Contact metamorphosed dunite-harzburgite complex in the Chugoku district,western Japan

The Tari-Misaka ultramafic complex, which is emplaced into the Paleozoic sediments and thermally metamorphosed by two younger granitic masses, is divided into four zones on the basis of the mineral assemblage. They are, in order of increasing metamorphic grade: Zone I antigorite-olivine-orthopyroxene-clinopyroxene. Zone II olivine-talc. Zone III olivine-anthophyllite. Zone IV olivine-orthopyroxene. Strongly serpentinized clinopyroxene-bearing harzburgite in Zone I is similar to ordinary Alpine-type harzburgite. In Zonne II, two kinds of olivine are recognized. One is Mg-rich olivine (Fo₉₃ to Fo₉₇) with opaque inclusions and is probably a recrystallization product of serpentine with talc. The other is Fe-rich olivine (Fo₈₈ to Fo₉₃) free of opaque inclusions and is probably a relic of the primary peridotite. Olivine in Zone III and Zone IV is also relatively Mg-rich (Fo₉₁ to Fo₉₅). Chromitite in Zone IV commonly has an assemblage, olivine+cordierite+Mg-Al spinel (Mg/Mg+Fe²⁺, more than 0.9). Enstatite is rare and coexists with less magnesian Mg-Al spinel (Mg/Mg+Fe²⁺, less than 0.9). Petrological and mineralogical characters of the ultramafic rocks can be well explained by thermal metamorphism of strongly serpentinized peridotite by granitic intrusion. Metamorphic zones are consistent with the experimental results in the system MgO-SiO₂-H₂O. The assemblage olivine+cordierite indicates that the metamorphism occurred at relatively low pressures (<3kb).     

Extension of the empirical Alyavdin equation for representing batch grinding data

The Alyavdin equation for batch grinding data is:

$\text{1 ? P(χ, t) = [1 ? P(χ, 0)]}\text{exp}\text{?}\text{c(x)t}{}^{\mathrm{p}}\text{]}$

where P(χ,t) is the weight fraction less than size χ after grinding time t, c (χ) is constant with t and p is a constant close to one. It is shown that this equation is illogical (except for a single size of feed) unless c (χ) varies with P(χ,0), which makes the equation of little utility. A new empirical equation is developed for finite size intervals:

which reduces to the Alyavdin equation for a single size of feed, and which gives consistent computations for any feed size distribution. Techniques are given for determining K_i, γ values from sets of batch grinding data. The values are then used to predict size distributions for other times and other feed size distributions. The equation was quite successful in predicting size distributions in batch milling: (a) providing the feed size distribution was not un-natural, that is, not truncated or (b) if a truncated feed was used, the values of K_i and γ are determined from size distributions of grinding of the same type of feed. Thus, K_i, γ are not, unfortunately, completely independent of the starting feed size distribution.     

Enrichment Ratio-Tonnage Diagrams for Resource Assessment

The enrichment ratio (ER), defined as the ratio of grade of a metal element in a deposit to the crustal abundance of the metal, is proposed for assessing mineral resources. According to the definition, the enrichment ratio of a polymetallic deposit is given as a sum of enrichment ratios of all metals. The relation between ER and the cumulative tonnage integrated from the high ER side of about 4750 deposits in the world is approximated by the combination of three exponential functions crossing at ER values of 16 · 10³ and 600. High ER deposits are expected for the commodities Ag, Pb, and Au+Ag, and for epithermal, mesothermal, unconformity-related and vein types. In contrast, low ER deposits are typical for the commodities Cu, Mn, Mo, Ni, and U, and for chemically precipitated, Cyprus, laterite, orthomagmatic, pegmatite, placer, porphyry, and sandstone deposits. The critical ER value of the low ER class (the differential metal amount decreases with decreasing ER in the regions lower than the value) is 250 in all deposits, 610 in W+Mo, 2800 in Pb+Zn and 360 in Au+Ag, 530 in massive sulfides, 160 in the orthomagmatic type, 170 in placers, 220 in the porphyry type, 1900 in the replacement type, 580 in the stratabound type, 3400 in the unconformity-related type, and 1700 in vein type deposits. The frequency proportion determined by a keyword and a commodity provides valuable suggestions for mineral exploration: for example, the exploration target for chromite is a deposit characterized as orthomagmatic, whereas the expected commodity of a newly developed orthomagmatic deposit is chromite.     

