Poverty among inner‐city residents is associated with their marginal status in the labor market. Marginalization in the labor market begins during youth when important educational and employment decisions are made. Analysis of 1990 U.S. Census tract data for San Antonio, Texas identifies the lack of a high school diploma, poverty, non‐employment, and non‐enrollment in school as conditions of marginality for youth. Spatial patterns of youth labor market marginalization show concentrations in the inner city and in sectors on the West, South, and Eastside. Regression analysis reveals that levels of youth marginalization are associated with neighborhood context represented by the employment, behavioral, and ethnic characteristics of the overall residential population of a census tract. 相似文献
The ability to deduce exhumation mechanisms from thermochronological data is hampered by the fact that assumptions on the thermal state of the lithosphere have to be made. Additional argumentation is generally required to discriminate between erosion-controlled and tectonically induced exhumation. This problem can be overcome by studying the spatial distribution of zircon and apatite (U-Th)/He and fission track data. In this work the variation of four different low temperature isotopic systems generating age trends along a sampling line is used to infer mechanisms of Quaternary exhumation in the Central High Himalayan Metamorphic Belt. Observed zircon age trends with southwards increasing cooling ages (from 0.5 to 1.7 Ma) are attributed to tectonically induced exhumation. The uniform apatite cooling ages clustered c. 0.5 Ma are attributed to erosion. 相似文献
A number of technologies have been developed in the Planeta Research Center for Space Hydrometeorology to provide the satellite monitoring of sea ice cover and water parameters for the Caspian Sea. These technologies produce maps of sea ice, sea ice drift, tracking of near-surface water fluxes, automated classification of ice and water objects, surface wind, and sea surface temperature. Satellite-based products are used for operational hydrometeorology and climate studies of the Caspian Sea environment. A specialized web service for the preparation and comprehensive analysis of satellite data on hydrometeorological and ice conditions in the Caspian Sea was developed to provide information on ice cover characteristics, surface wind, and sea surface temperature. 相似文献
This study investigates the influence of low ozone episodes on UV-B radiation in Austria during the period 1999 to 2015. To this aim observations of total column ozone (TCO) in the Greater Alpine Region (Arosa, Switzerland; Hohenpeissenberg, Germany; Hradec Kralove, Czech Republic; Sonnblick, Austria), and erythemal UV-B radiation, available from 12 sites of the Austrian UV-B monitoring network, are analyzed. As previous definitions for low ozone episodes are not particularly suited to investigate effects on UV radiation, a novel threshold approach—considering anomalies—is developed to provide a joint framework for the analysis of extremes. TCO and UV extremes are negatively correlated, although modulating effects of sunshine duration impact the robustness of the statistical relationship. Therefore, information on relative sunshine duration (SDrel), available at (or nearby) UV-B monitoring sites, is included as explanatory variable in the analysis. The joint analysis of anomalies of both UV index (UVI) and total ozone (∆UVI, ∆TCO) and SDrel across sites shows that more than 65% of observations with strongly negative ozone anomalies (∆TCO < −1) led to positive UVI anomalies. Considering only days with strongly positive UVI anomaly (∆UVI > 1), we find (across all sites) that about 90% correspond to negative ∆TCO. The remaining 10% of days occurred during fair weather conditions (SDrel ≥ 80%) explaining the appearance of ∆UVI > 1 despite positive TCO anomalies. Further, we introduce an anomaly amplification factor (AAF), which quantifies the expected change of the ∆UVI for a given change in ∆TCO.
Precise positioning with the current Chinese BeiDou Navigation Satellite System is proven to be of comparable accuracy to the Global Positioning System, which is at centimeter level for the horizontal components and sub-decimeter level for the vertical component. But the BeiDou precise point positioning (PPP) shows its limitation in requiring a relatively long convergence time. In this study, we develop a numerical weather model (NWM) augmented PPP processing algorithm to improve BeiDou precise positioning. Tropospheric delay parameters, i.e., zenith delays, mapping functions, and horizontal delay gradients, derived from short-range forecasts from the Global Forecast System of the National Centers for Environmental Prediction (NCEP) are applied into BeiDou real-time PPP. Observational data from stations that are capable of tracking the BeiDou constellation from the International GNSS Service (IGS) Multi-GNSS Experiments network are processed, with the introduced NWM-augmented PPP and the standard PPP processing. The accuracy of tropospheric delays derived from NCEP is assessed against with the IGS final tropospheric delay products. The positioning results show that an improvement in convergence time up to 60.0 and 66.7% for the east and vertical components, respectively, can be achieved with the NWM-augmented PPP solution compared to the standard PPP solutions, while only slight improvement in the solution convergence can be found for the north component. A positioning accuracy of 5.7 and 5.9 cm for the east component is achieved with the standard PPP that estimates gradients and the one that estimates no gradients, respectively, in comparison to 3.5 cm of the NWM-augmented PPP, showing an improvement of 38.6 and 40.1%. Compared to the accuracy of 3.7 and 4.1 cm for the north component derived from the two standard PPP solutions, the one of the NWM-augmented PPP solution is improved to 2.0 cm, by about 45.9 and 51.2%. The positioning accuracy for the up component improves from 11.4 and 13.2 cm with the two standard PPP solutions to 8.0 cm with the NWM-augmented PPP solution, an improvement of 29.8 and 39.4%, respectively. 相似文献
