Identification of dissolved and particulate carbonyl compounds produced by marine harmful algal bloom species

Carbonyl compounds, especially polyunsaturated aldehydes (PUAs), are increasingly reported as teratogenic to grazers and deleterious to phytoplankton. While PUAs have been considered to be mainly produced by diatoms after cell wounding, little is known about whether microalgae other than diatoms, particularly harmful algal bloom (HAB)-forming species, produce carbonyl compounds. In this study, we analyzed the carbonyl compounds from eight common HAB-forming species ( Akashiwo sanguinea , Karenia mikimotoi , Karlodinium venefi cum , Margalefi dinium polykrikoides , Prorocentrum donghaiense , P . minimum , Scrippsiella trochoidea , and Heterosigma akashiwo ) using gas chromatography-mass spectrometry in full scan and selected ion monitoring (SIM) modes. Our results show a ubiquitous presence of carbonyl compounds in both dissolved and particulate forms in all species we examined. In the full scan mode, 133 chromatographic peaks were detected from 51 samples altogether. Both the varieties of carbonyl compounds and their quantities were algal species dependent, although most of the carbonyl compounds could not be fully identifi ed according to the mass spectral database only due to the unavailability of enough standards for all analytes. Aided with nine standards in SIM mode, we further identifi ed and quantifi ed all nine aldehydes (2-methyl-2-pentenal, trans-2-nonenal, cis-6-nonenal, 2,6-dimethyl-5-heptenal, trans-2-hexenal, trans-2- decenal, 2,4-heptadienal, trans-trans-2,4-octadienal, and trans-trans-2,4-decadienal). Four of these nine aldehydes were detected in particulate form, which confi rmed that trans-2-nonenal could be produced by K . mikimotoi , Karl . venefi cum , P . donghaiense , P . minimum , S . trochoidea , and H . akashiwo , 2,4-heptadienal and trans-trans-2,4-decadienal by A . sanguinea , M . polykrikoides , and S . trochoidea , and trans, trans-2,4- octadienal by S . trochoidea , respectively. We proved that some dinofl agellate and raphidophyte species could contribute to the pool of carbonyl compounds including PUAs in a marine ecosystem. Some carbonyl compounds, particularly those in high cell quota and/or dissolved concentration, may be related to fi shkilling or allelopathy which needs further identifi cation and quantifi cation.     

Opportunistic-tended life history traits of Siniperca kneri in the Three Gorges Reservoir,China: potential responses to impoundment

Reservoir impoundment changes original fluvial habitats into lentic environments. Fish species adapted to lentic habitats may take the advantage of such habitat changes and show typical life history traits might facilitate the population increase. Siniperca kneri rarely occurred in fishery landing in the Three Gorges Reservoir (TGR) area before its impoundment in 2003, but it is now a dominant species. In this study, a total of 438 females of S . kneri were collected monthly during September 2012 through January 2014 using gill nets in the TGR. The age, growth, and reproductive biology were then investigated, and compared with other S . kneri populations. The standard length at age 1 was 149.9 mm in the TGR, which is larger than the three compared populations (i.e., Sandaohe Reservoir, Xinfengjiang Reservoir, and North River), but smaller than one (the Guishi Reservoir). The youngest mature female in the TGR was age 1, which is younger than that of the two compared populations (i.e., Xinfengjiang Reservoir and the North River). The relative fecundity in the TGR was 140 eggs/g, which is higher than that of the only available compared population (Xinfengjiang Reservoir, 96 eggs/g). Our results demonstrated that S . kneri in the TGR tended to have faster growth in the first year, a younger age at first maturation, and higher reproductive eff ort. We suggest that such opportunistic-tended life history traits might facilitate rapid increase of the population.     

GPS/PWV时间序列特征提取方法的研究

针对GAMIT/GLOBK软件解算得到的4 a GPS/PWV时间序列的特征提取问题,提出基于滤波辅助的部分集成经验模态分解（PEEMD）与Hilbert谱分析相结合的特征提取方法。首先,在PEEMD方法的基础上,结合滤波辅助的PEEMD方法与Hilbert谱分析,建立GPS/PWV时间序列特征提取模型;然后,将所提出的方法应用于TNML测站4 a的GPS/PWV长时间序列和7 d的GPS/PWV短时间序列分析中,并将滤波辅助的PEEMD结果与传统的小波分解结果进行对比。结果表明,该特征提取方法能准确有效地提取出 GPS/PWV时间序列中的周年周期和日周期特征分量,滤波辅助的PEEMD分解结果与小波分解结果一致,且提取的特征分量与原始信号更加吻合。     

