Arsenic anomalies in shallow Venetian Plain (Northeast Italy) groundwater

A pilot area within the Venetian Plain was selected to assess the arsenic (As) contamination of groundwater. The area represents a typical residential, industrial and agricultural organization representative of most western countries, and is also devoid of lithologies with high or anomalous As content. Hydrogeological and chemical data have been collected, the latter spatialized by a geostatistical approach. The unconfined aquifer reservoir varies from a predominantly gravel composition in the north to a sandy and silt–clay composition further south, including peat layers. The hydrochemical features of the waters are rather homogeneous, featuring low mineral content and a Ca-bicarbonate signature. In contrast, the redox state is highly variable; oxidizing conditions are predominant in the northern and coarse parts of the aquifer, whereas reducing potentials prevail in the southern and silt–clay parts. Several well waters contain arsenic in excess of drinkable limits (=10 ppb), and most of these wells are located in the southern area. A large portion of the studied area has a high probability of containing non-potable water (up to 150 ppb As). Remarkably, As “hot spots” (As > 300 ppb, up to 431 ppb) were identified at the transition from gravel to silt–clay sediments. No industrial or agricultural source of As has been found.     

A numerical Round Robin on tunnels under seismic actions

Although the seismic behaviour of shallow circular tunnels in soft ground is generally safer than aboveground structures, some tunnels were recently damaged during earthquakes. In some cases, damage was associated with strong ground shaking and site amplification, which increased the stress level in the tunnel lining. Pseudo-static and simplified dynamic analyses enable to assess transient changes in internal forces during shaking. Nevertheless, experimental evidences of permanent changes in internal loads in the tunnel lining would suggest that a full dynamic analysis including plastic soil behaviour should be performed when modelling the dynamic interaction between the tunnel and the ground. While sophisticated numerical methods can be used to predict seismic internal forces on tunnel structures during earthquakes, the accuracy of their predictions should be validated against field measurements, but the latter are seldom available. A series of centrifuge tests were therefore carried out at the University of Cambridge (UK) on tunnel models in sand, in the framework of a research project funded by the Italian Civil Protection Department. A numerical Round Robin on Tunnel Tests was later promoted among some research groups to predict the observed behaviour by means of numerical modelling. In this paper, the main results of five selected numerical predictions are summarized and compared with the experimental results.     

Relevance of Pentane- and Hexane-Utilizing Bacterial Indicators for Finding Hydrocarbon Microseepage: A Study from Jamnagar Sub-basin, Saurashtra, Gujarat, India

Mesozoic sediments are source rocks for nearly half the world’s hydrocarbon reserves. Hence, there is great interest in the oil industry to know the trap and sub-trappean sediment thickness and their extent in the trap covered regions of Jamnagar study area. The microbial prospecting method is applied in the Jamnagar sub-basin, Gujarat for evaluating the prospects for hydrocarbon exploration by investigating the anomalous abundance of n-pentane- and n-hexane-oxidizing bacteria of this area. A total of 150 near-surface soil samples were collected in Jamnagar sub-basin, Gujarat for the evaluation of hydrocarbon resource potential of the basin. In this study, bacterial counts for n-pentane-utilizing bacteria range between 1.09 × 10² and 9.89 × 10⁵ cfu/g and n-hexane-utilizing bacteria range between 1.09 × 10² and 9.29 × 10⁵ cfu/g. The adsorbed hydrocarbon gases consisting of ethane plus hydrocarbons (ΣC₂₊) of 1–977 ppb and n-pentane (nC₅) of 1–23 ppb. The integrated geomicrobial and adsorbed soil gas studies showed the anomalous hydrocarbon zones nearby Khandera, Haripur, and Laloi areas which could probably aid to assess the true potential of the basin. Integrated geophysical studies have shown that Jamnagar sub-basin of Saurashtra has significant sediment thickness below the Deccan Traps and can be considered for future hydrocarbon exploration.     

