Chemical and structural relations of epitaxial xenotime and zircon substratum in sedimentary and hydrothermal environments: a TEM study

Xenotime overgrowths on detrital zircon in siliciclastic sediments have been reported in numerous studies. However, in natural samples, solid solution of zircon and xenotime is limited to near-end-member compositions. In order to characterize the interface region between both minerals and to draw inferences on the growth mechanisms of authigenic xenotime, we studied xenotime overgrowths on detrital zircon grains from two Phanerozoic sandstone samples with contrasting post-depositional histories. In one sample, the small (≤10 μm), pyramidal xenotime overgrowths are of diagenetic origin and grew without major discontinuity on the detrital zircon grain. The second sample shows up to >50-μm-wide, porous and inclusion-rich, hydrothermal xenotime overgrowths on detrital zircon, whereas the transition zone between both minerals is accompanied by large pore volume. Chemical compositions of the xenotime precipitates from the two samples differ particularly in Y, REE, Th and Sc concentrations, whereas high MREE availability in the diagenetic sample and the presence of Sc in the hydrothermal sample, respectively, appear to have promoted xenotime growth. Transmission electron microscopy on electron-transparent foils cut from the interface region shows that both the diagenetic xenotime and the hydrothermal xenotime are crystalline and grew in optical and crystallographic continuity to their detrital zircon substrata. Only a narrow transition zone (≤90 nm—diagenetic sample, 200–300 nm—hydrothermal sample) between zircon and xenotime is in part made up of nanometre-scale crystalline domains that are slightly distorted and may have formed from dissolution–re-precipitation processes at the zircon rim along with precipitation from the respective fluid.     

TiO2 exsolution from garnet by open-system precipitation: evidence from crystallographic and shape preferred orientation of rutile inclusions

We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe²⁺ to Fe³⁺ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.     

Re-assessment of foundation settlements for the Burj Khalifa, Dubai

This paper deals with the re-assessment of foundation settlements for the Burj Khalifa Tower in Dubai. The foundation system for the tower is a piled raft, founded on deep deposits of calcareous rocks. Two computer programs, Geotechnical Analysis of Raft with Piles (GARP) and Non-linear Analysis of Piled Rafts (NAPRA) have been used for the settlement analyses, and the paper outlines the procedure adopted to re-assess the foundation settlements based on a careful interpretation of load tests on trial piles in which the interaction effects of the pile test set-up are allowed for. The paper then examines the influence of a series of factors on the computed settlements. In order to obtain reasonable estimates of differential settlements within the system, it is found desirable to incorporate the effects of the superstructure stiffness which act to increase the stiffness of the overall foundation system. Values of average and differential settlements for the piled raft calculated with GARP and NAPRA were found to be in reasonable agreement with measured data on settlements taken near the end of construction of the tower.     

Frictional sliding in serpentine at very high pressure

Using a new four-channel system for detecting acoustic emissions in a multianvil apparatus, we have assessed the pressure–temperature range for such emissions, as well as the role of dehydration, by deforming samples of extensively serpentinized peridotite. We show that in the absence of dehydration and for samples initially faulted at low pressure, acoustic emissions occurred well outside the expected pressure–temperature field of unassisted brittle failure. Emissions were also detected during and after dehydration of serpentine. Microstructures of post-run specimens revealed fault slip with offsets up to ~ 500 μm, regardless of whether or not dehydration took place. Dehydration appears to effectively stop slip on pre-existing faults and create new ones. Analysis of P-wave travel times from the four sensors confirmed that the acoustic emissions originated within the specimen during fault slip. These observations suggest that earthquakes can be triggered by slip along an existing fault containing serpentine under significantly higher pressure and temperature conditions than previously thought possible without dehydration.     

多代理人系统在商业街消费者行为模拟中的应用——以上海南京东路为例

用模型方法研究消费者行为经历了从集合模型到个体模型的过程.随着计算机技术的进步,近十余年来多代理人技术得到了长足的发展.当前,将消费者个体行为模型和多代理人系统相结合来模拟商业街消费者活动,已经成为相关研究和实践领域的前沿方法.其主要优点在于能够使相关人员以单个消费者为基础,整合复杂的相关因素,预测整体或局部商业空间的动态运行效果,作为规划开发的依据.本文介绍由笔者基于NetLogo开发的一个模拟商业街消费者行为的多代理人模拟平台,包括系统的建构和模拟的流程.该模拟系统的核心由四个基于有限理性原理的消费者决策模型构成:回家决策、方向选择决策、休息决策、商店光顾决策.然后应用这个平台于研究上海南京东路消费者行为的实例.该数据收集于2007年,现场记录了消费者在南京东路的活动过程,并被用于拟合行为模型.将模拟的代理人个体行为集合后,于三方面同观察到的消费者实际行为作比较,包括从事不同活动的消费者数量随时间的变化、在各街道段中活动的消费者数量随时间的变化,以及单个商店中的消费者人次和延时;同时分析了模拟中的问题.结果显示该模拟平台总体上能够较好地预测消费者集合行为.     

