构造-蚀变岩相填图方法在南秦岭汉阴黄龙金矿中的应用

随着新一轮全国危机矿山找矿工作的开展,低成本、高效率的就矿找矿理论和方法对于一些老矿区的深部和外围找矿尤为重要。矿区构造-蚀变岩相填图的范围就是矿区勘查范围,在填图过程中把控岩构造、控矿构造、矿化蚀变等信息作为填图重点,以矿区地质图为底图,把野外填图过程中收集到的有关控矿构造、矿化蚀变等信息分期次,分不同特征等标示在底图上,形成控岩控矿构造实际材料图,在实际材料图基础上,编制矿区构造-蚀变岩相图,从而寻找主要的控矿构造和与矿化密切相关的蚀变岩相带,并为下一步矿区外围和深部找矿、工程布置提供靶区依据。黄龙金矿区位于扬子板块北缘南秦岭构造带,矿区志留系梅子垭组地层经历了多期构造变形,并叠加有区域变质和热液变质作用。本研究采用构造-蚀变岩相填编图的方法,在矿区填编出了3条脆-韧性剪切带和黑云母变斑晶化、硅化等蚀变岩相带,并认为脆-韧性剪切带、黑云母变斑晶化带、硅化带及蚀变岩相叠加带等蚀变与金矿体存在密切关系,是矿区下一步外围及深部找矿的重点靶区。     

陕西省洛南地区二叠系石盒子组砂岩特征及物源区探讨

为了认识陕西省洛南地区二叠系石盒子组砂岩特征及其物源,给探索渭河盆地前新生代基底组成提供依据,本文综合分析了洛南二叠系石盒子组砂岩组分和重矿物特征。结果表明,砂岩物源区主要为再旋回造山带和克拉通地块,物源区与北秦岭造山带的演化关系密切,南秦岭构造带北部下古生界也为石盒子组提供部分物源,中二叠世晚期华北、秦岭板块面接触碰撞,北秦岭构造带快速隆升,南秦岭物源区提供物源减少,砂岩物源主要为中酸性岩浆岩+低级变质岩+沉积岩。二叠纪鄂尔多斯盆地南缘向南延至洛南—栾川断裂附近,洛南地区二叠系石盒子组河流沼泽相含煤岩系沉积应该属于鄂尔多斯盆地南缘沉积,结合渭北—渭河—洛南地区晚古生代地层对比成果,认为渭河地区二叠纪至少曾沉积过二叠系石盒子组地层,渭河新生代盆地基底具有残存二叠系的可能。     

Estimates of potential nitrate reductase activity in sediments: comparisons of two incubation methods and four inhibitors

Sediment samples, collected from a large shallow lake, Taihu, China, were incubated in two conditions (with and without air extraction) with regard to four soil enzyme’s inhibitors (dry and moist heat sterilizations, chloramphenicol and toluene) to estimate the potential nitrate reductase (Nar) activities. The objectives of paper were to define (1) whether to exclude air from the mixture of sediment and substrate solution prior to incubation was necessary, and (2) the efficacy of four inhibitors when assaying the enzyme. No significant difference between two incubation methods was found (P < 0.05), indicating that it is not necessary for estimating the potential Nar activity in the sediment to construct an initial anaerobic condition by air extractions prior to incubation. Toluene (1.0 mL/g sediment) and dry heat sterilization effectively and persistently inhibit the reduction of nitrate to nitrite during the incubation of 42 h. The authors concluded that both should be used as preferred inhibitors. In contrast, chloramphenicol (30 μg/g sediment) and moist heat sterilization inhibitors restrained nitrate reduction for <24 h only. In addition, it was found that no nitrite produced was substantially reduced in 24 h. Therefore, it should be needless for potential Nar activity estimation in the sediment to add 2,4-dinitrophenol to inhibit nitrite reductase.     

吉林龙冈火山群金龙顶子火山喷发物中幔源包体的基本特征及其地质意义

龙冈火山群金龙顶子火山喷发发生在距今1500年前,其火山喷发物中所含的幔源橄榄岩包体是我国在最新火山喷发物中所发现的幔源包体。这些包体以普遍含有韭闪石为特征。包体的结构和位错构造反映这些包体在上地幔条件下经历过一定程度的变形作用。包体的平衡温度大多数集中在800～950℃之间,只有个别样品温度达到1050℃;平衡压力大多数集中在1.0～1.5 GPa之间。由包体平衡温度、压力得到的上地幔地温线稍低于中国东部由新第三纪包体得到的上地幔地温线,但接近第四纪包体得到的地温线。包体在上地幔条件下变形时的差异应力在30～44MPa,应变速率为10-18s-110-15s-1。角闪石的出现反映上地幔流体的渗透及交代作用。金龙顶子火山发的玄武岩浆直接来自35～50km的上地幔顶部。     

喀斯特微观溶蚀机理研究

通过溶蚀孔隙的扫描电镜观察,讨论了喀斯特微观溶蚀机理,认为水-岩界面的选择性溶蚀是最本质的特征,化学成分和矿物结构是选择性溶蚀的两个重要方面。同时对微裂隙尖墙的溶蚀特点,提出了形成囊状溶孔的机制。     

Geochronological and geochemical evidence for a Late Ordovician to Silurian arc-back-arc system in the northern Great Xing'an Range,NE China