Diffusion of water was experimentally investigated for melts of albitic (Ab) and quartz-orthoclasic (Qz29Or71, in wt %) compositions with water contents in the range of 0 to 8.5 wt % at temperatures of 1100 to 1200 °C and at pressures
of 1.0 and 5.0 kbar. Apparent chemical diffusion coefficients of water (Dwater) were determined from concentration-distance profiles measured by FTIR microspectroscopy. Under the same P-T condition and water content the diffusivity of water in albitic, quartz-orthoclasic and haplogranitic (Qz28Ab38 Or34, Nowak and Behrens, this issue) melts is identical within experimental error. Comparison to data published in literature
indicates that anhydrous composition only has little influence on the mobility of water in polymerized melts but that the
degree of polymerization has a large effect. For instance, Dwater is almost identical for haplogranitic and rhyolitic melts with 0.5–3.5 wt % water at 850 °C but it is two orders of magnitude
higher in basaltic than in haplogranitic melts with 0.2–0.5 wt % water at 1300 °C. Based on the new water diffusivity data,
recently published in situ near-infrared spectroscopic data (Nowak 1995; Nowak and Behrens 1995), and viscosity data (Schulze et al. 1996) for hydrous
haplogranitic melts current models for water diffusion in silicate melts are critically reviewed. The NIR spectroscopy has
indicated isolated OH groups, pairs of OH groups and H2O molecules as hydrous species in polymerized silicate melts. A significant contribution of isolated OH groups to the transport
of water is excluded for water contents above 10 ppm by comparison of viscosity and water diffusion data and by inspection
of concentration profiles from trace water diffusion. Spectroscopic measurements have indicated that the interconversion of
H2O molecules and OH pairs is relatively fast in silicate glasses and melts even at low temperature and it is inferred that
this reaction is an active step for migration of water. However, direct jumps of H2O molecules from one cavity within the silicate network to another one can not be excluded. Thus, we favour a model in which
water migrates by the interconversion reaction and, possibly, small sequences of direct jumps of H2O molecules. In this model, immobilization of water results from dissociation of the OH pairs. Assuming that the frequency
of the interconversion reaction is faster than that of diffusive jumps, OH pairs and water molecules can be treated as a single
diffusing species having an effective diffusion coefficient . The shape of curves of Dwater versus water content implies that increases with water content. The change from linear to exponential dependence of Dwater between 2 and 3 wt % water is attributed to the influence of the dissociation reaction at low water content and to the modification
of the melt structure by incorporation of OH groups.
Received: 26 March 1996 / Accepted: 23 August 1996 相似文献
Canister embedment of highly compacted Na bentonite forms a low-permeable medium of significant homogeneity both macro- and microscopically. However, despite the fact that a large part of the porewater is in interlamellar positions and not mobile by ordinary hydraulic gradients, there are still a number of pore passages that let water and gas through even at very high bulk densities. A preliminary model for flow and diffusion has been outlined on the basis of generalized, quantitative microstructural data and basic physical relationships. It accounts for actually recorded hydraulic and gas conductivities as well as for commonly measured swelling pressures. Qualitatively, it is in agreement also with published ion diffusion data. 相似文献
The language of transformational change is increasingly applied to climate policy, and particularly in climate finance. Transformational change in this context is used with respect to low-carbon development futures, with the emphasis on mitigation and GHG metrics. But, for many developing countries, climate policy is embedded in a larger context of sustainable development objectives, defined through a national process. Viewed thus, there is a potential tension between mitigation-focused transformation and nationally driven sustainable development. We explore this tension in the context of operationalizing the Green Climate Fund (GCF), which has to deal with the fundamental tension between country ownership and transformational change. In relation to climate finance, acceptance of diverse interpretations of transformation are essential conditions for avoiding risk of transformational change becoming a conditionality on development. We further draw lessons from climate governance and the development aid literature. The article examines how in the case of both the Clean Development Mechanism and Nationally Appropriate Mitigation Actions, there has been limited success in achieving both development objectives and ‘nationally appropriate’ mitigation. The development aid literature points to process-based approaches as a possible alternative, but there are limitations to this approach.
Policy relevance
The concept of transformational change has gained prominence in climate finance. The conundrum facing the GCF is that it seeks to support transformational change in the climate realm, in a context where countries may have competing priorities. Balancing or even transcending this tension is a fundamental design challenge for the GCF. A primary focus on mitigation, particularly if metrics of performance are tied exclusively to GHG reduction, raise concerns about diluting ownership by recipient countries and evokes concerns of conditionality or worse. The literature on development assistance has explored options notably conditions on process and adequate capacity, and suggests that there are no short cuts to building domestic ownership. Actors on climate change need to avoid the risk that transformational change is perceived as, and becomes, an imposed condition. The risk that transformation change, operationalized in the context of unequal power relations, becomes an imposition on development, needs to be avoided. 相似文献