Two Periods of Skarn Mineralization in the Baizhangyan W–Mo Deposit,Southern Anhui Province,Southeast China: Evidence from Zircon U–Pb and Molybdenite Re–Os and Sulfur Isotope Data

The recently discovered Baizhangyan skarn‐porphyry type W–Mo deposit in southern Anhui Province in SE China occurs near the Middle–Lower Yangtze Valley polymetallic metallogenic belt. The deposit is closely temporally‐spatially associated with the Mesozoic Qingyang granitic complex composed of g ranodiorite, monzonitic g ranite, and alkaline g ranite. Orebodies of the deposit occur as horizons, veins, and lenses within the limestones of Sinian Lantian Formation contacting with buried fine‐grained granite, and diorite dykes. There are two types of W mineralization: major skarn W–Mo mineralization and minor granite‐hosted disseminated Mo mineralization. Among skarn mineralization, mineral assemblages and cross‐cutting relationships within both skarn ores and intrusions reveal two distinct periods of mineralization, i.e. the first W–Au period related to the intrusion of diorite dykes, and the subsequent W–Mo period related to the intrusion of the fine‐grained granite. In this paper, we report new zircon U–Pb and molybdenite Re–Os ages with the aim of constraining the relationships among the monzonitic granite, fine‐grained granite, diorite dykes, and W mineralization. Zircons of the monzonitic granite, the fine‐grained granite, and diorite dykes yield weighted mean U–Pb ages of 129.0 ± 1.2 Ma, 135.34 ± 0.92 Ma and 145.3 ± 1.7 Ma, respectively. Ten molybdenite Re–Os age determinations yield an isochron age of 136.9 ± 4.5 Ma and a weighted mean age of 135.0 ± 1.2 Ma. The molybdenites have δ³⁴S values of 3.6‰–6.6‰ and their Re contents ranging from 7.23 ppm to 15.23 ppm. A second group of two molybdenite samples yield ages of 143.8 ± 2.1 and 146.3 ± 2.0 Ma, containing Re concentrations of 50.5–50.9 ppm, and with δ³⁴S values of 1.6‰–4.8‰. The molybdenites from these two distinct groups of samples contain moderate concentrations of Re (7.23–50.48 ppm), suggesting that metals within the deposit have a mixed crust–mantle provenance. Field observation and new age and isotope data obtained in this study indicate that the first diorite dyke‐related skarn W–Au mineralization took place in the Early Cretaceous peaking at 143.0–146.3 Ma, and was associated with a mixed crust–mantle system. The second fine‐grained granite‐related skarn W–Mo mineralization took place a little later at 135.0–136.9 Ma, and was crust‐dominated. The fine‐grained granite was not formed by fractionation of the Qingyang monzonitic granite. This finding suggests that the first period of skarn W–Au mineralization in the Baizhangyan deposit resulted from interaction between basaltic magmas derived from the upper lithospheric mantle and crustal material at 143.0–146.3 and the subsequent period of W–Mo mineralization derived from the crust at 135.0–136.9 Ma.     

河北省白洋淀洼地环境地球化学物源判断

河北省白洋淀洼地是一个大型天然平原洼地,在洼地的深、浅层土壤中均发现了以Cu、Pb、Zn、Cd为主的多变量地球化学异常。运用地球化学特征法、参考元素法及多元统计法,对深、浅层土壤Cu、Pb、Zn、Cd异常的性质和成因进行了判别。结果表明,深层土壤异常与特定的地球化学沉积环境有关,以自然地质作用成因为主,而浅层土壤异常具有典型的二元叠加特征,以人为源的输入为主。     

核爆炸与地震识别研究进展

综述了近年来核爆炸与天然地震识别研究的进展, 揭示了从频谱比、震级比到综合因素的概率方法的发展过程, 特别指出小当量核爆炸识别的重要性. 文章借助量子场论和相变理论分析讨论了地震波波长与动量的关系. 同时, 根据地壳介质的复杂性, 指出地震波传播过程中由于介质的非线性与弥散的联合作用, 导致产生孤波的可能性.     

大城市近郊农地流转的时空特征及影响因素

以武汉市蔡甸区为例,结合多源、多时段的村级农地流转数据,采用探索性空间分析和多元线性回归分析方法,揭示大城市近郊农地流转的时空特征及影响因素。研究发现：① 流转规模呈跨越式增长,经历快速增长和短期减速增长两个阶段,流转速度受土地政策影响较大;农地流转的空间分布由随机转向集聚,高高集聚区由主干道沿线转移至以农业为主的平原街镇,低低集聚区由不显著到集中于城镇化水平较高的街镇;② 控制自然、区位、社会经济等因素后,发现流转主体、流转用途对农地流转具有显著影响。建议清楚把握农地流转时空演化特征,合理选择流转主体和流转用途,以优化大城市近郊的人地关系,促进城乡统筹和乡村振兴。     

社会经济系统水循环研究进展

水循环包括自然水循环和社会经济水循环两个方面。社会经济系统水循环指社会经济系统对水资源的开发利用及各种人类活动对水循环的影响。对目前国际国内关于社会经济水循环关注的主要问题 (水资源安全、水资源社会经济研究、人类活动对水循环的影响、水环境、水资源可持续管理和综合管理) 及其进展进行了评述。水资源安全的主要对策已由增加供给转变为水资源需求管理。增加社会参与和明晰水权是水资源管理体制改革的方向。水价在水资源管理中的重要作用得到越来越多的重视。水资源可持续管理和综合管理正逐步落实。水资源需求管理机制、水权水价等水资源管理制度设计、作为可持续水资源管理基础的生态需水问题和环境变化对水资源的影响,将是未来社会经济系统水循环研究的焦点。     

