Sm-Nd,K-Ar and petrologic study of some kimberlites from eastern United States and their implication for mantle evolution

We provide new data on Sm-Nd systematics, K-Ar dating and the major element chemistry of kimberlites from the eastern United States (mostly from central New York State) and their constituent mineral phases of olivine, clinopyroxene, garnet, phlogopite and perovskite. In addition, we report Nd-isotopes in a few kimberlites from South Africa, Lesotho and from the eastern part of China. The major element compositions of the New York dike rocks and of their constituent minerals including a xenolith of eclogite are comparable with those from the Kimberley area in South Africa. The K-Ar age of emplacement of the New York dikes is further established to be 143 Ma.We have analyzed the Nd-isotopic composition of the following kimberlites and related rocks: Nine kimberlite pipes from South Africa and Lesotho, two from southern India; one from the U.S.S.R., fifteen kimberlite pipes and related dike rocks from eastern and central U.S. and two pipes from the Shandong Province of eastern China. The age of emplacement of these kimberlites ranges from 1300 million years to 90 million years. The initial Nd-isotopic compositions of these kimberlitic rocks expressed as _Nd ^I with respect to a chondritic bulk-earth growth-curve show a range between 0 and +4, with the majority of the kimberlites being in the range 0 to +2. This range is not matched by any other suite of mantle-derived igneous rocks. This result strengthens our earlier conclusion that kimberlitic liquids are derived from a relatively primeval and unique mantle reservoir with a nearly chondritic Sm/Nd ratio.     

Comprehensive chemical analyses of natural cordierites: implications for exchange mechanisms

Cordierite samples from pegmatites and metamorphic rocks have been analysed for major [electron microprobe analysis (EMPA)] and trace elements [inductively coupled plasma mass spectrometry (ICP-MS), secondary ion mass spectrometry analyses (SIMS)] as well as for H₂O and CO₂ (coulometric titration), and the results evaluated in conjunction with published data in order to determine which exchange mechanisms are significant. Apart from the homovalent substitutions FeMg₋₁ and MnMg₋₁ on the octahedral site, some minor KNa₋₁ on the Ch0 channel site, and Fe³⁺Al₋₁ on the T₁1 tetrahedral site, the three most important substitution mechanisms are those for the incorporation of Li on the octahedral sites (NaLi□₋₁Mg₋₁), and of Be and other divalent cations on the tetrahedral T₁1 site (NaBe□₋₁Al₋₁ and Na(Mg,Fe²⁺)□₋₁Al₋₁). The dominant role of the last vector is clearly demonstrated. We propose a new generalized formula for cordierite: ^Ch(Na,K)_0–1 ^VI(Mg,Fe²⁺,Mn,Li)₂ ^IVSi₅ ^IVAl₃ ^IV(Al, Be, Mg, Fe²⁺, Fe³⁺)O₁₈ *x^Ch(H₂O, CO₂…). Our results show that the population of (Mg, Fe²⁺) on the T₁1-site is limited to about 0.08 a.p.f.u. Other exchange mechanisms that were encountered in experiments operate only under P–T conditions or in bulk compositions that are rarely realized in nature. Routine analyses by electron microprobe in which Li and Be are not determined can be plotted as (Mg+Fe+Mn) versus (Si+Al) to assess whether significant amounts of Li and Be could be present. These amounts can be calculated as Li (a.p.f.u.)=Al+Na–4 and Be (a.p.f.u.)=10–2Al–M²⁺–Na.     

Determination of Antibiotic Residues in Manure,Soil, and Surface Waters

In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fields with the subsequent mechanisms surface run‐off/interflow, leaching, and drift. For this purpose a series of surface waters, soils, and liquid manures from North Rhine‐Westphalia (Northwestern Germany) were sampled and analyzed for up to 29 compounds by HPLC‐MS/MS. In each of the surface waters antibiotics could be detected. The highest concentrations were found in samples from spring (300 ng/L of erythromycin). Some of the substances detected (e.g., tylosin), as well as characteristics in the landscape suggest an input from agriculture in some particular cases. In the investigation of different liquid manure samples by a fast immunoassay method sulfadimidine could be detected in the range of 1…2 mg/kg. Soil that had been fertilized with this liquid manure showed a content of sulfadimidine extractable by accelerated solvent extraction (ASE) of 15 μg/kg dry weight even 7 months after the application. This indicates the high stability of some antibiotics in manure and soil.     

