The Hekla 1947 tephra in the north of Ireland: regional distribution,concentration and geochemistry

A cryptotephra layer from the eruption of Hekla in 1947 has recently been discovered in Irish peatlands. This tephra layer represents the most recent deposition of volcanic ash in the UK prior to the eruption of Eyjafjallajökull in 2010. Here we examine the concentration and geochemistry of the Hekla 1947 tephra in 14 peat profiles from across Northern Ireland. Electron probe microanalysis of individual tephra shards (n = 91) reveals that the tephra is of dacitic–andesitic geochemistry and is highly similar to the Hekla 1510 tephra, although spheroidal carbonaceous particle profiles can be used for successful discrimination of the two layers. The highest concentrations of Hekla 1947 are found in western sites, probably reflecting the pathway of the ash fall event due to the prevailing wind direction. Comparable tephra concentrations from two cores (1 km apart) from a single bog and from nearby sites may suggest that tephra shard concentrations in peat profiles reflect ash fallout densities across a specific region, rather than site‐specific factors associated with peatlands. This paper firmly establishes Hekla 1947 as a useful chronostratigraphic marker for the twentieth century, although within a restricted zone. Copyright © 2012 John Wiley & Sons, Ltd.     

Volatile (sulphur and chlorine), major,and trace element geochemistry of mafic to intermediate tephras from the Chilean Southern Volcanic Zone (33–43°S)

Here we present the first systematic investigation of volatile geochemistry along the Southern Volcanic Zone (SVZ) of Chile. Holocene olivine-hosted melt inclusions in the most mafic tephras sampled from 16 volcanoes along the volcanic front of the SVZ between 33°S and 43°S were analysed for pre-eruptive sulphur, chlorine, and major element contents. These results are combined with trace element compositions of the host whole rocks. The highest fractionation-corrected gas contents occur in the least-degassed melt inclusions from small monogenetic cones of Los Hornitos, Cabeza de Vaca, and Apagado from both the transitional and the southern-central SVZ, reaching ~3,000 μg/g S and 1,400 μg/g Cl, while the lowest abundances of ~1,100 μg/g S and ~600 μg/g Cl were found in the central SVZ at Volcán Lonquimay, Volcán Llaima, and Volcán Villarrica. Chlorine co-varies with trace element indicators for the degree of melting and/or source enrichment, such that the lowest Cl contents are found in high-degree melts from the most depleted mantle sources. The size of the volcanic edifices correlates inversely with Cl abundances in the melt. This could reflect more extensive degassing during ascent through the complex magma plumbing systems beneath the stratovolcanoes or greater dilution during larger degrees of melting of more depleted sources, or a combination of these factors. Compared to other subduction zones, the SVZ melt inclusions exhibit Cl and S abundances in the same range as most of those from the Central American and those from the Marianas arcs.     

The influence of Fe<Superscript>3+</Superscript> on garnet–orthopyroxene and garnet–olivine geothermometers

Applying Fe²⁺–Mg exchange geothermometers to natural samples may lead to incorrect temperature estimates if significant Fe³⁺ is present. In order to quantify this effect, high-pressure experiments were carried out in a belt apparatus in a natural system close to CFMAS at 5 GPa and 1,100–1,400 °C. The oxygen fugacity in the experiments was at or below the Re–ReO₂ buffer. This is at significantly more oxidized conditions than in previous experiments, and, as consequence, higher Fe³⁺/Fe²⁺ ratios were generated. The Fe³⁺ content of garnet in the experiments was quantified by electron microprobe using the flank method. Making the usual assumption that Fe_total = Fe²⁺, the two-pyroxene thermometer of Brey and Köhler (J Pet 31:1353–1378, 1990) reproduced the experimental temperature to ±35 °C and the garnet–clinopyroxene Fe²⁺–Mg exchange thermometer of Krogh (Contrib Miner Pet 99:44–48, 1988) overestimated the temperatures on average by only 25 °C. On the other hand, application of the garnet–olivine (O’Neill and Wood in Contrib Miner Pet 70:59–70, 1979) and garnet–orthopyroxene (Harley in Contrib Miner Pet 86:359–373, 1984) exchange geothermometers yielded an underestimation in calculated temperatures of >200 °C. However, making explicit accounting for Fe³⁺ in garnet (i.e. using only measured Fe²⁺) leads to a vast improvement in the agreement between calculated and experimental temperatures, generally to within ±70 °C for the garnet–orthopyroxene geothermometer as well as noticeable improvement of calculated temperatures for the garnet–olivine geothermometer. Our results demonstrate that the two-pyroxene and garnet–clinopyroxene thermometers are rather insensitive to the presence of Fe³⁺ whilst direct accounting of Fe³⁺ in garnet is essential when applying the garnet–olivine and garnet–orthopyroxene thermometers.     

