Distribution and Influence of Iron Phases the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-ray Electron Spin Resonance(ESR) spectroscopes.The purity of the samples and the degree of their structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which persist after chemical dissolution of free iron.The Moessbauer spectra of these clays show two doublets with isomer shift and quadrupole splitting typical of octahedrally coordinated Fe^3 ,in addition to third doublet with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H) sample.Six-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octahedral symmetry as well as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activation of the investigated montmorillonite samplas by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,the amount and site occupation of Fe associated with kaolinite samples show an inverse correlation with the parameters used to describe the degree of crystallinity perfection,color,brightness and vitrification range of these kaolinite samples.     

Rock composition and origin of the Duwi Formation calcareous rocks, Upper Egypt

Upper Cretaceous phosphorite beds of the Duwi Formation, Upper Egypt, are intercalated with limestone, sandy limestone, marl, calcareous shales, and calcareous sandstone. Calcareous intercalations were subjected to field and detailed petrographic, mineralogical and geochemical investigations in order to constrain their rock composition and origin. Mineralogically, dolomite, calcite, quartz, francolite and feldspars are the non-clay minerals. Smectite, kaolinite and illite represent the clay minerals. Major and trace elements can be classified as the detrital and carbonate fractions based on their sources. The detrital fraction includes the elements that are derived from detrital sources, mainly clay minerals and quartz, such as Si, Al, Fe, Ti, K, Ba, V, Ni, Co, Cr, Zn, Cu, Zr, and Mo. The carbonate fraction includes the elements that are derived from carbonates, maily calcite and dolomite, such as Ca, Mg and Sr. Dolomite occurs as being dense, uniform, mosaic, very fine-to-fine, non-ferroan, and non-stoichiometrical, suggesting its early diagenetic formation in a near-shore oxidizing shallow marine environment. The close association and positive correlation between dolomite and smectite indicates the role of clay minerals in the formation of dolomite as a source of Mg^2＋ -rich solutions. Calcareous rocks were deposited in marine, oxidizing and weakly alkaline conditions, marking a semi-arid climatic period. The calcareous/argillaceous alternations are due to oscillations in clay/carbonate ratio.     

Mineralogy, geochemistry, and origin of felsic dike swarms in Aqaba complex (Wadi Al-Yutum), South Jordan

The present work deals with the geologic setting and mineralogical and geochemical study of Late Precambrian magmatic rocks especially the felsic dike swarms of northeast Aqaba complex in South Jordan. The northeast Aqaba complex represents one of the most significant regions in the South Jordan basement. The basement rocks in the studied region are composed of schists, gneisses, migmatites, met gabbros, diorite, and granite. It is invaded by post-orogenic dike swarms. The post-orogenic dike swarms have been recognized as felsic dikes of dacite, rhyodacite, and rhyolite composition. They are composed of plagioclase, K-feldspar, quartz, biotite, and hornblenble with a porphyritic texture. Chemically, they are enriched in compatible elements especially in the large ion lithophile elements such as K, Rb, and Ba. The values of A/NK are more than A/CNK, indicating that dacitic dike swarms have metaluminous nature. Meanwhile, the values of A/NK are less than A/CNK in rhyodacitic and rhyolitic dike swarms of prealuminous nature. This felsic dike can be related to an intercontinental setting that was accompanied by a chemical evolution of the extensional movements and is formed by partial melting of crustal rocks, which are already known from other areas in the northeast portion of the Arabian-Nubian Shield.     

Modelling the effects of climatic and hydrological regime changes on the sediment dynamics of the Fraser River Basin,British Columbia,Canada

Future sediment dynamics may be affected by changing climates or hydrological regimes because of the close link between hydrology and sediment erosion, deposition, and transport. Previously, investigations of these potential changes have been constrained by a combination of limited observational data, hydrological drivers, and appropriate mechanistic models. Additionally, there is often ambiguity regarding how to disentangle the impacts of climate and hydrology from direct human factors such as reservoirs and land‐use change, which often exert more control over sediment dynamics. In this study, we utilize a recently developed, large‐scale, distributed, mechanistic sediment transport model to project future sediment erosion, deposition, and transportation within the Fraser River Basin in British Columbia, Canada—a basin with historical water flux and sediment load observations and limited anthropogenic influences upstream of its delta. The sediment model is driven by synthetic land‐surface hydrology derived from Scenarios A1B, A2, and B1 of the Special Report on Emissions Scenarios, which were provided by the Pacific Climate Impacts Consortium. Resulting simulations of water flux and sediment load from 1965 to 1994 are first validated against observational data then compared with future projections. Future projections show an overall increase in annual hillslope erosion and in‐channel transportation, a shift towards earlier spring peak erosion and transportation, and longer persistence of the sediment signal through the year. These shifts in timing and annual yield may have deleterious effects on spawning sockeye salmon and are insufficient to counteract future coastal retreat caused by sea‐level rise.     

Encke's special perturbation technique associated with the KS regularized variables

In this paper of the series, a special perturbation technique of Encke-type associated with the KS regularized variables will be developed for satellite motions in the Earth's gravitational field with axial symmetry. Its computational algorithm is of recursive nature and could be applied for any perturbed conic motion whatever the number of the zonal harmonic coefficients may be. Applications of the algorithm are also included.Now at the Department of Mathematics, Girls College of Education, Jeddah, Saudi Arabia.     