Metasomatized harzburgite xenoliths from Avacha volcano as fragments of mantle wedge of the Kamchatka arc: Implication for the metasomatic agent

Abstract   Abundant peridotite xenoliths have been found in pyroclasitics of Avacha (Avachinsky) volcano, the south Kamchatka arc, Russia. They are mostly refractory harzburgite with or without clinopyroxene: the Fo of olivine and Cr/(Cr + Al) atomic ratio of spinel range from 91 to 92 and from 0.5 to 0.7, respectively. They are metasomatized to various extents, and the metasomatic orthopyroxene has been formed at the expense of olivine. The metasomatic orthopyroxene, free of deformation and exsolution, is characterized by low contents of CaO and Cr₂O₃. The complicated way of replacement possibly indicates low viscosity of the metasomatic agent, namely hydrous fluids released from the relatively cool slab beneath the south Kamchatka arc. This is a good contrast to the north Kamchatka arc, where the slab has been hot enough to provide slab-derived melts. High content of total orthopyroxene, 40 vol% on average, in metasomatized harzburgite from Avacha suggests silica enrichment of the mantle wedge, and is equivalent to some subcratonic harzburgite. Some subcratonic harzburgites therefore could have been formed by transportation of subarc metasomatized peridotites to a deeper part of the upper mantle.     

Missing ophiolitic rocks along the Mae Yuam Fault as the Gondwana–Tethys divide in north-west Thailand

Abstract Thailand comprises two continental blocks: Sibumasu and Indochina. The clastic rocks of the Triassic Mae Sariang Group are distributed in the Mae Hong Son–Mae Sariang area, north‐west Thailand, which corresponds to the central part of Sibumasu. The clastic rocks yield abundant detrital chromian spinels, indicating a source of ultramafic/mafic rocks. The chemistry of the detrital chromian spinels suggests that they were derived from three different rock types: ocean‐floor peridotite, chromitite and intraplate basalt, and that ophiolitic rocks were exposed in the area, where there are no outcrops of them at present. Exposition of an ophiolitic complex denotes a suture zone or other tectonic boundary. The discovery of chromian spinels suggests that the Gondwana–Tethys divide is located along the Mae Yuam Fault zone. Both paleontological and tectonic aspects support this conclusion.     

Determination of Multiple Trace Element Compositions in Thin (> 30 μm) Layers of NIST SRM 614 and 616 Using Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS)

To understand and/or avoid small-scale chemical heterogeneities within geological materials prepared as normal thin sections, in situ multiple trace element determination coupled with the simultaneous microscopic observation of the sample during analysis is preferable. We have examined fifty trace elements in thin (< 30 μm) layers of the NIST SRM 614 and 616 glass reference materials by LA-ICP-MS using different pit diameters and internal standard elements (Ca and Si). Compositional heterogeneities of Tl, Bi, As and Cd were found in NIST SRM 614 and 616 at the spatial resolution of ca. 10 0 μm. Except for these elements, the RSDs of six determinations for most elements were better than 10% in NIST SRM 614 when ablation diameters were < 50 μm. The measured concentrations for most elements in NIST SRM 614 and 616 agree with previous values in the literature at the 95% confidence level with the exception of W and Bi. New LA-ICP-MS data for K, As and Cd are also reported. The results support the view that the latest LA-ICP-MS is a powerful and flexible analytical technique for the determination of multiple ultra-trace element compositions in geological materials prepared as normal thin sections of the type that has been used for polarising optical microscopic observations since the end of the 19th century.     

