The Chandrayaan-1 X-ray Spectrometer: First results

We present X-ray fluorescence observations of the lunar surface, made by the Chandrayaan-1 X-ray Spectrometer during two solar flare events early in the mission (12th December 2008 and 10th January 2009). Modelling of the X-ray spectra with an abundance algorithm allows quantitative estimates of the MgO/SiO₂ and Al₂O₃/SiO₂ ratios to be made for the two regions, which are in mainly basaltic areas of the lunar nearside. One of these ground tracks includes the Apollo 14 landing site on the Fra Mauro Formation. Within the 1σ errors provided, the results are inside the range of basaltic samples from the Apollo and Luna collections. The Apollo 14 soil composition is in agreement with the results from the January flare at the 1σ uncertainty level. Discrepancies are observed between our results and compositions derived for the same areas by the Lunar Prospector gamma-ray spectrometer; some possible reasons for this are discussed.     

Use of Remotely-Derived Bathymetry for Modelling Biomass in Marine Environments

The paper presents results on the influence of geometric attributes of satellite-derived raster bathymetric data, namely the General Bathymetric Charts of the Oceans, on spatial statistical modelling of marine biomass. In the initial experiment, both the resolution and projection of the raster dataset are taken into account. It was found that, independently of the equal-area projection chosen for the analysis, the calculated areas are very similar, and the differences between them are insignificant. Likewise, any variation in the raster resolution did not change the computed area. Although the differences were shown to be insignificant, for the subsequent analysis we selected the cylindrical equal area projection, as it implies rectangular spatial extent, along with the automatically derived resolution. Then, in the second experiment, we focused on demersal fish biomass data acquired from trawl samples taken from the western parts of ICES Sub-area VII, near the sea floor. The aforementioned investigation into processing bathymetric data allowed us to build various statistical models that account for a relationship between biomass, sea floor topography and geographic location. We fitted a set of generalised additive models and generalised additive mixed models to combinations of trawl data of the roundnose grenadier (Coryphaenoides rupestris) and bathymetry. Using standard statistical techniques—such as analysis of variance, Akaike information criterion, root mean squared error, mean absolute error and cross-validation—we compared the performance of the models and found that depth and latitude may serve as statistically significant explanatory variables for biomass of roundnose grenadier in the study area. However, the results should be interpreted with caution as sampling locations may have an impact on the biomass–depth relationship.     

Nonuniform cratering of the terrestrial planets

We estimate the impact flux and cratering rate as a function of latitude on the terrestrial planets using a model distribution of planet crossing asteroids and comets [Bottke, W.F., Morbidelli, A., Jedicke, R., Petit, J.-M., Levison, H.F., Michel, P., Metcalfe, T.S., 2002. Icarus 156, 399-433]. After determining the planetary impact probabilities as a function of the relative encounter velocity and encounter inclination, the impact positions are calculated analytically, assuming the projectiles follow hyperbolic paths during the encounter phase. As the source of projectiles is not isotropic, latitudinal variations of the impact flux are predicted: the calculated ratio between the pole and equator is 1.05 for Mercury, 1.00 for Venus, 0.96 for the Earth, 0.90 for the Moon, and 1.14 for Mars over its long-term obliquity variation history. By taking into account the latitudinal dependence of the impact velocity and impact angle, and by using a crater scaling law that depends on the vertical component of the impact velocity, the latitudinal variations of the cratering rate (the number of craters with a given size formed per unit time and unit area) is in general enhanced. With respect to the equator, the polar cratering rate is about 30% larger on Mars and 10% on Mercury, whereas it is 10% less on the Earth and 20% less on the Moon. The cratering rate is found to be uniform on Venus. The relative global impact fluxes on Mercury, Venus, the Earth and Mars are calculated with respect to the Moon, and we find values of 1.9, 1.8, 1.6, and 2.8, respectively. Our results show that the relative shape of the crater size-frequency distribution does not noticeably depend upon latitude for any of the terrestrial bodies in this study. Nevertheless, by neglecting the expected latitudinal variations of the cratering rate, systematic errors of 20-30% in the age of planetary surfaces could exist between equatorial and polar regions when using the crater chronology method.     

