α-FeOOH)

Acta Geochimica - Goethite (α-FeOOH) is one of the most abundant minerals on the Earth surface, occurring in temperate, tropical and equatorial climates. Fe in goethite can be substituted by...     

The local impacts of climate change in the Ferlo, Western Sahel

Recent increases in the accuracy of climate models have enhanced the possibilities for analyzing the impacts of climate change on society. This paper explores how the local, economic impacts of climate change can be modeled for a specific eco-region, the Western Sahel. The people in the Sahel are highly dependent on their natural resource base, and these resources are highly vulnerable to climate change, in particular to changes in rainfall. Climate models project substantial changes in rainfall in the Sahel in the coming 50 years, with most models predicting a reduction in rainfall. To connect climate change to changes in ecosystem productivity and local income, we construct an ecological–economic model that incorporates rangeland dynamics, grazing and livestock prices. The model shows that decreased rainfall in the Sahel will considerably reduce local incomes, in particular if combined with increases in rainfall variability. Adaptation to these climate change projections is possible if reductions in rainfall are followed by destocking to reach efficient grazing levels. However, while such a strategy is optimal from the perspective of society, the stocking rate is determined by individual pastoralists that face few incentives to destock.     

Gold mineralization in the Mazowe area, Harare-Bindura-Shamva greenstone belt, Zimbabwe: II. Genetic relationships deduced from mineralogical, fluid inclusion and stable isotope studies, and the Sm-Nd isotopic composition of scheelites

In the Mazowe area some 40 km NW of Harare in Zimbabwe, gold mineralization is hosted in a variety of lithologies of the Archean Harare-Bindura-Shamva greenstone belt, in structures related to the late Archean regional D2/3 event. Conspicuous mineralzogical differences exist between the mines; the mainly granodiorite-hosted workings at Mazowe mine are on pyrite-rich reefs, mines of the Bernheim group have metabasalt host rocks and are characterized by arsenopyrite-rich ores, and Stori's Golden Shaft and Alice mine, both in metabasalts, work sulfide-poor quartz veins. In contrast to the mineralogical diversity, near-identical fluid inventories were found at the different mines. Both H₂O-CO₂-CH₄ fluids of low salinity, and highly saline fluids are present and are regarded to indicate fluid mixing during the formation of the deposits. Notably, these fluid compositions in the Mazowe gold field markedly contrast to ore fluids “typical” of Archean mesothermal gold deposits on other cratons. Stable isotope compositions of quartz from the various deposits (δ¹⁸O=10.8 to 13.2‰ SMOW), calcite (δ¹⁸O=9.5 to 11.9‰ SMOW and δ¹³C=−3.2 to −8.0‰ PDB), inclusion water (δD=−28 to −40‰ SMOW) and sulfides (δ³⁴S=1.3 to 3.2‰ CDT) are uniform within the range typical for Archean lode gold deposits worldwide. The fluid and stable isotope compositions support the statement that the mineralization in the Mazowe gold field formed from relatively reduced fluids with a “metamorphic” signature during a single event of gold mineralization. Microthermometric data further indicate that the deposits formed in the PT range of 1.65–2.3 kbar and 250–380 °C. Ages obtained by using the Sm/Nd and Rb/Sr isotope systems on scheelites are 2604 ± 84 Ma for the mineralization at Stori's Golden Shaft mine, and 2.40 ± 0.20 Ga for Mazowe mine. The Archean age at Stori's is regarded as close to the true age of gold mineralization in the area, whereas the Proterozoic age at Mazowe mine probably reflects later resetting. Received: 30 September 1998 / Accepted: 17 August 1999     

Mineralogy, Petrology, and Magmatic Conditions from the Fish Canyon Tuff, Central San Juan Volcanic Field, Colorado