Effects of N:P ratio of Artemisia ordosica on growth influenced by soil calcium carbonate

Soil calcium carbonate(CaCO_3) has a strong solid phosphorus effect, and high content of CaCO_3 can significantly reduce the effectiveness of soil phosphorus. To reveal the limiting effect of soil CaCO_3 on the growth of plants on sand land and its mechanism of plant physiology, we performed pot experiments with a two-factor randomized block design and a three-factor orthogonal design for different soil CaCO_3 content treatments using Artemisia ordosica seedlings. In the experiments, we surveyed plant height, aboveground biomass, root length and root weight and analyzed N, P concentrations and RNA content of the seedlings, and discussed the relationships between relative growth rate(RGR) of the seedlings and N:P ratio as well as RNA. Results show that, the RGRs of plant height and above-ground biomass of the seedlings decreased significantly with the increase of soil CaCO_3 content, and those for root length and root weight decreased. The RGRs of plant height and above-ground biomass of the seedlings were significantly negatively correlated with leaf N:P ratios, but significantly positively correlated with leaf RNA content and leaf P concentrations. It can be seen that soil CaCO_3 is a stress factor for the growth of A. ordosica seedlings, and the growth response of the seedlings under the influence of soil CaCO_3 is in line with the Growth Rate Hypothesis.     

中国锰矿物研究

我们自1970年起,先后对广西、广东、湖南、江西、福建、贵州、四川、云南、辽宁、陕西、甘肃等锰矿床进行了考察和标本采集。在大量光薄片鉴定、化学分析及电子探针分析、X射线粉晶分析的基础上,基本上查明了我国各类锰矿床中主要锰矿物的种属和名称。其中较有工业意义的达二十余种。这些锰矿物大多是我国未曾发现或未报道过的。     

库车坳陷东部山前带古近系不同体系域内扇三角洲沉积砂体的对比研究

通过对塔里木盆地库车坳陷南天山山前带克孜勒努尔沟与依奇克里克野外露头沉积相的精细研究,结合山前带大量地震剖面分析与迪那201井、东秋5井等多口钻井测井相和岩心精细描述,将古近系库姆格列木群划分为2个层序。层序2低位域以冲积扇沉积为主,自湖侵体系域始,研究区广泛发育退积与进积型扇三角洲沉积。库姆格列木群层序2湖侵体系域内扇三角洲平原砂体以正韵律沉积为主,砂砾岩占地层厚度的(68.4～87)%;扇三角洲前缘砂体正、反韵律均有分布,砂砾岩占地层的百分比有所降低,为(55.2～77)%。高位体系域内主要发育以反韵律砂体为主的扇三角洲前缘沉积。古近系苏维依组只发育一个层序,其低位体系域的砂体为扇三角洲平原与前缘的分流河道砂体,湖侵体系域内扇三角洲前缘砂体正、反韵律均发育,高位体系域内主要发育扇三角洲前缘沉积,以反韵律砂体为主,正韵律砂体相对较少。对比苏维依组不同体系域内砂体储集性,湖侵域内砂体优于高位域内砂体。扇三角洲沉积体中有利储集砂体首选为湖侵体系域内的扇三角洲前缘水下分流河道和河口坝砂体,次之为低位域扇三角洲前缘(平原)分流河道砂体,最后是高位域内的河口坝及席状砂沉积砂体。特别要指出:低位体系域或者湖侵体系域底部发育的扇三角洲前缘(平原)分流河道砂体(底砂砾岩)被快速湖侵的较厚的暗色泥岩所覆盖,可形成较好储集场所。     

中国北方6种新的砂岩型铀矿对铀资源潜力的提示

经过近10多年的努力,在中国北方中新生代沉积盆地发现和探明了6种新的大型、特大型砂岩型铀矿,暂时定名为伊犁式、吐哈式、东胜式、乌兰察布式、马尼特式、通辽式砂岩型铀矿。各种式样的铀矿产于不同构造背景的沉积盆地,矿床地质、矿体地质和控矿因素也有明显的差异性特征。成矿演化基本特点是:伊犁式、吐哈式都是典型的层间氧化-还原作用成矿,但前者在单斜整体抬升和差异升降构造活动背景下的不断叠加富集为重要特征,后者则在斜坡带隆升加断层及小型背斜构造活动的背景下在断裂南北两侧分带成矿;东胜式主要受古层间氧化带控制并接受后期还原改造再富集;乌兰察布式最新研究认为是重要的沉积成岩型铀矿,与湖泛事件演变密切相关;马尼特式是潜水氧化-还原作用与层间氧化-还原作用交替转化形成的古河谷型铀矿床;通辽式是"构造剥蚀天窗+断裂活动+深部还原物质"控矿,也可能还与基性岩脉(热源)有关。上述6种式样铀矿的另一规律是从西部向东部,西部(前三种)均产于中下侏罗统含煤碎屑岩系,东部(后三种)均产于上白垩统泥质砂岩和细砂岩。笔者指出,6种新的砂岩型铀矿的意义不仅仅在于发现和探明的本身增强了中国铀资源保障能力,更重要的意义还在于对中国铀资源潜力及今后找矿方针、勘查部署等多方面的重要提示。     

海南夏季雷暴时空分布特征及成因

利用海南18个市县雷暴资料、海南地形高度资料、海南日最高气温资料、海口和三亚2个测站日辐射观测资料和海南中尺度乡镇自动站逐时风资料等,研究海南夏季雷暴时空分布特征及可能原因.结果表明:海南大部分地区夏季雷暴主要发生在白天,集中发生在午后,只有以三亚为代表的南部地区表现出雷暴主要发生在夜间,与其余地区相反.研究认为这种差...