Error evolution in the dynamics of an ocean general circulation model

The problem of error propagation is considered for spatially uncorrelated errors of the barotropic stream function in an oceanic general circulation model (OGCM). Such errors typically occur when altimetric data from satellites are assimilated into ocean models. It is shown that the error decays at first due to the dissipation of the smallest scales in the error field. The error then grows exponentially before it saturates at the value corresponding to the difference between independent realizations. A simple analytic formula for the error behavior is derived; it matches the numerical results documented for the present primitive-equation ocean model, and other models in the literature.     

A critical evaluation of oxidation versus reduction during metamorphism of L and LL group chondrites,and implications for asteroid spectroscopy

Abstract— Modal mineralogies of individual, equilibrated (petrologic type 4–6 L and LL chondrites have been measured using an electron microprobe mapping technique, and the chemical compositions of coexisting silicate minerals have been analyzed. Progressive changes in the relative abundances and in the molar Fe/Mn and Fe/Mg ratios of olivine, low‐Ca pyroxene, and diopside occur with increasing metamorphic grade. Variations in olivine/low‐Ca pyroxene ratios (Ol/Px) and in metal abundances and compositions with petrologic type support the hypothesis that oxidation of metallic iron accompanied thermal metamorphism in ordinary chondrites. Modal Ol/Px ratios are systematically lower than normative Ol/Px ratios for the same meteorites, suggesting that the commonly used C.I.P.W. norm calculation procedure may not adequately estimate silicate mineral abundances in reduced chondrites. Ol/Px ratios calculated from visible and near‐infrared (VISNIR) reflectance spectra of the same meteorites are not in agreement with other Ol/Px determinations, possibly because of spectral complexities arising from other minerals in chondrites. Characteristic features in VISNIR spectra are sensitive to the proportions and compositions of olivine and pyroxenes, the minerals most affected by oxidative metamorphism. This work may allow spectral calibration for the determination of mineralogy and petrologic type, and thus may be useful for spectroscopic studies of asteroids.     

On the breakdown of zircon upon “dry” thermal annealing

Zircon samples without and with secondary chemical alteration from diverse sources were subjected to heat treatment at 1400 °C for 96 h. Resulting new phases and textures suggest that decomposition of zircon into component oxides occurred in all experiments to various degrees. The crucible material was found to have a strong influence on the extent of breakdown, especially in the case of altered starting materials. In this study the progressive stages of the breakdown of zircon grains are described. The factors that may govern the decomposition are discussed, including radiation damage, secondary alteration and external reaction conditions (sample container, atmosphere). Alumina crucibles should generally be avoided in dry annealing of zircon, to minimise uncontrolled breakdown into oxides.     

Stratigraphic status,age, and paleobathymetry of the Grey shale Member,Dalmiapuram Formation,Cauvery Basin,India

Grey shale Member of the Dalmiapuram Formation, Ariyalur Group, Cauvery Basin, India was studied for its stratigraphic position, age, and paleobathymetry with a re-look into the lithological relationship and foraminifer assemblages in the deepened limestone mine excavations at M/s Dalmia Cements, Dalmiapuram. Twenty grey shale samples from Kovandankurchchi (pit-4) and Kallakkudi mines yielded diversified calcareous, benthic, and rare index planktic foraminifera. The foraminiferal assemblages suggest a latest Albian age and middle neritic depositional conditions. The abundance of kaolinite and smectite clay minerals relate to warm/humid climate which corroborate with rising relative sea level during grey shale deposition. The grey shale occurs in patches within the marl bedded limestone member which exhibits cyclic deposition of limestone and marl. The limestone mine sections demonstrate that the grey shale forms part of basal marl bedded limestone, directly overlying the coral algal limestone. The present study demonstrates that the grey shale outcrops in Dalmiapuram Formation should be placed stratigraphically as part of marl bedded limestone. The member status for grey shale which is current usage stands discounted.