The Fish Canyon Tuff is one of the largest currently recognizedash-flow tuffs (> 3000 km³). It is a crystal-rich quartzlatite containing about 40 per cent phenocrysts of plagioclase,sanidine, biotite, hornblende, quartz, magnetite, sphene, andilmenite. Pyrrhotite occurs as inclusions in magnetite, sphene,and hornblende. The consistency of mineralogy and whole rockchemistry confirms that the Fish Canyon tuff is remarkably homogeneous.Most chemical variations can be accounted for by phenocryst-matrixfractionation, probably due to glass winnowing during eruptionand emplacement. The composition of the parent magma, correctedfor such winnowing, is very similar to that of calc-alkalinebatholiths such as the Boulder and the Sierra Nevada batholiths. Fe-Ti oxide geothermometers indicate temperatures of 800 ? 30?C for most of the outflow tuff. No evidence for a regular thermalgradient in the magma chamber could be detected. Two feldsparand Fe-Ti oxide equilibria indicate that the magma developedat depths of 25 to 30 km (about 9 kb pressure), and was eruptedwithout time for phenocryst re-equilibration. The reconstructedcomposition of the liquid in equilibrium with the phenocrystsalso suggests a deep source for this ash flow. A late, upperpackage of flow units have mineralogical characteristics whichmay reflect partial re-equilibration in a shallower environment. Oxygen fugacities are moderately high (log fO₂ = — 11.5?0.3) but are similar to those obtained from other continentalcalc-alkaline ash-flow tuffs. The water fugacity is limitedby calculations using biotite equilibria and experimental workrelating to the stability of the phenocryst assemblage. Bestestimates are that water fugacity was 2000 ? 1000 bars. Theactivities of sulphurous gases are estimated at fSO₂ = 2 to4 bars, fso₂ = 150 to 200 bars, fH₂S = 70 to 80 bars. The Fish Canyon Tuff therefore came from a deep, homogeneous,granitic magma body of batholithic proportions. Calculationsof its probable viscosity, density, and size indicate that thesystem should convect with any reasonable thermal gradient.Convective mixing may account for the homogeneity of the parentmagma body.     

Lower Temperature Terminations of the Three-phase Region Plagioclase-Alkali Feldspar-Liquid

Geological and experimental evidence indicate that the three-phasefield, plagioclase-alkalifeldspar-liquid, may terminate in severaldifferent ways. The possible terminations have been developedfrom Schreinemakers' rules governing the disappearance of three-phasefields. In igncous rocks, these different terminations may arisefrom variations in the relative amounts of additional componentsin magmas, or from changes of total pressure, or from structuralchanges that effect the extent of solid solution in feldspar. The three-phase region originates from the intersection of thesolidus and the feldspar solvus. The available evidence regardingthis intersection is reviewed, as is the evidence for the existenceand form of the boundary curve on the feldspar liquidus. Thedata are used to project a series of isobaric polythermal andisobaric isothermal diagrams for each possible termination.Subsequent discussions relate the theoretical arguments to thenatural evidence, suggest the more probable geological environmentsof some of the terminations, and indicate characteristic featuresof each termination. It may be possible to identify the type of termination involvedin the crystallization of some rocks. The necessary data arethe amounts and compositions of both kinds of coexisting feldsparsand of the feldspar components of the coexisting liquid at oneor more stages of the crystallization process. Volcanic rocksare most suitable for such studies. The terminations explain many of the compositional relationshipspossible between feldspar crystals and silicate melt under geologicaland experimental conditions. These compositional relationshipsare fundamental to understanding the crystallization of igneousrocks and the formation of melts by partial fusion. Other geologicalapplications include a simple explanation for some resorbedfeldspars, the separation, correlation, and comparison of porphyriticrock units, interpretation of compositional changes of successivezones of zoned feldspars, and mantling of one feldspar by another.With all types of termination, extensive fractionation yieldsa liquid rich in Or and Ab that may crystallize to alkali feldsparor feldspars.     