Origin, age and stratigraphic significance of distal fallout ash tuffs from the Carboniferous–Permian continental Saar–Nahe Basin (SW Germany)

Thin, widespread, fallout tuff layers interbedded within fluvio-lacustrine successions of the Carboniferous-Permian Saar-Nahe Basin provide important tephrostratigraphic markers. In addition, radiogeochronometric data derived from the tuffs serve as calibration points for the adjustment to regional chronostratigraphy and to numerical time scales. The Pappelberg-Tuff in the Meisenheim Formation (Glan Group) has been dated by U/Pb zircon SHRIMP technique at 297.0Dž.2 Ma. Taking the Carboniferous/Permian boundary at 296 Ma, the Meisenheim Formation coincides approximately with this boundary. Consequently, underlying strata, lithostratigraphically regarded as the basal part of the 'Rotliegend', chronostratigraphically belong to the Upper Carboniferous. Bed thicknesses, grain size and sorting characteristics of the tuffs and the absence of contemporaneously emplaced volcanics within the Saar-Nahe Basin point to an extrabasinal derivation of the wind-drifted volcanic ash. Decreasing grain sizes of juvenile pyroclastic particles towards the north suggest source areas south of the basin within 300 km distance. The majority of the tuffs are rhyolitic to rhyodacitic and indicate petrographic and geochemical affinities to Moldanubian S-type granitoids, in particular to highly differentiated two-mica granites, and related volcanic effusives. Within the time frame considered here, such potential source rocks were emplaced in the northern and central Black Forest (SW Germany) and the northern Vosges (E France) at 100-150 km distance south of the Saar-Nahe Basin.     

Tectonometamorphic evolution of the Koralm Complex (Eastern Alps): constraints from microstructures and textures of the ‘Plattengneis’ shear zone

Lattice preferred orientations (LPO) of quartz have been investigated along a south–north oriented section across the Plattengneis of the Koralm Complex (Eastern Alps). The Plattengneis forms an important shear zone within the Austroalpine nappe complex of the Eastern Alps, which has developed during the Cretaceous evolution of the Alpine orogen. The quartz c-axes form small circle distributions in the southernmost parts of the Koralm Complex, which represent the uppermost structural level of the Plattengneis. Further to the North two maxima between the Y and Z directions of the finite strain can be interpreted in terms of preferred slip on the rhomb planes. These fabrics continuously grade into (type I and type II crossed) girdle distributions in a northward direction. A strong maximum near the Y-axis with the tendency to be distributed along a single girdle, with three corresponding maxima of a-axes near the margin of the pole figure, can be observed in the central and northern parts. Such LPO are characteristic for both high grade metamorphic conditions and high finite strain. The microstructures display that the deformation within the Plattengneis shear zone was synmetamorphic. A continuous increase of peak temperatures (and pressure) from approximately 550 °C to approximately 750 °C from the South to the central parts can be inferred from geothermometric calculations. The temperatures then decrease to approximately 650 °C from the central parts to the North. The related pressures increase from 8 to 16 kbar, and then decrease to 10 kbar. The LPO changes that have been observed in the study area are best interpreted in terms of temperature dependence of the activation of glide systems within quartz aggregates. The temperature and pressure evolution may indicate that the central parts of the Koralm Complex have been exhumed by larger amounts than the northern and southern parts. This is also documented by the LPO evolution. Therefore, we assume that the Plattengneis shear zone formed during the exhumation of the Koralm Complex, and is related to the exhumation of high-pressure units in the footwall of this shear zone. Accordingly, the kinematics of the Plattengneis shear zone is rather extensional than thrust-related. The implications for the structural evolution of the Eastern Alps are shortly discussed.     

Rapid and rhythmic ice sheet fluctuations in western Scandinavia 15-40 Kya–a review

