Focal Mechanisms and Stress Field in The Region Vogtland/Western Bohemia

We calculated focal mechanisms for 30 of the strongest events (1.5 M _L 3.3) in distinct subregions of Vogtland/Western Bohemia between 1990 and 1998. Our investigations are concerned with events of the swarms near Bad Elster (1991), Haingrün (1991), Nový Kostel (1994 and 1997) and Zwickau (1998), two events from a group of earthquakes near Klingenthal (1997) and eight single events. Seismograms were provided by the digital station networks of the Geophysical Observatory of the University of Munich, the Technical University of Freiberg, the Academy of Sciences of the Czech Republic in Prague, the Masaryk University in Brno and some nearby stations of the German Regional Seismic Network (GRSN). To calculate focal mechanisms two inversion methods were applied. The inferred focal mechanisms do not show a simple, uniform pattern of seismic dislocation. All possible dislocation types – strike-slip, normal and thrust faulting - are represented. The prevailing mechanisms are normal and strike-slip faulting. Considerable differences in the fault plane solutions are noted for the individual subregions as well as in some cases among the individual events of a single swarm. For the Nový Kostel area we succeeded to resolve a change in the orientations of the nodal planes for the two successive swarms of December 1994 and January 1997. Besides this we also observe a change in the mechanisms, namely from strike-slip and normal faulting (December 1994) to strike-slip and thrust faulting (January 1997). Based on the inferred focal mechanisms the stress field was estimated. It turned out, that the dominating stress field in the region Vogtland/Western Bohemia does not substantially differ from the known stress field of West and Central Europe, being characterized by a SE-NW direction of the maximum compressive horizontal stress. We conclude that the seismicity in the Vogtland/Western Bohemia region is not predominantly caused by an independent local stress field, but rather controlled by the dominating stress regime in Central Europe.     

Behaviour of H2O2, NH3, and black carbon in mixed-phase clouds during CIME

We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H₂O₂, NH₃ and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H₂O₂ and NH₃ are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H₂O₂ is driven by co-condensation with water vapour onto ice crystals while NH₃ uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH₄⁺ in the ice could explain this result. Finally, it appears that the H₂O₂–SO₂ reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.     

Synthesis of monticellite–forsterite and merwinite–forsterite symplectites in the CaO–MgO–SiO<Subscript>2</Subscript> model system: influence of temperature and water content on microstructure evolution

Homogeneous single crystals of synthetic monticellite with the composition \({\text{Ca}}_{0.88}{\text{Mg}}_{1.12}{\text{SiO}}_4\) (Mtc I) were annealed in a piston-cylinder apparatus at temperatures between 1000 and \(1200\,^{\circ }\hbox {C}\), pressures of 1.0–1.4 GPa, for run durations from 10 min to 24 h and applying bulk water contents ranging from 0.0 to 0.5 wt% of the total charge. At these conditions, Mtc I breaks down to a fine-grained, symplectic intergrowth. Thereby, two types of symplectites are produced: a first symplectite type (Sy I) is represented by an aggregate of rod-shaped forsterite immersed in a matrix of monticellite with end-member composition (Mtc II), and a second symplectite type (Sy II) takes the form of a lamellar merwinite–forsterite intergrowth. Both symplectites may form simultaneously, where the formation of Sy I is favoured by the presence of water. Sy I is metastable with respect to Sy II and is successively replaced by the latter. For both symplectite types, the characteristic spacing of the symplectite phases is independent of run duration and is only weeakly influenced by the water content, but it is strongly temperature dependent. It varies from about 400 nm at \(1000\,^{\circ }\hbox {C}\) to 1200 nm at \(1100\,^{\circ }\hbox {C}\) in Sy I, and from 300 nm at \(1000\,^{\circ }\hbox {C}\) to 700 nm at \(1200\,^{\circ }\hbox {C}\) in Sy II. A thermodynamic analysis reveals that the temperature dependence of the characteristic spacing of the symplectite phases is due to a relatively high activation energy for chemical segregation by diffusion within the reaction front as compared to the activation energy for interface reactions at the reaction front. The temperature dependence of the characteristic lamellar spacing and the temperature-time dependence of overall reaction progress have potential for applications in geo-thermometry and geo-speedometry.     

Frictional sliding in serpentine at very high pressure

Using a new four-channel system for detecting acoustic emissions in a multianvil apparatus, we have assessed the pressure–temperature range for such emissions, as well as the role of dehydration, by deforming samples of extensively serpentinized peridotite. We show that in the absence of dehydration and for samples initially faulted at low pressure, acoustic emissions occurred well outside the expected pressure–temperature field of unassisted brittle failure. Emissions were also detected during and after dehydration of serpentine. Microstructures of post-run specimens revealed fault slip with offsets up to ~ 500 μm, regardless of whether or not dehydration took place. Dehydration appears to effectively stop slip on pre-existing faults and create new ones. Analysis of P-wave travel times from the four sensors confirmed that the acoustic emissions originated within the specimen during fault slip. These observations suggest that earthquakes can be triggered by slip along an existing fault containing serpentine under significantly higher pressure and temperature conditions than previously thought possible without dehydration.     