Flow properties of turbidity currents in Bute Inlet, British Columbia

Bute Inlet, a fiord along the southwestern coast of British Columbia, Canada, includes a sea-floor sedimentation system 70 km in length which resembles those developed on some large submarine fans. Turbidity currents originate at the head of the flord on the submerged delta fronts of the Homathko and Southgate rivers. They move downslope for about 30 km within a single large incised channel, spill onto a depositional area termed the channel lobe complex, and finally spread out over a low-relief distal splay area that passes 55 km downslope into a flat basin floor. During the present study, turbidity currents in Bute Inlet were studied using sea-floor morphology, bottom sediment distribution, and in-situ instrument packages. The mean velocities of the most recent flows, estimated from surface sediment grain size, has varied between 100–120 cm s^–1 in the incised channel, 20–50 cms^–1 in the channel lobe complex, and < 5 cm s^–1 on the basin floor. Velocities based on channel morphology are poorly constrained but are in the range of 160-425 cm s^–1 in the upper part of the incised channel and 66 cm s^–1 in the lower channel. Calculated flow densities range from 1.049 to 1.028g cm^–3. Turbidity flows monitored in 1986 using submerged instrument packages exceeded 32 m in thickness in the upper part of the incised channel, where the maximum measured velocity was 330 cm s^–1. At the head of the channel lobe complex the maximum velocity had declined to 75 cm s^–1. The density of the monitored flows is estimated at 1.025-1.03g cm^–3. The cored sediments and channel morphology yield estimates of mean flow velocities that are generally greater than those measured by the in-situ instrument packages and estimated from modern surface sediments. The former suggest past flow velocities up to 500 cm s^–1 in the incised channel, about 20 cm s^–1 in spillover deposits along the lower part of the incised channel, and 100-140 cm s^–1 in the distal splay. The contrast between the velocities of modern and past flows suggests that past flows may have been considerably larger and more energetic than those presently occurring in Bute Inlet. The size properties of sediments in the monitored turbidity flows suggest a strong vertical size gradient in the suspended load during transport. The surface and cored sediments fine downslope from the channel lobe complex to distal splay area. Distinctive sedimentary sequences are recognized in cores from the spillover lobes, channel lobe complex, distal splay, and basin floor depositional areas. Many individual turbidites grade downslope from massive T_a divisions in the channel lobe complex and probably in the incised channel to T_a divisions overlain by slurried divisions on the distal splay and largely slurried beds on the basin floor. These facies suggest that individual currents commonly evolve from largely cohesionless suspensions in the incised channel and channel lobe complex to dilute cohesive slurries downslope on the distal splay and basin floor. Many flows in Bute Inlet fail to develop a traction state of sedimentation and the resulting turbidites lack well-developed T_b. T_c, and T_d divisions.     

云南瓦渣钨矿区老君山花岗岩体的SHRIMP锆石U-Pb定年、地球化学特征及成因探讨

云南省瓦渣钨矿区位于老君山花岗岩体的东北接触带,属于滇东南-桂西白垩纪钨锡多金属成矿区中的组成部分。该矿床与矿区西部大面积分布的老君山第一期中粗粒二云二长花岗岩在时间和成因上有着密切联系。本文通过SHRIMP锆石U-Pb测年、岩石主量元素、微量元素和稀土元素的系统研究,进而探讨该花岗岩的形成年龄和动力学背景、岩石物质来源以及形成温度和压力。研究表明,与瓦渣钨矿床有关的中粗粒二云二长花岗岩属于高钾钙碱性岩系,为强过铝质S型花岗岩。岩体形成时代为83.3±1.5Ma,属于晚白垩世,形成于岩石圈伸展环境,其源岩为富粘土的泥质来源,其形成温度为875～900℃,压力约为7×108Pa,相当于深度为26km。     