Jewish settlement and its economic impact on the West Bank, 1967–1987

This paper focuses on the process of Jewish settlement in the West Bank and its economic consequences in the period from 1967 to the outbreak of the Intifada late in 1987. It attempts to show that this process is the practical application of Israeli objectives which are based on expansion and occupation of neighbouring Arab lands, facilitated by the fashioning of a dual or bifurcate economy there.After the war of June 1967, Israeli occupation authorities started to draw up plans with a view to settling Jews in the West Bank. There has been an increase in the numbers of settlements and settlers, estimated at 122 and 52,000 respectively in 1987. The pattern of settlement distribution is randomly dispersed, although it is concentrated in a region located to the NW of Jerusalem. The settlement began in the Jordan valley and extended gradually westward in the highlands.Jewish settlement has affected economic development of the West Bank, where there were many constraints on Arab agriculture and industry. Inequality is evident between settlers and Palestinians in an economy that has been structurally bifurcated: although settlers represent about 3% of total population of the West Bank, their economic activity constitutes at least 35% of the GDP of the West Bank.     

Kinematic significance of fold- and fault-related fracture systems in the Zagros mountains, southern Iran

Initiation and formation of folds and the Kazerun high-angle fault zone, in the Zagros fold-and-thrust belt, were related to the continuing SW–NE oriented contraction that probably initiated in the Late Cretaceous, and intensified, starting in Miocene, when the Arabian and Eurasian plates collided. The contraction that led to folding and thrusting of the Phanerozoic sequence in the belt has led to the strike–slip reactivation of basement faults that formed during the Precambrian. Two major systems of fractures have developed, under the same regional state of contraction, during the folding and strike–slip faulting processes. Folding led to the formation of a system of fold-related fractures that comprises four sets of fractures, which include an axial and a cross-axial set that trend parallel and perpendicular to the confining fold axial trace, respectively, and two oblique sets that trend at moderate angles to the axial trace. Slip along high-angle, strike–slip faults formed a system of fractures in the damage zone of the faults (e.g., Kazerun), and deformed folds that existed in the shear zone by rotating their axial plane. This fault-related fracture system is made of five sets of fractures, which include the two sets of Riedel shear fractures (R and R′), P- and Y-shear fractures, and an extensional set.

Remote sensing analysis of both fracture systems, in a GIS environment, reveals a related kinematic history for folding outside of the Kazerun shear zone and faulting and deformation (fracturing and rotation of folds) within the Kazerun fault zone. Rotation of the folds and formation of the five sets of the fault-related fractures in the Kazerun shear zone are consistent with a dextral motion along the fault. The mean trends of the shortening directions, independently calculated for the fold- and fault-related fracture systems, are remarkably close (N53 ± 4°E and N50 ± 5°E, respectively), and are perpendicular to the general NW–SE trend of the Zagros fold-and-thrust belt. Although segments of the Kazerun fault are variably oriented within a narrow range, the angular relationships between sets of fault-related fractures and these segments remain constant.     

Magmatic unmixing in spinel from late Precambrian concentrically-zoned mafic–ultramafic intrusions, Eastern Desert, Egypt

Spinel is widespread in the ultramafic core rocks of zoned late Precambrian mafic–ultramafic complexes from the Eastern Desert of Egypt. These complexes; Gabbro Akarem, Genina Gharbia and Abu Hamamid are Precambrian analogues of Alaskan-type complexes, they are not metamorphosed although weakly altered. Each intrusion is composed of a predotite core enveloped by pyroxenites and gabbros at the margin. Silicate mineralogy and chemistry suggest formation by crystal fractionation from a hydrous magma. Relatively high Cr₂O₃ contents are recorded in pyroxenes (up to 1.1 wt.%) and amphiboles (up to 1.4 wt.%) from the three plutons. The chrome spinel crystallized at different stages of melt evolution; as early cumulus inclusions in olivine, inclusions in pyroxenes and amphiboles and late-magmatic intercumulus phase. The intercumulus chrome spinel is homogenous with narrow-range of chemical composition, mainly Fe³⁺-rich spinel. Spinel inclusions in clinopyroxene and amphibole reveal a wide range of Al (27–44 wt.% Al₂O₃) and Mg (6–13 wt.% MgO) contents and are commonly zoned. The different chemistries of those spinels reflect various stages of melt evolution and re-equilibration with the host minerals. The early cumulus chrome spinel reveals a complex unmixing structures and compositions. Three types of unmixed spinels are recognized; crystallographically oriented, irregular and complete separation. Unmixing products are Al-rich (Type I) and Fe³⁺-rich (Type II) spinels with an extensive solid solution between the two end members. The compositions of the unmixed spinels define a miscibility gap with respect to Cr–Al–Fe³⁺, extending from the Fe³⁺–Al join towards the Cr corner. Spinel unmixing occurs in response to cooling and the increase in oxidation state. The chemistry and grain size of the initial spinel and the cooling rate control the type of unmixing and the chemistry of the final products. Causes of spinel unmixing during late-magmatic stage are analogous to those in metamorphosed complexes. The chemistry of the unmixed spinels is completely different from the initial spinel composition and is not useful in petrogenetic interpretations. Spinels from oxidized magmas are likely to re-equilibrate during cooling and are not good tools for genetic considerations.     

Environmental study of the Amman-Zerqa Basin Jordan

 Rapid population growth, urbanization expansion of rural settlements, industrial activity, intensively irrigated agriculture, pesticides consumption, and continuous dumping of hazardous waste in the Amman-Zerqa Basin since 1967 are the major factors threatening the quality of the environment. Thus, an environmental recommendation is proposed to protect the environment and water resources in the study area. The chemical analysis of the springs in the study area showed salinity increasing with time, which indicates water pollution affecting these springs. The laboratory analyses indicated that the quality of the treated waste water of Khirbet Es-Samra Treatment plant conforms to the World Health Organization (WHO) standards from the chemical, physical, and the microbiological point of view. Toxic elements such as cadmium identified in the surface water flow of the basin are in concentrations higher than those recommended by WHO Received: 30 January 1997 · Accepted: 30 June 1997