Seismicity around the Hekla and Torfajökull volcanoes, Iceland, during a volcanically quiet period, 1991–1995

The volcano Hekla in south Iceland had its latest eruption in January–March 1991. The eruption was accompanied and followed by considerable seismic activity. This study examines the seismicity in the Hekla region (63°42′–64°18′N, 18°30′–20°12′W) during a period when the high activity related to the eruption had ceased, from July 1991 to October 1995. The aim is to define the level of the normal background seismicity of the area that can be compared to the eruption-related activity. The Hekla Volcano proper was generally aseismic during the study period. The most prominent earthquake cluster is in the neighbouring Torfajökull Volcano. The epicentres are concentrated in the western part of the caldera and west of it. The hypocentres are located at all depths from the surface down to 14?km, with highest activity at 5–12?km. Inside this cluster, in the northwest part of the caldera, is a spherical volume void of earthquakes, approximately 4?km in diameter and centred at 8?km depth. This is interpreted as a cooling magma body. Small, low-frequency events of volcanic origin were occasionally recorded at Torfajökull. This activity has mainly occurred in swarms and was most abundant during the first year of the study period, presumably reflecting some kind of connection to the 1991 Hekla eruption. Our study area also includes the easternmost section of the South Iceland seismic zone, a transform zone characterized by bookshelf faulting on transverse faults. Two lineaments of epicentres were identified, roughly corresponding to mapped faults of the South Iceland seismic zone. The hypocentres are relatively deep, mainly at 6–12?km, matching the general trend of hypocentral depth increasing toward the east. The seismicity is highest in the area of the mapped faults. However, the epicentres extend beyond them and indicate greater width of the South Iceland seismic zone, or 20–30?km rather than approximately 10?km as indicated by the length of the surface faults. The seismicity in the volcanic systems of Hekla and Vatnafjöll shows some characteristics of the South Iceland seismic zone. Epicentres are concentrated into two N–S lineaments, one of which coincides with the location of the 1987 Vatnafjöll earthquake (M_w=5.9), a strike-slip event on a N- to S-trending fault. The hypocentres of the Hekla–Vatnafjöll events are mainly at 8–13?km depth, which indicates a continuation of the depth trend of the earthquakes of the South Iceland seismic zone. The events located at Hekla proper and immediately north of it are all of low-frequency character, which can be held as an indication of volcanic origin. On the other hand, they show clear S arrivals at observing stations like normal high-frequency tectonic earthquakes.     

A new implementation of narrowband interference detection,characterization, and mitigation technique for a software-defined multi-GNSS receiver

Due to the very low power of satellite signals when reaching the earth’s surface, global navigation satellite system receivers are vulnerable to various types of radio frequency interference, and, therefore, countermeasures are necessary. In the case of a narrowband interference (NBI), the adaptive notch filtering technique has been extensively investigated. However, the research on the topic has focused on the adaptation of the notch frequency, but not of the notch width. We present a fully adaptive solution to counter NBI. The technique is capable of detecting and characterizing any number of narrow interfered bands, and then optimizing the mitigation process based on such characterization, namely the estimates of both interference frequency and width. Its full adaptiveness makes it suitable to cope with the unpredictable and diverse nature of unintentional interfering events. In addition to a thorough performance evaluation of the proposed method, which shows its benefits in terms of signal quality improvement, an analysis of the impact of different NBI profiles on GPS L1 C/A and Galileo E1 is also conducted.     

Keck adaptive optics images of Jupiter’s north polar cap and Northern Red Oval

We present observations at near-infrared wavelengths (1-5 μm) of Jupiter’s north polar region and Northern Red Oval (NN-LRS-1). The observations were taken with the near-infrared camera NIRC2 coupled to the adaptive optics system on the 10-m W.M. Keck Telescope on UT 21 August 2010. At 5-μm Jupiter’s disk reveals considerable structure, including small bright rings which appear to surround all small vortices. It is striking, though, that no such ring is seen around the Northern Red Oval. In de Pater et al. [2010a. Icarus 210, 742-762], we showed that such rings also exist around all small vortices in Jupiter’s southern hemisphere, and are absent around the Great Red Spot and Red Oval BA. We show here that the vertical structure and extent of the Northern Red Oval is very similar to that of Jupiter’s Red Oval BA. These new observations of the Northern Red Oval, therefore, support the idea of a dichotomy between small and large anticyclones, in which ovals larger than about two Rossby deformation radii do not have 5-μm bright rings. In de Pater et al. [2010a. Icarus 210, 742-762], we explained this difference in terms of the secondary circulations within the vortices. We further compare the brightness distribution of our new 5-μm images with previously published radio observations of Jupiter, highlighting the depletion of NH₃ gas over areas that are bright at 5 μm.     

Organic carbon mobilization in a Bangladesh aquifer explained by seasonal monsoon-driven storativity changes

Currently, the most widely accepted hypothesis to explain high As concentrations in Bangladesh groundwaters is that dissolved organic C (DOC) reduces solid Fe (hydr)oxides and mobilizes sorbed arsenate. The nature of the DOC and its release mechanism are still controversial. Based on weekly to biweekly sampling over the course of one monsoon cycle at six monitoring wells of different depths, it is proposed that storativity changes drive natural DOC release from clay–peat layers to the adjacent aquifers. With a decrease in hydraulic heads during the dry season, total mineralization and DOC concentrations increased. With the onset of the rainy season and an increase in hydraulic heads, release of clay–peat derived components stopped and vertical water displacement due to groundwater recharge from rainwater occurred, causing aquifer flushing and a decrease in total mineralization and DOC concentrations. Total As and DOC concentrations correlated over depth. However, at the depth of maximum concentrations, the As peak was observed during the rainy season. At present, the reason for this inverse seasonal trend between As and DOC is unclear. Higher mineralization or DOC concentrations could lead to increased As sorption or the increased arsenite release is a time-lag abiotic or microbial response to the DOC peak. The vulnerability of the Pleistocene aquifer towards increased As concentrations was found to be much higher than previously assumed. Though sorption capacities were determined to be higher than in the Holocene aquifer, probably due to intact Fe (hydr)oxides, long-term continuous As input from overlying clay and peat layers by the proposed seasonal storativity changes has led to increased aqueous As concentrations of 85 μg/L, considerably higher than drinking water standards. Until now, aquifer and especially aquitard and aquiclude hydraulics have not been considered sufficiently when attempting to explain As mobilization in Bangladesh.