Exsolution in ternary feldspars

It is shown that the microstructures of the antiperthites of the South Norwegian anorthosites strongly suggest an exsolution origin. In addition to the normal exsolution reactions responsible for most antiperthites, exsolution of potash feldspar in plagioclase may occur by a discontinuous mode of precipitation.     

Implementation and testing of a lateral boundary scheme as an open boundary condition in a barotropic ocean model

The flow relaxation scheme (FRS) is tested as an open boundary condition (OBC). This scheme was originally designed to relax external solutions (ES) from a large area model towards solutions in a limited area model with a fine mesh. When one uses the FRS as a pure OBC; i.e. the ES are unknown and set equal to zero, the FRS method degenerates to a sponge type OBC. Since a sponge type OBC does not work well in all cases, for instance in the case of an alongshore uniform wind; Chapman (1985) and Røed and Cooper (1987), we introduced local wind induced solutions as a part of the ES.When we also included the tide in the ES, the tests showed that the FRS method handled the tidal input problem very well. Even in the case where noise was added to the tide in the ES, the results were good.The major drawbacks for the FRS method are the required extention of the computer-space and -time.     

Results from microseismic monitoring,conventional instrumentation,and tomography surveys in the creation and thinning of a burst-prone sill pillar

Located in northern Québec, the Lac Shortt Mine was a small gold mine consisting of a thin subvertical orebody which was mined in three main phases. High stress and rockbursting conditions were experienced when ore was extracted in the upper zone between the surface and a depth of 500 metres during the first two phases of mining. Severe rockbursts were experienced in late 1989 near the shaft and in the footwall development following a deepening of the mine shaft to a depth of 830 m and partial development of footwall drift access for the third phase of mining (the mining of the lower zone starting at a depth of 830 m moving upward toward a depth of 500 m). A 16-channel Electrolab MP250 microseismic system, with a Queen's University Full-Waveform piggy-back system, was installed underground at the site due to these problems.It was expected that the thinning sill would be subjected to an ever-increasing load as the thickness of the 500 m sill pillar decreased in the face of the mining excavation from below. A monitoring program consisting of the microseismic monitoring system, a range of conventional geomechanics monitoring tools as well as the undertaking of periodic seismic tomography surveys to assess the ongoing state of stress and rock mass condition within the sill was therefore warranted.The anomalously high-magnitude stress field and the brittle rockmass created a situation in which rockmass failure was common and violent. In the creation and thinning of the sill pillar, the location of banded microseismic activity was crucial in tracing rockmass failure and the associated ground control problems. Reliable source-location determination enabled the identification of areas of stress increase. The movement of the rockmass failure front could be followed, and was responsible for stope dilution, footwall and orebody development deterioration, and caving.Source-mechanism analyses gave accurate double-couple solutions for approximately forty percent of these events having at least ten recognizable polarities. Results suggested movement along vertical north-south striking or vertical east-west striking features. Underground observation of damaged access points showed that vertical north-south striking joints were experiencing failure.The microseismic activity, which was consistently concentrated close to the southwest and northeast corners of current production stopes, could be explained by a stress field oriented obliquely to the strike of the orebody, as measured prior to shrinkage of the sill pillar byin situ stress measurements and observed borehole overbreaks. The orientations of theP andT axes for the microseismic activity further confirmed that the stress field oriented obliquely to strike.While an increase in compressional-wave velocity of 2.3 percent, corresponding to a measured stress increase of approximately 10 MPa could be measured by repeated tomographic surveys, it was relatively small and only a factor of two or so above the velocity measured uncertainty. The relative insensitivity of thein situ rock mass modulus to the applied stress is believed to be largely due to the rockmass discontinuities being relatively closed prior to stress increase, as substantiated by the small deformations seen by the extensometer and borehole camera. This situation existed because of the very high pre-mining stress level.The experimental demonstration that the rock could not absorb substantially increased load through the mechanism of discontinuity closure or tightening (which would be reflected in the modulus) may be evidence in itself of potentially burst-prone ground, such as encountered at Lac Shortt.     

Facies architecture and sedimentology of a meandering fluvial system: a Palaeogene example from the Weisselster Basin, Germany

The Schleenhain open pit coal mine, located 30 km south of Leipzig, Germany, exposes Upper Eocene and Oligocene non-marine strata representing fluvial deposition in the centre of the Weisselster Basin. Active mining and successive cuts provided the rare opportunity to obtain a three-dimensional perspective of laterally extensive surface outcrops. These were used to construct a detailed fence diagram, which provided the basis for recognition of key architectural elements in the weakly consolidated meandering stream deposits. In addition to the eight basic architectural elements of Miall (1985 ), the element SL (shallow lake deposits) was newly defined and the element CH (channel) was subdivided into CHg (palaeo-river system) and CHk (small channel). The profiles contain parts of two fining-upward cycles, which are separated by an unconformity spanning the Early Oligocene. Deposits of the first cycle begin with transverse sand bars (downstream accretion deposits-DA) and point bars (lateral accretion deposits-LA). The upper part of the cycle is represented by overbank fines (OF) and the element SL, which consists of laterally discontinuous lenses of dark, plant-bearing, kaolinite-rich clays, that were deposited in shallow lakes adjacent to the active channel. Coal seams interlayered with palaeosols are the main constituents of element OF. Sheetlike bodies of medium to fine gravels (gravel bars and bedforms-GB) on an erosive coal surface mark the beginning of the second cycle. Dissolution of underlying Permian salts and sulphates prior to, during, and after the deposition of the Palaeogene strata caused the development of two synclines within the outcrop. Coal seams and clay horizons which thicken and dip towards the centre of the synclines, provide evidence for their chronological development.     