A re-examination of petrogenesis and 40Ar/39Ar systematics in the Chain of Ponds K-feldspar: “diffusion domain” archetype versus polyphase hygrochronology

K-feldspar (Kfs) from the Chain of Ponds Pluton (CPP) is the archetypal reference material, upon which thermochronological modeling of Ar diffusion in discrete “domains” was founded. We re-examine the CPP Kfs using cathodoluminescence and back-scattered electron imaging, transmission electron microscopy, and electron probe microanalysis. ⁴⁰Ar/³⁹Ar stepwise heating experiments on different sieve fractions, and on handpicked and unpicked aliquots, are compared. Our results reproduce the staircase-shaped age spectrum and the Arrhenius trajectory of the literature sample, confirming that samples collected from the same locality have an identical Ar isotope record. Even the most pristine-looking Kfs from the CPP contains successive generations of secondary, metasomatic/retrograde mineral replacements that post-date magmatic crystallization. These chemically and chronologically distinct phases are responsible for its staircase-shaped age spectra, which are modified by handpicking. While genuine within-grain diffusion gradients are not ruled out by these data, this study demonstrates that the most important control on staircase-shaped age spectra is the simultaneous presence of heterochemical, diachronous post-magmatic mineral growth. At least five distinct mineral species were identified in the Kfs separate, three of which can be traced to external fluids interacting with the CPP in a chemically open system. Sieve fractions have size-shifted Arrhenius trajectories, negating the existence of the smallest “diffusion domains.” Heterochemical phases also play an important role in producing nonlinear trajectories. In vacuo degassing rates recovered from Arrhenius plots are neither related to true Fick’s Law diffusion nor to the staircase shape of the age spectra. The CPP Kfs used to define the “diffusion domain” model demonstrates the predominance of metasomatic alteration by hydrothermal fluids and recrystallization in establishing the natural Ar distribution among different coexisting phases that gives rise to the staircase-shaped age spectrum. Microbeam imaging of textures is as essential for ⁴⁰Ar/³⁹Ar hygrochronology as it is for U–Pb geochronology.     

Velocity potential formulations of highly accurate Boussinesq-type models

The highly accurate Boussinesq-type equations of Madsen et al. (Madsen, P.A., Bingham, H.B., Schäffer, H.A., 2003. Boussinesq-type formulations for fully nonlinear and extremely dispersive water waves: Derivation and analysis. Proc. R. Soc. Lond. A 459, 1075–1104; Madsen, P.A., Fuhrman, D.R., Wang, B., 2006. A Boussinesq-type method for fully nonlinear waves interacting with a rapidly varying bathymetry. Coast. Eng. 53, 487–504); Jamois et al. (Jamois, E., Fuhrman, D.R., Bingham, H.B., Molin, B., 2006. Wave-structure interactions and nonlinear wave processes on the weather side of reflective structures. Coast. Eng. 53, 929–945) are re-derived in a more general framework which establishes the correct relationship between the model in a velocity formulation and a velocity potential formulation. Although most work with this model has used the velocity formulation, the potential formulation is of interest because it reduces the computational effort by approximately a factor of two and facilitates a coupling to other potential flow solvers. A new shoaling enhancement operator is introduced to derive new models (in both formulations) with a velocity profile which is always consistent with the kinematic bottom boundary condition. The true behaviour of the velocity potential formulation with respect to linear shoaling is given for the first time, correcting errors made by Jamois et al. (Jamois, E., Fuhrman, D.R., Bingham, H.B., Molin, B., 2006. Wave-structure interactions and nonlinear wave processes on the weather side of reflective structures. Coast. Eng. 53, 929–945). An exact infinite series solution for the potential is obtained via a Taylor expansion about an arbitrary vertical position z = zˆ. For practical implementation however, the solution is expanded based on a slow variation of zˆ and terms are retained to first-order. With shoaling enhancement, the new models obtain a comparable accuracy in linear shoaling to the original velocity formulation. General consistency relations are also derived which are convenient for verifying that the differential operators satisfy a potential flow and/or conserve mass up to the order of truncation of the model. The performance of the new formulation is validated using computations of linear and nonlinear shoaling problems. The behaviour on a rapidly varying bathymetry is also checked using linear wave reflection from a shelf and Bragg scattering from an undulating bottom. Although the new models perform equally well for Bragg scattering they fail earlier than the existing model for reflection/transmission problems in very deep water.     