Complete mantle section of a slow-spreading ridge-derived ophiolite: An example from the Isabela ophiolite in the Philippines

Abstract   The Isabela ophiolite shows a complete ophiolite sequence exposed along the eastern coast of northern Luzon, the Philippines. It forms the Cretaceous basement complex for the northeastern Luzon block. This ophiolite is located at the northern end of a trail of ophiolites and ophiolitic bodies along the eastern margin of the Philippine Mobile Belt. This paper presents new findings regarding the nature and characteristics of the Isabela ophiolite. Peridotites from the Isabela ophiolite are relatively fresh and are composed of spinel lherzolites, clinopyroxene-rich harzburgites, depleted harzburgites and dunites. The modal composition, especially the pyroxene content, defines a northward depletion trend from fertile lherzolite to clinopyroxene-rich harzburgites and more refractory harzburgites. Variation in modal composition is accompanied by petrographic textural variations. The chromium number of spinel, an indicator of the degree of partial melting, concurs with petrographic observations. Furthermore, the Isabela ophiolite peridotites are similar in spinel and olivine major-element geochemistry and clinopyroxene rare earth-element composition to abyssal peridotites from modern mid-oceanic ridges. Petrological and mineral compositions suggest that the Isabela ophiolite is a transitional ophiolite subtype, with the fertile lherzolites representing lower sections of the mantle column that are usually absent in most ophiolitic massifs. The occurrence of the fertile peridotite presents a rare opportunity to document the lower sections of the ophiolitic mantle. The variability in composition of the peridotites in one continuous mantle section may also represent a good analogy of the melting column in the present-day mid-oceanic ridges.     

WinASEAN for remote sensing data analysis

The image analysis system ASEAN (Advanced System for Environmental ANalysis with Remote Sensing Data) was designed and programmed by a software development group, ImaSOFr, Department of Remote Sensing Technology and GIS, Institute for Geography, National Centre for Natural Science and Technology of Vietnam under technical cooperation with the Remote Sensing Technology Centre of Japan and financial support from the National Space Development Agency of Japan. ASEAN has been in continuous development since 1989, with different versions ranging from the simplest one for MS-DOS with standard VGA 320×200×256 colours, through versions supporting SpeedStar 1.0 and SpeedStar PRO 2.0 true colour graphics cards, up to the latest version named WinASEAN, which is designed for the Windows 3.1 operating system. The most remarkable feature of WinASEAN is the use of algorithms that speed up the image analysis process, even on PC platforms. Today WinASEAN is continuously improved in cooperation with NASDA (National Space Development Agency of Japan), RESTEC (Remote Sensing Technology Center of Japan) and released as public domain software for training, research and education through the Regional Remote Sensing Seminar on Tropical Eco-system Management which is organised by NASDA and ESCAR In this paper, the authors describe the functionality of WinASEAN, some of the relevant analysis algorithms, and discuss its possibilities of computer-assisted teaching and training of remote sensing.     

Re–Os isotope systematics for the Lince–Estefanía deposit: constraints on the timing and source of copper mineralization in a stratabound copper deposit, Coastal Cordillera of Northern Chile

The Lince–Estefanía stratabound copper deposit in the Michilla district is one of the most important deposits in the Coastal Cordillera of northern Chile and is one of the most representative of this type of deposit. Chalcocite and bornite characterize the main stage of hypogene copper sulfide mineralization. Rhenium and osmium isotopes are used here to constrain the age of hypogene mineralization and the source of osmium contained in these ore minerals. A Re–Os isochron yielded an age of 160±16 Ma (2σ), with an associated initial ¹⁸⁷Os/¹⁸⁸Os ratio of 1.06±0.09 (mean square of weighted deviates=1.8). This age is consistent with available geochronological data from volcanic rocks that host the mineralization and associated alteration phases. The high initial ¹⁸⁷Os/¹⁸⁸Os ratio indicates a lower crustal component for the source of Os and, by inference, the Cu sulfides that contain this Os. Late hematite occurs as an isolated phase or, more commonly, is associated with the chalcocite–bornite and supergene chalcocite–covellite associations. Analyses performed on pure hematite indicate a disturbance of the Re–Os system, and hence, this mineral phase is not useful as a Re–Os geochronometer.