DMS and SO2 at Baring Head, New Zealand: Implications for the Yield of SO2 from DMS

Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO₂) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO₂ diurnalcycles, consistent with the photochemical production of SO₂ from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO₂ from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO₂ yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO₂ yield is lower in the range of 20–40%.     

Effective timescales of coupling within fluvial systems

This paper presents a review of the coupling concept in fluvial geomorphology, based mainly on previously published work. Coupling mechanisms link the components of the fluvial system, controlling sediment transport down the system and the propagation of the effects of base-level change up the system. They can be viewed at several scales: at the local scale involving within-hillslope coupling, hillslope-to-channel coupling, and within-channels, tributary junction and reach-to-reach coupling. At larger scales, coupling can be considered as zonal coupling, between major zones of the system or as regional coupling, relating to complete drainage basins. These trends are illustrated particularly by the examples of hillslope-to-channel coupling in the Howgill Fells, northwest England, badland systems in southeast Spain, alluvial fans in Spain, USA and UAE, and base-level-induced dissection of Neogene sedimentary basins in southeast Spain. As the spatial scales increase, so do the timescales involved. Effective temporal scales relate to magnitude and frequency characteristics, recovery time and propagation time, the relative importance changing with the spatial scale. For downsystem coupling at the local scale, the first two are important, with propagation time increasing in importance in larger systems, especially in those involving upsystem coupling related to base-level change. The effective timescales range from the individual event, with a return period of decades, through decadal to century timescales for downsystem coupling, to tens to hundreds of thousands of years for the basinwide response to base-level change. The effective timescales influence the relative importance of factors controlling landform development.     

Measuring Urban Streetscapes for Livability: A Review of Approaches

Increasing interest in urban livability demands that geographers and planners more precisely define what constitutes a livable streetscape, a fundamental building block of urban places. Widespread examination of streetscape livability will require precise and efficient measurements of (1) physical characteristics at the spatial scale of individual streetscapes and (2) indicators of experiential quality based on revealed behavior or stated preference. This article reviews approaches to collecting both types of measurements, showing that innovative methods using geographic information systems (GIS), Internet-enabled surveys, and even social media could be useful complements to traditional qualitative methods for collecting streetscape measurements.     

Prehistoric soil and water detention structures (gabarbands) at Phang,Sindh Kohistan,Pakistan: An adaptation to environmental change?

Five gabarbands (dams), components of integrated soil and water conservation systems, were investigated in the arid region of Sindh Kohistan. The dams are associated with two prehistoric Kot Dijian settlements, Phang and Kohtrash (3200–2800 B. C.). The dams were constructed with relatively permeable materials. Three of the dams, South, East, and North, close off water gaps and a strike valley, respectively, to form a detention basin. The West Dam, located on Phang Nai, upstream of the detention basin removed the coarser sediment fraction from the flows. Spring Dam, located in a water gap to the north of the detention basin, acted as a low-head weir to distribute flow from a perennial spring onto the floodplain of Baran Nai, where double-cropping was probably practiced. Faulting eliminated the spring, which had probably supported the Kohtrash site, and led to construction of the detection basin for the purposes of subsurface storage of detained flows. Association of both modern and prehistoric sites with springs suggests that there has not been appreciable climate change in Sindh Kohistan in the last 5000 years. © 1993 John Wiley & Sons, Inc.     

The fate of terrestrial organic matter in two Scottish sea lochs

Sea lochs are zones of rapid organic matter (OM) turnover. Most of this OM is of allochthonous origin, being introduced into the lochs via freshwater input. In this study the behaviour of terrestrially derived OM was elucidated using a combination of parameters which indicate OM diagenesis in the near surface sediments from two Scottish sea lochs, Loch Creran and Loch Etive. Alkaline CuO oxidation was used to determine lignin phenols which serve as biomarkers for terrestrial OM in sediments. Stable carbon isotope, total carbon and nitrogen and total OM (including the labile and refractory fractions) compositions were also determined.     

Trace element and molecular markers of organic carbon dynamics along a shelf–basin continuum in sediments of the western Arctic Ocean

Molecular organic biomarkers together with trace element composition were investigated in sediments east of Barrow Canyon in the western Arctic Ocean to determine sources and recycling of organic carbon in a continuum from the shelf to the basin. Algal biomarkers (polyunsaturated and short-chain saturated fatty acids, 24-methylcholesta-5,24(28)-dien-3β-ol, dinosterol) highlight the substantial contribution of organic matter from water column and sea-ice primary productivity in shelf environments, while redox markers such as acid volatile sulfide (AVS), Mn, and Re indicate intense metabolism of this material leading to sediment anoxia. Shelf sediments also receive considerable inputs from terrestrial organic carbon, with biomarker composition suggesting the presence of multiple pools of terrestrial organic matter segregated by age/lability or hydrodynamic sorting. Sedimentary metabolism was not as intense in slope sediments as on the shelf; however, sufficient labile organic matter is present to create suboxic and anoxic conditions, at least intermittently, as organic matter is focused towards the slope. Basin sediments also showed evidence for episodic delivery of labile organic carbon inputs despite the strong physical controls of water depth and sea-ice cover. Principal components analysis of the lipid biomarker data was used to estimate fractions of preserved recalcitrant (of terrestrial origin) and labile (of marine origin) organic matter in the sediments, with ranges of 12–79%, 14–45%, and 37–66% found for the shelf, slope, and basin cores, respectively. On average, the relative preserved terrestrial organic matter in basin sediments was 56%, suggesting exchange of organic carbon between nearshore and basin environments in the western Arctic.     

Interactions between sediment chemistry and frenulate pogonophores (Annelida) in the north-east Atlantic

The small frenulate pogonophores (Annelida: Pogonophora a.k.a. Siboglinidae) typically inhabit muddy sediments on the continental slope, although a few species occur near hydrothermal vents and cold seeps. We present data on the distribution and habitat characteristics of several species on the European continental shelf and slope from 48°N to 75°N and show how the animals interact with the chemistry of the sediments. The environments inhabited include: shallow (30 m), organic-rich, fjord sediments; slope sediments (1000–2200 m) and methane seeps at 330 m depth. All the species studied obtain nutrition from endosymbiotic bacteria. They take up reduced sulphur species, or in one case, methane, through the posterior parts of their tubes buried in the anoxic sediment. We conclude that most species undertake sulphide ‘mining’, a mechanism previously demonstrated in the bivalves Lucinoma borealis and Thyasira sarsi. These pogonophores participate in the sulphur cycle and effectively lower the sulphide content of the sediments. Our results show that the abundance of frenulate pogonophores increases with increasing sedimentation and with decreasing abundance of other benthos, particularly bioturbating organisms. The maximum sustainable carrying capacity of non-seep sediments for frenulate pogonophores is limited by the rate of sulphate reduction.