华南石炭纪中期白云岩地层分布及其形成模式

石炭纪是地质演化历史上重要的时期,发生了全球规模的海西造山运动,晚古生代大冰期（LPIA）达到峰值,全球海平面频繁波动,导致古气候和古环境的剧烈变化。在华南,石炭纪中期,浅水碳酸盐岩台地相区广泛发育一套白云岩沉积。本文系统总结华南3个主要碳酸盐台地内白云岩的厚度及时代,识别出白云岩时空分布的差异性。结合石炭纪中期全球气候环境特征,认为冰期兴盛引发了全球海平面下降,导致华南各沉积盆地形成利于白云岩化的环境,白云岩得以发育。而白云岩时空分布的差异性可能与各沉积盆地独特的构造演化以及不同成岩模式有关。中下扬子碳酸盐岩台地白云岩的形成模式主要为萨勃哈模式和成岩早期浅埋藏的渗透回流模式,形成相对较薄的白云岩沉积;中南部和西南部碳酸盐岩台地白云岩的形成模式为渗透回流模式,成岩规模较大,沉积较厚。     

空间分辨率对中国夏季降水时空演变特征的影响

本文使用1979—2021年国家气候中心160站(R₁₆₀)和国家级地面气象观测站2 314站(R₂₃₁₄)逐月降水观测资料,利用EOF (Empirical Orthogonal Function)分解和相关分析等方法,研究两类资料夏季降水时空变化特征及其与海气因素之间物理联系的表征水平差异,并分析了差异的可能原因。结果表明,R₁₆₀在我国西北、青藏高原等地区站点极为稀疏,导致其各EOF模态对上述地区降水的时空变化特征描述失真,中东部地区偏低的空间分辨率会使局地强降水的变化特征信号损失,造成降水的年际变率降低。而R₂₃₁₄主模态能够更为真实地反映我国降水的时空演变特征,特别是在极端降水频发的江淮地区以及降水受局地地形影响较大的山区,其EOF主模态的空间分布和时间系数演变与ENSO (El Niño-Southern Oscillation)、西太平洋副热带高压、青藏高原雪盖等气候强迫信号之间的相关性更为显著。     

Effects of Hypoxia on Dopamine Concentration and the Immune Response of White Shrimp （Litopenaeus vannamei）

Effects of hypoxia on the dopamine concentration and the immune response of White Shrimp Litopenaeus vannamei were studied. The results showed that hypoxia had significant effects on the concentration of dopamine (DA) in the haemolymph, haemocyte count, phenoloxidase activity, phagocytic activity of haemocytes and bacteriolytic and antibacterial activity in the haemolvmph (P<0.05). The concentration of the dopamine in haemolymph reached its maximum in the 3.0 and 1.5mgL-1 DO groups at 12h and 6h, and then returned to normal after 24h and 12h, respectively. All immune parameters decreased with the reduction of dissolved oxygen. Total haemocyte count (THC), the hyaline cells and semi-granular cells in the 3.0mgL-1 DO group became stable after 12h,while granular cells did so after 24h, The THC and different haemocyte count (DHC) in the 1.5mgL-1 DO group became stable alter 24h. Phenoloxidase activity and bacteriolytic activity in the 3.0 and 1.5mgL-1 DO groups reached their stable levels after 24 h and 12 h respectively, while phagocytic activity and antibacterial activity became stable after 24 and 12, and 36 and 24 It, respec-tively. It was also indicated that the changes of dopamine concentrations in haemolymph, haemocyte count and phenoloxidase activ-ity were obviously related to the exposure time under hypoxic conditions.     

解决了一场地质学争议的岩石

一个跨国研究小组在最近一期《自然》杂志上报道：在27亿年以前的太古时代,一种稀有的岩浆岩叫做科马提岩（komatiite）,形成于大约1700℃的地幔中。     

火星着陆器研究新土样

美国国家航空航天局的官员称,该局的“凤凰”号着陆器又将一份火星土样送到着陆器上搭载的湿化学实验室里。     

基于FME的土地管理数据共享途径的探讨

对空间数据共享的实现方法及土地管理数据进行了简单介绍,在分析FME体系结构的基础上给出了在土地管理中利用FME解决问题的实例,同时探讨了利用FME Objects及FME Server实现土地管理数据共享的具体开发方案。     

GNSS形变监测中系统误差的时空相关性研究

通过大量实测数据分析了系统误差的时空变化规律,论证了具有时空相关性的双差观测值系统误差残差的存在,实现了观测值的滤波及求差,提高了分离微小形变量的精度。