Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.     

Morphology and Luminosity Segregations in Galaxy Groups

We study morphology and luminosity segregation of galaxies in groups. We analyze the two catalogs of (∼2×400) groups which have been identified in the Nearby Optical Galaxy sample, by means of hierarchical and percolation `friends-of-friends' methods. We find that earlier-type (brighter) galaxies are more clustered and lie closer to the group centers, both in position and in velocity, than later-type (fainter) galaxies. Spatial segregations are stronger than kinematical segregations. These effects are generally detected at the ≳3-sigma level, with the exception of morphological segregation in velocity, which is the weakest effect. Our main results are confirmed by the analysis of statistically more reliable groups (with at least five members), and are strengthened by the detection of segregation in both hierarchical and percolation catalogs. Luminosity segregation is shown to be independent of morphology segregation. Our conclusions agree with a continuum of segregation properties of galaxies in systems, from low-mass groups to massive clusters. This revised version was published online in July 2006 with corrections to the Cover Date.     

Speckle interferometry observations of asteroids at tng

The Speckle camera of the 3.5 m Telescopio Nazionale Galileo (TNG) has been used to measure apparent sizes and shapes of a number of main belt asteroids. The average size measurements are in a generally good agreement with the results of indirect IRAS-based radiometric techniques. The measured shapes are compared with predictions based on previously derived spin axis directions and lightcurve photometry of some of the observed objects. Also in this case the agreement is reasonable and the speckle observations allow us to discriminate in some cases between the two pole solutions usually found for each object. No clear evidence of binaries was found. The results show that the TNG speckle camera can be a powerful tool to resolve relatively large main belt asteroids and to calibrate the results of the IRAS survey.     

Resonant and Secular Families of the Kuiper Belt

We review ongoing efforts to identify occupants of mean-motion resonances(MMRs) and collisional families in the Edgeworth–Kuiper belt. Directintegrations of trajectories of Kuiper belt objects (KBOs) reveal the 1:1(Trojan), 5:4, 4:3, 3:2 (Plutino), 5:3, 7:4, 9:5, 2:1 (Twotino), and 5:2 MMRsto be inhabited. Apart from the Trojan, resonant KBOs typically have largeorbital eccentricities and inclinations. The observed pattern of resonanceoccupation is consistent with resonant capture and adiabatic excitation bya migratory Neptune; however, the dynamically cold initial conditions priorto resonance sweeping that are typically assumed by migration simulationsare probably inadequate. Given the dynamically hot residents of the 5:2 MMRand the substantial inclinations observed in all exterior MMRs, a fraction ofthe primordial belt was likely dynamically pre-heated prior to resonancesweeping. A pre-heated population may have arisen as Neptune gravitationallyscattered objects into trans-Neptunian space. The spatial distribution of Twotinosoffers a unique diagnostic of Neptune's migration history. The Neptunian Trojanpopulation may rival the Jovian Trojan population, and the former's existence isargued to rule out violent orbital histories for Neptune. Finally, lowest-order seculartheory is applied to several hundred non-resonant KBOs with well-measured orbitsto update proposals of collisional families. No convincing family is detected.     

Observations of SN1988A with the faint object spectrograph on the 4.2 m William Herschel Telescope

We present two spectra of the supernova SN1988A in M58 (NGC4579) over the wavelength range 4000–9700 Å, as recorded by the Faint Object Spectrograph on the 4.2 m William Herschel Telescope at the Observatorio del Roque de los Muchachos. We conclude that SN1988A was a type II supernova.     

Observation and preliminary analysis of a recent Jovian satellite phenomenon

The occultation of Io by Ganymede as observed on 10 June 1985 is reported. The middle of the occultation minimum was found to occur at 14h 14m 5.7s UT. In the plane perpendicular to the line of sight the centres of the two satellite disks passed to within ~ 2530 km of each other, at a relative velocity, in this plane, of about 11 kms^–1. The values of these last two quantities, however, depend on what assumptions are made about the light distribution over io's disk.     

A neural network approach to ship track-keeping control

This paper presents an on-line trained neural net work controller for ship track-keeping problems. Following a brief review of the ship track-keeping control development since the 1980's, an analysis of various existing backpropagation-based neural controllers is provided. We then propose a single-input multioutput (SIMO) neural control strategy for situations where the exact mathematical dynamics of the ship are not available. The aim of this study is to build an autonomous neural controller which uses rudder to regulate both the tracking error and heading error. During the whole control process, the proposed SIMO neural controller adapts itself on-line from a direct evaluation of the control accuracy, and hence the need for a “teacher” or an off-line training process can be removed. With a relatively modest amount of quantitative knowledge of the ship behavior, the design philosophy enables real time control of a nonlinear ship model under random wind disturbances and measurement noise. Three different track-keeping tasks have been simulated to demonstrate the effectiveness of the training method and the robust performance of the proposed neural control strategy