Growth of multilayered polycrystalline reaction rims in the MgO–SiO<Subscript>2</Subscript> system,part II: modelling

Part I of this contribution (Gardés et al. in Contrib Mineral Petrol, 2010) reported time- and temperature-dependent experimental growth of polycrystalline forsterite-enstatite double layers between single crystals of periclase and quartz, and enstatite single layers between forsterite and quartz. Both double and single layers displayed growth rates decreasing with time and pronounced grain coarsening. Here, a model is presented for the growth of the layers that couples grain boundary diffusion and grain coarsening to interpret the drop of the growth rates. It results that the growth of the layers is such that (Δx)² ∝ t ^1−1/n , where Δx is the layer thickness and n the grain coarsening exponent, as experimentally observed. It is shown that component transport occurs mainly by grain boundary diffusion and that the contribution of volume diffusion is negligible. Assuming a value of 1 nm for the effective grain boundary width, the following Arrhenius laws for MgO grain boundary diffusion are derived: log D _gb,0^Fo (m²/s) = −2.71 ± 1.03 and E _gb^Fo = 329 ± 30 kJ/mol in forsterite and log D _gb,0^En (m²/s) = 0.13 ± 1.31 and E _gb^En = 417 ± 38 kJ/mol in enstatite. The different activation energies are responsible for the changes in the enstatite/forsterite thickness ratio with varying temperature. We show that significant biases are introduced if grain boundary diffusion-controlled rim growth is modelled assuming constant bulk diffusivities so that differences in activation energies of more than 100 kJ/mol may arise. It is thus important to consider grain coarsening when modelling layered reaction zones because they are usually polycrystalline and controlled by grain boundary transport.     

Use of deuterated water as a conservative artificial groundwater tracer

Conservative tracers are necessary to obtain groundwater transport velocities at the field scale. Deuterated water is an effective tracer for this purpose due to its similarity to water, chemical stability, non-reactivity, ease of handling and sampling, relatively neutral buoyancy, and reasonable price. Reliable detection limits of 0.1 mg deuterium/L may be obtained in field tests. A field example is presented in which deuterated water, bromide, and pentafluorobenzoic acid are used as groundwater tracers. Deuterated water appeared to be transported conservatively, producing almost identical breakthrough curves as that of other soluble tracers. Electronic Publication     

沈积岩石学

沈积学,在二十世纪初叶始渐起而为地质学中之新支,近数十年来随着石油工业之发达,而日趋蓬勃;一变昔日仅以岩石性质研究为沈积原因之解说,而侧重沈积作用及沈积环境之     

The influence of grain-size analysis methods and sediment mixing on curve shapes and textural parameters: Implications for sediment trend analysis

To this day, deterministic physical models capable of explaining the evolution of grain-size distributions in the course of transport are still lacking. For this reason, various attributes of particle frequency distributions, in particular curve shapes and textural parameters, have for many decades been investigated for potential information about transport behaviour and size-sorting processes of sediments in numerous environments. Such approaches are essentially conceptual and hence rely heavily on the validity of the assumptions on which they are based. A factor which has to date been largely ignored in this context, is the fact that different methods of grain-size analysis (e. g. sieving, laser absorption and diffraction, settling velocity measurements), when applied to the same sample material, produce variable curve shapes, and hence incongruous textural data. This is illustrated by selected examples showing the differences between sieving and settling results, conversion of settling velocities into equivalent settling diameters (psi-phi-transformations), and the influences of particle shape, particle density, and water temperature. It is demonstrated that particle-size distributions are not only method-dependent but also dependent on the adopted post-processing procedure. As a result, only frequency curves generated by the same method and subsequently processed by identical computational procedures can be meaningfully compared. Furthermore, the computation of textural parameters from bi- or multimodal size distributions produces spurious results which are unrelated to the processes leading to the mixing of different size populations frequently observed in nature. In such cases, only the decomposition of such distributions into individual populations and the spatial comparison of such populations makes any sense. Because a physical explanation for the generation of size distributions is lacking, a particular curve shape of a grain-size population has no meaning on its own. Only a systematic comparison of progressively changing curve shapes (and associated textural parameters) of sediments collected on a closely spaced grid can yield data suitable for sediment trend analysis.     