新疆博格达造山带晚古生代构造-岩浆演化过程:火山岩组合及地球化学证据

最近,笔者在博格达山东段北部的西地-伊齐-小红柳峡一带的地质调查中发现,该区发育有大量晚石炭世柳树沟组双峰式火山岩及早二叠世卡拉岗组酸性火山岩建造,但双峰式火山岩性质及成因有别于其南侧七角井早石炭世双峰式火山岩。玄武岩富钠贫钾(K_2O=0.18%～0.45%,Na_2O=2.24%～3.63%),属拉斑系列;TiO_2=1.6%～1.7%,略高于MORB,较高的Al(Al_2O_3=16.2%～16.7%)、高Mg(MgO=8.12%～9.54%,Mg~#=61～64),以及低K_2O/TiO_2和K_2O/P_2O_5比值(分别为0.1～0.27、0.63～1.68),反映了在岩浆演化过程中分离结晶作用不明显;Rb/Sr比值0.01～0.02,Zr/Nb=21.6～39.7,Zr/Y=5.38～7.47,以及不相容元素Ba、Zr、Hf相对略富集、Nb-Ta和Th相对亏损,显示岩石具有板内玄武岩的特点;稀土元素球粒陨石标准化配分图上整体接近于平坦型,(La/Yb)_N=1.8～1.9,Eu无异常至轻微正异常(δEu=1.07～1.12),正ε_(Nd)(t)值(+5.63～+5.89),(~(143)Nd/~(144)Nd)_I=0.512927～0.512944,Th/Yb0.2,Ta/Yb=0.1,表明玄武岩浆源于亏损软流圈地幔,且在演化过程中不曾发生过斜长石的分离结晶作用,并暗示当时的大陆地壳可能由于拉张而变得较薄,玄武岩浆形成后快速上升至地表喷发。双峰式火山岩中的流纹岩Rb-Sr等时线年龄为296±2Ma(1σ),具高Si(SiO_2=76%～80%),富钾贫钠(K_2O=5.1%～5.7%,Na_2O=0.94%～2.03%);低Al(Al_2O_3=7.9%～10.4%);低Ti、Ca和P含量,属高钾钙碱性系列;微量元素Rb、Th、Zr、Hf、K相对富集,Ba、Sr、P、Ti、Nb、Ta为显著亏损;轻稀土元素适度富集且轻、重稀土分馏程度低,(La/Yb)_N=5.1～7.1,(La/Sm)_N=2、(Gd/Yb)_N=1.6～2.2,以及强烈的负Eu异常(δEu=0.17～0.2),(~(87)Sr/~(86)Sr)_I=0.7051～0.7052,δ~(18)O=11.6‰,指示岩石源于地壳物质的部分熔融,源区存在有斜长石残留,形成于大陆裂谷环境。早二叠世末流纹岩(Rb-sr等时线年龄为278±2Ma)具高Si(SiO_2=74%),富钾贫钠(K_2O/Na_2O2),低Al(Al_2O_3=11.0%)以及较低的Ti和P含量的特征,岩石为高钾钙碱性系列;微量元素PM标准化图解上表现为Rb、Ba、Th、U、K、La、Ce不相容元素相对富集,高场强元素Nb、Ta、P、Ti以及Sr为明显的负异常;轻稀土轻度富集,(La/Yb)_N=5～6,(La/Sm)_N=3,(Gd/Yb)_N=1.3～1.4,以及强烈的负Eu异常(δEu=0.31～0.39),(~(87)Sr/~(86)Sr)_I为0.7069,δ~(18)O=11.97‰,指示源于地壳物质部分熔融的产物,形成于伸展垮塌的构造环境。综合研究结果表明,博格达山前身裂谷岩浆作用始于早石炭世,结束于晚石炭世末期,早二叠世末进入后造山伸展的演化阶段。     

Oxygen and Carbon Isotope Studies of Contact Metamorphism of Carbonate Rocks

O¹⁸/O¹⁶ and C¹²/C¹³ ratios have been determined for carbonaterocks and coexisting minerals from two contact metamorphic aureolesat Birch Creek, California and Marble Canyon, Texas. The peliticmetasediments and granitic intrusions of the Birth Creek localitywere also analyzed for their O¹⁸/¹⁶ and D/H ratios. Oxygen andcarbon isotope fractionations in coexisting dolomite and calciteare interrelated but show no obvious correlation with sampledistance from the intrusive contact. Small-scale oxygen isotopicexchange effects between rock units are observed within a fewfeet of the intrusive-country rock contacts and the marble-schistcontacts at Birch Creek. Oxygen isotopic temperatures obtainedfrom quartz—biotite fractionations in the biotite schistsof Birch Creek show a systematic decrease with increasing distanceaway from the intrusive contact; the isotopic contact temperatureis calculated to be 535–45°C. Low O¹⁸/¹⁶ and C¹³/¹²ratiosof the contact metamorphic marbles generally correlate wellwith presence of calc-silicate minerals, indicating that theCO₂ liberated during metamorphic decarbonation reactions isenriched in both O¹⁸and C¹² relative to the carbonates. Materialbalance calculations indicate that the liberated CO₂ is about5 per mille richer in O¹⁸ and about 6 per mille richer in C¹³than coexisting calcite.