Alteration in CM carbonaceous chondrites inferred from modal and chemical variations in matrix

The modal abundance of matrix in CM chondrites appears to vary from 57–85 vol%. The concentrations of volatile elements that should occur in matrix remain approximately constant despite differences in the proportions of matrix, suggesting that the differing matrix contents may not be real primary variations but are optical effects due to aqueous alteration processes that make other petrologic components unrecognizable. Apparent matrix content can be used as a qualitative measure of the degree of alteration experienced by each CM chondrite. Fe/Si ratios in matrices decrease progressively with increasing alteration due to the formation of new phyllosilicate phases with higher Mg/Fe ratios and optically recognizable opaque minerals that are not counted as matrix. The aqueous alteration process in CM chondrites appears to have been largely isochemical if the bulk meteorites are considered as the reacting systems, although depletion patterns and isotopic anomalies indicate open-system behavior for a few highly mobile components.     

Chaotic Diffusion And Effective Stability of Jupiter Trojans

It has recently been shown that Jupiter Trojans may exhibit chaotic behavior, a fact that has put in question their presumed long term stability. Previous numerical results suggest a slow dispersion of the Trojan swarms, but the extent of the ‘effective’ stability region in orbital elements space is still an open problem. In this paper, we tackle this problem by means of extensive numerical integrations. First, a set of 3,200 fictitious objects and 667 numbered Trojans is integrated for 4 Myrs and their Lyapunov time, T_L, is estimated. The ones following chaotic orbits are then integrated for 1 Gyr, or until they escape from the Trojan region. The results of these experiments are presented in the form of maps of T_Land the escape time, T_E, in the space of proper elements. An effective stability region for 1 Gyr is defined on these maps, in which chaotic orbits also exist. The distribution of the numbered Trojans follows closely the T_E=1 Gyr level curve, with 86% of the bodies lying inside and 14% outside the stability region. This result is confirmed by a 4.5 Gyr integration of the 246 chaotic numbered Trojans, which showed that 17% of the numbered Trojans are unstable over the age of the solar system. We show that the size distributions of the stable and unstable populations are nearly identical. Thus, the existence of unstable bodies should not be the result of a size-dependent transport mechanism but, rather, the result of chaotic diffusion. Finally, in the large chaotic region that surrounds the stability zone, a statistical correlation between T_LandT_E is found.     

Dissolved carbon and 33-133-133-1anomalies in the water column caused by hydrocarbon seeps on the northwestern Gulf of Mexico slope

Alkalinity, dissolved inorganic carbon (DIC), and ¹³C profiles from seep sites on the northwestern Gulf of Mexico upper slope show anomalously negative ¹³C values of up to –4.5 PDB, increased levels of DIC of up to 2.45 mmole/liter, and slight alkalinity rises of up to 2.54 meq/liter, relative to water column profiles from a seep-free site (0.63, 2.04 mmole/liter, and 2.39 meq/liter). The observed DIC enrichments coupled with the¹³C-depletions are attributed to the release of CO₂ by microbial oxidation of crude oil in the seep environment, and its migration into the water column. The ¹³C composition of the migrating CO₂ is estimated to be –26.0 on the basis of dissolved carbon inventory. Manifestation of DIC and ¹³C anomalies in the water column caused by hydrocarbon seepage holds promise to be useful for hydrocarbon reconnaissance surveys over large offshore tracts on account of the simplicity of sampling acquisition, and rapidity of analytical techniques in the laboratory.     

Peak metamorphic temperatures in type 6 ordinary chondrites: An evaluation of pyroxene and plagioclase geothermometry

Abstract— Quantifying the peak temperatures achieved during metamorphism is critical for understanding the thermal histories of ordinary chondrite parent bodies. Various geothermometers have been used to estimate equilibration temperatures for chondrites of the highest metamorphic grade (type 6), but results are inconsistent and span hundreds of degrees. Because different geothermometers and calibration models were used with different meteorites, it is unclear whether variations in peak temperatures represent actual ranges of metamorphic conditions within type 6 chondrites or differences in model calibrations. We addressed this problem by performing twopyroxene geothermometry, using QUILF95, on the same type 6 chondrites for which peak temperatures were estimated using the plagioclase geothermometer (Nakamuta and Motomura 1999). We also calculated temperatures for published pyroxene analyses from other type 6 H, L, and LL chondrites to determine the most representative peak metamorphic temperatures for ordinary chondrites. Pyroxenes record a narrow, overlapping range of temperatures in H6 (865–926 °C), L6 (812–934 °C), and LL6 (874–945 °C) chondrites. Plagioclase temperature estimates are 96–179 °C lower than pyroxenes in the same type 6 meteorites. Plagioclase estimates may not reflect peak metamorphic temperatures because chondrule glass probably recrystallized to plagioclase prior to reaching the metamorphic peak. The average temperature for H, L, and LL chondrites (～900 °C), which agrees with previously published oxygen isotope geothermometry, is at least 50 °C lower than the peak temperatures used in current asteroid thermal evolution models. This difference may require minor adjustments to thermal model calculations.