The early Paleozoic tectonic evolution of the Xing'an-Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing'an Block,i.e.,the Xinlin-Xiguitu Ocean and the Nenjiang Ocean.However,the early development of the Nenjiang Ocean remains unclear.Here,we present zircon U-Pb geochronology and whole-rock elemental and Sr-Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area.LA-ICP-MS zircon U-Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443-436 Ma and 452-451 Ma,respectively.The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs,and depleted in HFSEs,with relatively low U/Th ratios of 0.18-0.36 andεNd(t)values of-1.6 to+0.5.These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts,consistent with a back-arc basin setting.By contrast,the andesitic tuffs are characterized by high MgO(>5 wt.%),Cr(138-200 ppm),and Ni(65-110 ppm)contents,and can be termed as high-Mg andesites.Their low Sr/Y ratios of 15.98-17.15 and U/Th values of 0.24-0.25 and moderate(La/Sm)_n values of 3.07-3.26 are similar to those from the Setouchi Volcanic Belt(SW Japan),and are thought to be derived from partial melting of subducted sediments,and subsequent melt-mantle interaction.The Duobaoshan basalts have high Nb(8.44-10.30 ppm)and TiO2 contents(1.17-1.60 wt.%),typical of Nb-enriched basalts.They are slightly younger than regional adakitic rocks and have positiveεNd(t)values of+5.2 to+5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts.Synthesized with coeval arc-related igneous rocks from the southeastern Xing'an Block,we propose that the Duobaoshan high-Mg andesitic tuffs and Nbenriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi-Duobaoshan arc belt,and they were formed by the northwestern subduction of the Nenjiang Ocean.Such a subduction beneath the integrated Xing'an-Erguna Block also gave rise to the East Ujimqin-Xinglong igneous belt in a continental back-arc basin setting.Our new data support an early Paleozoic arc-back-arc model in the northern Great Xing'an Range.     

An extensive erosion surface of a strongly deformed limestone bed in the Gushan and Chaomidian formations (late Middle Cambrian to Furongian), Shandong Province,China: Sequence–stratigraphic implications

In order to understand sequence development and sea-level fluctuations during the late Middle Cambrian to early Furongian on the North China epeiric platform, the present study focuses on a unique, subtle erosion surface of an extensive (approx. 100 km), strongly deformed limestone bed in the uppermost part of the Gushan Formation, Shandong Province, China. The Gushan Formation and the overlying Chaomidian Formation consist mainly of shales and a variety of carbonates that were deposited in subtidal environments (e.g., deep subtidal, shallow subtidal, shoreface/shoal, subtidal microbial flat, and restricted platform interior). Three third-order depositional sequences (S1–3) are identified, each of which comprises a thin transgressive systems tract (TST) and a relatively thick highstand systems tract (HST). Each sequence is bounded by a drowning unconformity (SB1), a subaerial unconformity (SB2), or a surface of submarine erosion (SB3). The upper sequence boundary (SB2) of sequence 1 (S1) is represented by a subtle erosion surface of an extensive, deformed limestone bed with a wide variety of soft-sediment deformation structures (e.g., lime mudstone breccias, chaotic wacke-packstone laminae and fragments, homogenized oolites, and clastic dykes), and is overlain by small sporadic microbial buildups and an extensive bioclastic grainstone bed. The deformed limestone was formed during early diagenesis by differential deformation processes (brecciation, liquefaction/fluidization, and injection) which were most likely induced by pore-water overpressure during the period of rapid sea-level fall. Despite the lack of subaerial exposure features (e.g., paleokarst, paleosol, etc.), the characteristics of the erosion surface (cutting well-lithified sediment below), the missing of a significant geological record (the Prochuangia biozone), and the worldwide correlatable positive carbon isotope excursion collectively indicate that the erosion surface developed under conditions of subaerial exposure after contemporaneous marine cementation of the deformed sediment. The missing of the Prochuangia biozone is most likely due to non-deposition at a subaerial hiatal surface. The erosion surface was submerged as a result of subsequent rise in sea level, where sporadic microbial buildups formed under suitable conditions. Freshly deposited, winnowed, shell-dominated transgressive lag deposits (containing Chuangia trilobite fragments, brachiopod shells, and abundant glauconite grains) formed with continued rise in sea level, which became, in turn, overlain by shale-dominated facies. The unique combination of the subtle erosion surface (sensu stricto a subaerial unconformity) and the underlying deformed limestone bed provides an important criterion for recognizing the subtle changes in relative sea level on shallow epeiric platforms.     

基于软硬石模板库的土石混合体细观损伤与力学特性分析

为了探究含软、硬两种岩性碎块石土石混合体的变形破坏过程与力学性质,发展了一种基于软硬石模板库的土石混合体建模方法。通过在PFC2D中建立符合原位结构特征的软硬石模板库,利用此模板库生成了不同含石量土石混合体颗粒流模型,对土石混合体进行了单轴压缩颗粒流模拟。结果表明：土石混合体破坏始于土-石接触面,土石介质分离大多因剪切破坏导致,加载前期微裂纹迅速增长,中、后期微裂纹增长速率减缓,但宏观变形渐趋显著;随着含石量的增加,土石混合体单轴抗压强度逐渐降低,块石的转动与侧向移动会加剧土石混合体的整体破坏;相同含石量下,随着软石比例的增加,单轴抗压强度呈下降趋势,试验后试样破裂率与单个软石颗粒的破裂程度均保持在较高水平,软石颗粒破裂是引起土石混合体单轴抗压强度降低的重要原因。