The Origin of Associated Basic and Acid Rocks in the Lebombo--Nuanetsi Igneous Province, Southern Africa, as implied by Strontium Isotopes

Whole rock Rb–Sr measurements were made on associatedbasic and acid intrusives and extrusives from the northern andsouthern ends of the Lebombo monocline with a view to determineif the acid rocks came from the mantle or from the crust. Inthe south, in Swaziland (now called Ngwame) and Zululand, rhyolitesand granophyres (age 202 14 m.y.) have an initial Si⁸⁷–Sr⁸⁶ratio of 0.7042 0.0005; in the north, in the Nuanetsi syncline,rhyolites (age 206 13 m.y.) and granites from ring complexes(age 177 7 m.y.) have initial ratios of 0.7081 0.0008 and0.7085 0.0007, respectively. The initial ratios of the basicrocks, basalts and gabbros, vary in both areas and have a rangefrom 0.7042 to 0.7125 which can be explained by crustal contamination.The low initial ratios and isotopic homogeneity of the acidmagmas over long distances (160 km) in Swaziland and Zululandare interpreted as implying that they were derived from themantle.     

Rates of iodine remineralization in terrigenous near-shore sediments

Much of the sedimentary geochemistry of iodine has been surmised from analyses of solid phase distributions without direct documentation of reactions or reaction rates. It is shown here that the anoxic production rate of dissolved I in nearshore terrigenous sediments decreases rapidly below the sediment-water interface and is strongly temperature controlled. An apparent activation energy of ~19.3 Kcal/mole comparable to that found for other microbially mediated reactions, describes the temperature dependence of release. Production of dissolved iodide is zeroth order with respect to natural ranges of pore water concentrations and apparently first-order with respect to a reactive I component in the solid phase. First order reaction coefficients in sediments from Mud Bay, South Carolina and Long Island Sound, Connecticut, U.S.A., are strongly depth dependent, varying from ~6.9/yr in the top few centimeters to an average of ~0.011/yr over the upper 70 cm. About 90% of the dissolved I flux comes from the top 10 cm with estimated values of ~ 15 and 29 μmoles/m²/day at 22–23°C in Mud Bay and Long Island Sound, respectively. The I/C net release ratio of decomposing material changes rapidly below the sediment surface. When temperature corrections are made, I remineralization rates from nearshore sediments below the bioturbated zone appear to be similar to those observed in deep water sediments underlying oxygenated waters.     

Watching meteors on Triton

The thin atmosphere of Neptune's moon Triton is dense enough to ablate micrometeoroids as they pass through. A combination of Triton's orbital velocity around Neptune and its orbital velocity around the Sun gives a maximum meteoroid impact velocity of approximately 19 km s⁻¹, sufficient to heat the micrometeoroids to visibility as they enter. The ablation profiles of icy and stony micrometeoroids were calculated, along with the estimated brightness of the meteors. In contrast to the terrestrial case, visible meteors would extend very close to the surface of Triton. In addition, the variation in the meteoroid impact velocity as Triton orbits Neptune produces a large variation in the brightness of meteors with orbital phase, a unique Solar System phenomenon.     

Search for H2 Emission from Disks around T Tauri and Herbig AE Stars

Preliminary results are presented of observations of the pure rotational lines of H2 toward T Tauri and Herbig Ae stars using the Short Wavelength Spectrometer (SWS) on the Infrared Space Observatory (ISO). The sources are selected to be isolated low- and intermediate-mass young stellar objects, for which the presence of a circumstellar disk has been established by millimeter interferometry. The lowest H2 S(0) and S(1) lines are detected in 3 out of 5 objects. The measured intensities indicate ∼ 0.01 M⊙ of warm (T ≈ 150 K) gas in the ISO beam. It is argued that for at least one case (HD 163296), the emission is probably dominated by the warm gas in the circumstellar disk rather than by shocked- or photon-heated gas in the surrounding envelope. Such observations can provide important constraints on the radial and vertical temperature profiles in circumstellar disks. This revised version was published online in August 2006 with corrections to the Cover Date.