The onshore record of Middle to Late Weichselian sediments and glacial history in Norway indicates a succession of four major ice advances alternating with rapid, considerable ice recessions and interstadial conditions. During all the glacial advances the ice sheet expanded from onshore/inland positions to the shelf areas. The basis for visualizing these variations in glaciation curves constructed along nine transects from inland to shelf, and for interpretation of the palaeoclimatic history, is the regional Quaternary stratigraphy, more than 300 datings, fossil content and some palaeomagnetic data. The methods applied in recent years for AMS radiocarbon dating of glacial sediments with low organic carbon content have given promising results with respect to accuracy and precision, and the results of such datings were an important tool for our reconstructions and for timing of the ice oscillations. The rapid and rhythmic ice fluctuations, as reconstructed in our new model, have been fairly synchronous in most parts of Norway. Ice advances commenced and culminated at 40, 30-28, 24-21 and 18-15 (¹⁴C) Kya. We describe three intervening interstadials from inland sites: Hattfjelldal I, Hattfjelldal II and Trofors. Our stratigraphical record also includes many indications of high, pre-Holocene, relative sea levels, suggesting a considerable glacioisostatic depression of western Scandinavia during the interstadials. In our glaciation model we suggest that, in addition to precipitation, the mountainous fjord and valley topography, glacial isostasy and relative sea level changes were probably more important for the size of the glacial fluctuations than were air temperature changes.     

Internal stratigraphic relationships in the Etendeka group in the Huab Basin, NW Namibia: understanding the onset of flood volcanism

The Etendeka Igneous Province in NW Namibia forms the eastern most extent of the Paraná–Etendeka Flood Basalt Province and, despite only covering about 5% of the Paraná–Etendeka, has been the focus of much interest, due to its extremely well exposed nature. The Huab Basin in NW Namibia forms the focus of this study, and formed a connected basin with the Paraná throughout Karoo times (late Palaeozoic) into the Lower Cretaceous. It contains a condensed section of the Karoo deposits, which indicate early periods of extension, and Lower Cretaceous aeolian and volcanic Etendeka deposits, which have their correlatives in the Paraná. In the Huab Basin, the volcanic rocks of the Etendeka Group consists of the Awahab and Tafelberg Formations, which are separated by a disconformity. Detailed examination of the Awahab Formation reveals an additional disconformity, which separates olivine-phyric basalts (Tafelkop-type) from basalt/basaltic andesites (Tafelberg-type) marking out a shield volcanic feature which is concentrated in an area to the SE of the Huab River near to the Doros igneous centre. Early volcanism consisted of pahoehoe style flows of limited lateral extent, which spilled out onto aeolian sands of an active aeolian sand sea 133 million years ago. This sand sea is equivalent to the sands making up the Botucatu Formation in the Paraná basin. The early expression of flood volcanism was that of laterally discontinuous, limited volume, pahoehoe flows of Tafelkop-type geochemistry, which interleaved with the aeolian sands forming the Tafelkop–Interdune Member basalts. These basalts are on-lapped by more voluminous, laterally extensive, basalt/basaltic andesite flows indicating a step-up in the volume and rate of flood volcanism, leading to the preservation of the shield volcanic feature. These geochemically distinct basalts/basaltic andesites form the Tsuhasis Member, which are interbeded with the Goboboseb and Sprinkbok quartz latite flows higher in the section. The Tsuhasis Member basalts, which form the upper parts of the Awahab Formation, are of Tafelberg-type geochemistry, but are stratigraphically distinct from the Tafelberg lavas, which are found in the Tafelberg Formation above. Thus, the internal stratigraphy of the flood basalt province contains palaeo-volcanic features, such as shield volcanoes, and other disconformities and is not that of a simple layer-cake model. This complex internal architecture indicates that flood volcanism started sporadically, with low volume pahoehoe flows of limited lateral extent, before establishing the more common large volume flows typical of the main lava pile.     

A comparison of biological trends from four marine ecosystems: Synchronies, differences, and commonalities

Major features of four marine ecosystems were analyzed based on a broad range of fisheries-associated datasets and a suite of oceanographic surveys. The ecosystems analyzed included the Gulf of Maine/Georges Bank in the Northwest Atlantic Ocean, the Norwegian/Barents Seas in the Northeast Atlantic Ocean, and the eastern Bering Sea and the Gulf of Alaska in the Northeast Pacific Ocean. We examined survey trends in major fish abundances, total system fish biomass, and zooplankton biomasses. We standardized each time series and examined trends and anomalies over time, using both time series and cross-correlational statistical methods. We compared dynamics of functionally analogous species from each of these four ecosystems. Major commonalities among ecosystems included a relatively stable amount of total fish biomass and the importance of large calanoid copepods, small pelagic fishes and gadids. Some of the changes in these components were synchronous across ecosystems. Major differences between ecosystems included gradients in the magnitude of total fish biomass, commercial fish biomass, and the timing of major detected events. This work demonstrates the value of comparative analysis across a wide range of marine ecosystems, suggestive of very few but none-the-less detectable common features across all northern hemisphere ocean systems.