振冲碎石桩处理黄土地基的效果分析

振冲碎石桩在不同的地基中有不同的作用,本文就某热电厂工程中用振冲碎石桩处理湿陷性黄土地基,消除地基的湿陷性;处理饱和(软)黄土地基,提高其承载能力,以及用振冲桩消除地基中饱和粉细砂的振动液化等效果,用试验和理论计算加以分析和讨论。     

生物炭对磷石膏中磷的固化作用

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。     

Scattering of elastic waves by a fracture zone containing randomly distributed cracks

We theoretically study the scattering ofP, SV andSH waves by a zonal distribution of cracks, which simulates a fault fracture zone. An investigation is conducted how the geometrical properties of the crack distribution and the frictional characteristics of the crack surface are reflected in the attenuation and dispersion of incident waves, as well as in the amplitudes of the transmitted and reflected waves from the zone. If the crack distribution within the fault zone changes temporally during the preparation process of the expected earthquake, it will be important for earthquake prediction to monitor it, utilizing the scattering-induced wave phenomena.We consider the two-dimensional problem. Aligned cracks with the same length are assumed to be randomly distributed in a zone with a finite width, on which elastic waves are assumed to be incident. The distribution of cracks is assumed to be homogeneous and sparse. The crack surface is assumed to be stress-free, or to undergo viscous friction; the latter case simulates fluid-filled cracks. The opening displacement of the crack is assumed to be negligibly small. The idea of the mean wave formalism is employed in the analysis, and Foldy's approximation is assumed.When the crack surface is stress-free, it is commonly observed for every wave mode (P, SV andSH) that the attenuation coefficientQ ^–1 peaks aroundka1, the phase velocity is almost independent ofk in the rangeka<1 and it increases monotonically withk in the rangeka>1, wherek is the intrinsicS wavenumber anda is the half length of the crack. The effect of the friction is to shift the peak ofQ ^–1 and the corner of the phase velocity curve to the low wavenumber range. The high wavenumber asymptote ofQ ^–1 is proportional tok ^–1 independently of model parameters and the wave modes. If the seismological observation thatQ ^–1 ofS waves has a peak at around 0.5 Hz in the earth's crust is combined with our results, the upper limit of crack size within the crust is estimated about 4 km. The information regarding the transmitted and reflected waves, such as the high wavenumber limit of the amplitude of the transmitted wave etc., allows estimation of the strength of the friction.     

Study on the kinetics of iron oxide leaching by oxalic acid

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.     

Are the South and North Liaohe Groups of North China Craton different exotic terranes? Nd isotope constraints

The Liaohe Group is an important Paleoproterozoic stratigraphic unit in the northeastern part of the North China Craton and is traditionally subdivided into the North and South Liaohe Groups. Associated with both the North and South Liaohe Groups are voluminous Paleoproterozoic granitoid rocks, named the Liaoji granitoids. Different tectonic models, including terrane amalgamation, continent–arc collision and rift closure, have been proposed to interpret the tectonic setting and evolution of the North and South Liaohe Groups and associated Liaoji granitoids. At the centre of the controversy between these models is whether or not the North and South Liaohe Groups developed on the same Archean basement. Nd isotopic geochemistry of the Liaoji granitoids provides important constraints on this controversial issue. The Liaoji granitoids associated with the North and South Liaohe Groups display similar ε_Nd values, restricted to a narrow range from 0 to 2, implying that these granitoid rocks were derived from the same or a similar magma source. Moreover, the Liaoji granitoids associated with the North and South Liaohe Groups have similar Nd model ages (T_DM), ranging from 2.4 to 2.6 Ga, suggesting that the protoliths of the Liaoji granitoids associated with both groups may have formed simultaneously, and that the basement rocks underneath the Liaoji granitoids and associated North and South Liaohe Groups belong to the same continental block rather than two different blocks. Combining lithological, structural and geochronological considerations, we interpret the North and South Liaohe Groups as having developed on a single late Archean basement that underwent Paleoproterozoic rifting associated with the intrusion of the Liaoji granitoids and the formation of the Liaohe Group, and closed upon itself in the Paleoproterozoic.     

藏西北三岔口地区泥瓮系生物礁特征及其意义

在羌塘西部的三岔口一带泥盆系拉竹龙组中发现规模较大的生物礁——台地前缘礁。下层礁体厚7．28m，上层礁体厚40.98m。两个礁体均为叠置礁，礁体由礁基、礁核、礁顶组成。剖面显示发育有礁前垮塌角砾、礁格架、礁间及礁后环境。泥盆纪生物礁的发现为羌塘盆地寻找油气资源提供了新思路。     

Estimating the minimum in-stream flow requirements via wetted perimeter method based on curvature and slope techniques

Under the assumptions of triangular cross section channel and uniform stable flow, an analytical solution of the minimum ecological in-stream flow requirement (MEIFR) is deduced. Based on the analytical solution, the uncertainty of the wetted perimeter method is analyzed by comparing the two techniques for the determination of the critical point on the relationship curve between wetted perimeter, P and discharge, Q. It is clearly shown that the results of MEIFR based on curvature technique (corresponding to the maximum curvature) and slope technique (slope being 1) are significantly different. On the P-Q curve, the slope of the critical point with the maximum curvature is 0.39 and the MEIFR varied prominently with the change of the slope threshold. This indicates that if a certain value of the slope threshold is not available for slope technique, curvature technique may be a better choice. By applying the analytical solution of MEIFR in the losing rivers of the Western Route South-to-North Water Transfer Project in China, the MEIFR value via curvature technique is 2.5%-23.7% of the multi-year average annual discharge, while that for slope technique is 11%-105.7%. General conclusions would rely on the more detailed research for all kinds of cross-sections.     

Towards models of strategic spatial choice behaviour: theory and application issues

Models of spatial choice behaviour have been around in geography urban planning for decades to assess the feasibility of planning actions or to predict external (competition) effects on existing destinations. Although these models differ in terms of complexity and key concepts, they all have in common that spatial choice behaviour is predicted as a function of the attributes of the choice alternatives and distance or travel time separation only. None of these models do take into account that the attributes of choice alternatives and travel time may be highly non-stationary and that often the utility that people derive from visiting a particular location also depends on the choice behaviour of other individuals. Under these circumstances, individuals may exhibit strategic choice behaviour. That is, they will choose particular choice options taking into account their expected behaviour of others such as to maximize their own utility. The purpose of the proposed paper is to discuss possible models of strategic choice behaviour for these urban planning problems. Theory will be outlined and some critical issues in the application of such models to problems of spatial choice will be discussed.     

基于IMAGIS的数字小区建模探讨

随着城市化水平的不断提高，对城市的规划管理也提出了很高的要求，数字城市作为数字地球的重要组成部分正是在这一背景下提出的。本文结合适普公司的IMAGIS软件，对城市小区鼍维场景建设中的相关问题进行了探讨，并以遂宁市某街区为例进行了实践。     

从电法勘探资料分析宋楼煤矿主斜井突水因素

根据宋楼煤矿主斜井直流电法勘探资料及矿井地质及水文地质条件的分析,煤矿主斜井突水原因应该是来自第四系砂砾石含水层及深层地下岩溶水。通过电法勘探确定裂隙发育带、富水区域、涌水部位,对此处实施钻孔注浆堵水后,恢复生产。