Effects of grazing by Daphnia on algal carotenoids: Implications for paleolimnology

Reverse-phase thin layer chromatography was used to quantify algal carotenoid degradation resulting from grazing by Daphnia magna in suspensions of lyophilized Oscillatoria utermöhlii, O. limnetica, Anabaena flos-aquae and Synechococcus sp. Three samples were removed every 24 h from 0 h to 144 h and the carotenoid, carbon and nitrogen content of the remaining algal-fecal mixture was determined. Grazing by Daphnia reduced carotenoid concentrations by 30%–80% after 144 h, with myxoxanthophyll being the most labile pigment in experiments with filamentous cyanophytes. However, as a group, the carotenoids were more resistant to the combined effects of grazing by Daphnia and bacterial action than were particulate algal carbon (78% to 82% lost by 144 h) or nitrogen (86%–90%) during the period in which easily digestible material remained. The maximal extent of carotenoid enrichment relative to particulate carbon ranged from 150% to 300% of initial pigment concentrations but declined with repeated coprophagy. On the basis of these results and published pigment budgets, we conclude both that fecal transportation of pigments may be an important determinant of carotenoid accumulation rates and that carotenoid stratigraphies should record predator-mediated changes in zooplankton community structure, especially in oligotrophic conditions.     

Models of travel demand with endogenous preference change and heterogeneous agents

In the literatures of regional science, urban economics, and urban development planning, a working assumption is that individuals respond to incentives and regulations, given their preferences. Models for planning and policy analyses are used to consider what might occur if the incentives or regulations were different. In these models, however, preferences are usually assumed to be given and stable, and agents are usually assumed to be homogeneous. This paper focuses on the implications of making preferences in models of policy implementation endogenously determined and time varying heterogeneous agents. We consider first the recent literature on intertemporal choice and preference change, which cuts across many disciplines, and more briefly the literature on norm-regarding behavior. We then elaborate a simple model of transportation demand—from a static to a dynamic orientation, from fixed and exogenously given preferences of strictly self-regarding agents to endogenously determined and policy-induced preferences of heterogeneous agents—and illustrate its characteristics with simple numerical examples.     

Effect of hysteretic smoothness on inelastic response spectra with constant‐ductility

This paper presents an efficient methodology for computing constant‐ductility inelastic response spectra. The computation of constant‐ductility spectra involves numerical root‐finding algorithms to find the strongest structure providing a desired ductility response. Smooth inelastic structural behavior is modeled using a first‐order nonlinear differential equation and the transient structural response is solved using an implicit algorithm requiring Newton iterations at each time step. For structural models with smooth hysteretic behavior (not piece‐wise linear), a simple root‐finding method involving a combination of hyperbolic fits, linear interpolation, and Newton's method converges upon the highest strength (conservative) solution with a small number of iterations. The effect of the hysteretic smoothness on the occurrence of multiple roots is examined for two near‐fault and two far‐fault earthquake records, and for two measures of ductility and for normalized hysteretic energy. The results indicate how the smoothness of the hysteretic behavior affects ductility demand and constant‐ductility response spectra. Copyright © 2010 John Wiley & Sons, Ltd.     

PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia)

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.     

Sensitive observations of radio recombination lines in Orion and W51: the data and detection of systematic recombination line blueshifts proportional to impact broadening

Sensitive spectral observations made in two frequency bands near 6.0 and 17.6 GHz are described for Orion and W51. Using frequency switching we were able to achieve a dynamic range in excess of 10,000 without fitting sinusoidal or polynomial baselines. This enabled us to detect lines as weak as T _A ∼1 mK in these strong continuum sources. Hydrogen recombination lines with Δn as high as 25 have been detected in Orion. In the Orion data, where the lines are stronger, we have also detected a systematic shift in the line center frequencies proportional to linewidth that cannot be explained by normal optical depth effects.