On the causes of pressure oscillations in low‐permeable and low‐compressible porous media

Nonphysical pressure oscillations are observed in finite element calculations of Biot's poroelastic equations in low‐permeable media. These pressure oscillations may be understood as a failure of compatibility between the finite element spaces, rather than elastic locking. We present evidence to support this view by comparing and contrasting the pressure oscillations in low‐permeable porous media with those in low‐compressible porous media. As a consequence, it is possible to use established families of stable mixed elements as candidates for choosing finite element spaces for Biot's equations. Copyright © 2011 John Wiley & Sons, Ltd.     

Molecular characterization of uranium(VI) sorption complexes on iron(III)-rich acid mine water colloids

A mixing of metal-loaded acid mine drainage with shallow groundwater or surface waters usually initiates oxidation and/or hydrolysis of dissolved metals such as iron (Fe) and aluminum (Al). Colloidal particles may appear and agglomerate with increasing pH. Likewise chemical conditions may occur while flooding abandoned uranium mines. Here, the risk assessment of hazards requires reliable knowledge on the mobility of uranium (U). A flooding process was simulated at mesocosm scale by mixing U-contaminated acid mine water with near-neutral groundwater under oxic conditions. The mechanism of U-uptake by fresh precipitates and the molecular structure of U bonding were determined to estimate the mobility of U(VI). Analytical and spectroscopic methods such as Extended X-ray Absorption Fine-Structure (EXAFS) spectroscopy at the Fe K-edge and the U L_III-edge, and Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) spectroscopy were employed. The freshly formed precipitate was identified as colloidal two-line ferrihydrite. It removed U(VI) from solution by sorption processes, while surface precipitation or structural incorporation of U was not observed. EXAFS data suggest a mononuclear inner-sphere, edge-sharing complex of U(VI) with ferrihydrite in the absence of dissolved carbonate. By employing a novel EXAFS analysis method, Monte Carlo Target Transformation Factor Analysis, we could for the first time ascertain a 3-D configuration of this sorption complex without the necessity to invoke formation of a ternary complex. The configuration suggests a slightly tilted position of the adsorbed unit relative to the edge-sharing Fe(O, OH)₆ octahedra. In the presence of dissolved carbonate and at pH ∼8.0, a distal carbonate O-atom at ∼4.3 Å supports formation of ternary U(VI)-carbonato surface complexes. The occurrence of these complexes was also confirmed by ATR-FTIR. However, in slightly acidic conditions (pH 5-6) in equilibrium with atmospheric CO₂, the U(VI) sorption on ferrihydrite was dominated by the binary complex species Fe(O)₂UO₂, whereas ternary U(VI)-carbonato surface complexes were of minor relevance. While sulfate and silicate were also present in the mine water, they had no detectable influence on U(VI) surface complexation. Our experiments demonstrate that U(VI) forms stable inner-sphere sorption complexes even in the presence of carbonate and at slightly alkaline pH, conditions which previously have been assumed to greatly accelerate the mobility of U(VI) in aqueous environments. Depending on the concentrations of U(VI) and carbonate, the type of surface complexes may change from binary uranyl-ferrihydrite to ternary carbonato-uranyl-ferrihydrite complexes. These different binding mechanisms are likely to influence the binding stability and retention of U(VI) at the macroscopic level.     

Geology and paleomagnetism of El Potrero pluton, Baja California: Understanding criteria for timing of deformation and evidence of pluton tilt during batholith growth

The 102 Ma El Potrero pluton, in the western foothills of Sierra San Pedro Mártir, in north-central Baja California, was emplaced during a long period of contractional deformation bracketed between 132 and 85 Ma that affected this segment of the Peninsular Ranges Batholith. The pluton records regional and emplacement related deformation manifested by: (1) a solid-state fabric developed on its eastern contact, which is produced by eastward lateral pluton expansion; (2) cleavage triple point zones in the host-rock NW and SE of the pluton; (3) subhorizontal ductile shear zones indicative of top-to-the-east transport; (4) magmatic and tectonic foliations parallel to regional structural trends and regional shear zones; (5) variable axial ratios of microgranitoid enclaves close to pluton–wall rock contacts; (6) evidence of brittle-emplacement mechanisms in the western border of the pluton, which contrast with features indicating mainly ductile mechanisms toward the east; and, (7) markedly discordant paleomagnetic directions that suggest emplacement in an active tectonic setting. The overall mean for 9 accepted paleomagnetic sites is Dec = 34.6°, I = 25.7° (k = 88.3, α₉₅ = 5.5°), and is deviated  35° with respect to the reference cratonic direction. This magnetization is interpreted to indicate a combination of tilt due to initial drag during vertical diapiric ascent (or westward lateral-oblique expansion) of the adjacent San Pedro Mártir pluton and later rotation ( 15°) by Rosarito Fault activity in the southwest; this rotation may have occurred as eastward contraction acted to fill the space emptied by the ascending San Pedro Mártir pluton. The Rosarito fault may have tilted several plutons in the area (Sierra San Pedro Mártir, El Potrero, San José, and Encinosa). Magnetic susceptibility fabrics for 13 sites reflect mostly emplacement-related stress and regional stress. Paleomagnetic data and structural observations lead us to interpret the El Potrero pluton as a syntectonic pluton, emplaced within a regional shear zone delimited by the Main Mártir Thrust and the younger Rosarito Fault.