Crustal thickness of the Moon: New constraints from gravity inversions using polyhedral shape models

A new method is presented for estimating crustal thickness from gravity and topography data on the Moon. By calculating analytically the exterior gravitational field for a set of arbitrarily shaped polyhedra, relief along the crust-mantle interface can be inverted for that satisfies the observational constraints. As this method does not rely upon filtering the Bouguer anomaly, which was required with previous inversions performed in the spherical-harmonic domain, and as the dramatic variations in spatial quality of the lunar gravity field are taken into account, our crustal thickness model more faithfully represents the available data. Using our model results, we investigate various aspects of the prominent nearside impact basins. The crustal thickness in the central portion of the Orientale and Crisium basins is found to be close to zero, suggesting that these basins could have conceivably excavated into the lunar mantle. Furthermore, given our uncertain knowledge of the density of the crust and mantle, it is possible that the Humorum, Humboldtianum, Nectaris, and Smythii basins could have excavated all the way through the crust as well. The crustal structure for most of the young impact basins implies a depth/diameter ratio of about 0.08 for their excavation cavities. As noted in previous studies, however, the crustal structure of Imbrium and Serenitatis is anomalous, which is conceivably a result of enhanced rates of post-impact viscous relaxation caused by the proximity of these basins to the Procellarum KREEP Terrane. Impact basins older than Smythii show little or no evidence for crustal thinning, suggesting that these ancient basins were also affected by high rates of viscous relaxation resulting from higher crustal temperatures early in the Moon's evolution. The lithosphere beneath many young basins is found to be supporting a downward directed force, even after the load associated with the mare basalts is removed, and this is plausibly attributed to superisostatic uplift of the crust-mantle interface. Those basins that are close to achieving a pre-mare isostatic state are generally found to reside within, or close to, the Procellarum KREEP Terrane.     

LunarEX—a proposal to cosmic vision

While the surface missions to the Moon of the 1970s achieved a great deal, scientifically much was also left unresolved. The recent plethora of lunar missions (flown or proposed) reflects a resurgence in interest in the Moon, not only in its own right, but also as a record of the early solar system including the formation of the Earth. Results from recent orbiter missions have shown evidence of ice or at least hydrogen within shadowed craters at the lunar poles.     

Evidence for superstructuring in ankerite

Summary Ankerite from the Radmer-Buchegg and Erzberg mines, Austria, were studied by high resolution electron microscope imaging and selected area diffraction. Electron diffraction data suggest the presence of a periodic antiphase structure. The unit cell of the periodic antiphase structure of ankerite consists probably of three units: CaMg(CO₃)₂ as a basal unit, CaFe(CO₃)₂ and CaCO₃. The last CaCO₃ unit is connected with excess of Ca in ankerite. The upper size limit of CaFe(CO₃)₂ domains is 20–40 nm according to dark-field image study.Other rhombohedral dicarbonates (Zn-dolomites, Fe-poor ankerites) have probably also domain structure. The size of domains seems to be controlled by the value of misfit of domain lattice to the host lattice and by the value of octahedral distortion of units of the periodic antiphase structure.

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Überstrukturen in Ankerit

Zusammenfassung Ankerite der Lagerstätten Radmer-Buchegg und Erzberg, Österreich wurden mittels hochauflösender Elektronenmikroskopie und Elektronenbeugung untersucht. Die Beugungsbilder lassen auf eine periodische Antiphasen-Struktur schließen, die sich aus drei Einheiten aufbaut: CaMg(CO₃)₂ als Basiseinheit, CaFe(CO₃)₂ und CaCO₃. CaCO₃ ist an einen Ca-Überschuß in Ankeriten gebunden. Dunkelfeldaufnahmen entsprechend beträgt die Obergrenze der CaFe(CO₃)₂ Domänengröße 20–40 nm.Andere rhomboedrische Doppelkarbonate (Zn-Dolomite, Fe-arme Ankerite) haben wahrscheinlich ebenfalls Domänenstruktur. Die Größe der Domänen scheint durch das Zusammenpassen des Domänengitters mit dem Gitter des Wirtskristalls sowie durch den Grad der oktaedrischen Verzerrung von Baueinheiten der Antiphasen-Struktur bestimmt zu werden.

     

Sulfide — carbonate relationships in the Navan (Tara) Zn-Pb deposit,Ireland

Samples from the mineralized micrite, the bottom part of the 1–5 lens were investigated. They contain Zn and Fe bearing low Mg-calcite, dolomite, Fedolomite, minrecordite-CaZn (CO₃)₂, sphalerite, pyrite, melnikovite and overgrown quartz. — Zn-dolomite consists probably of CaMg (CO₃)₂ and CaZn (CO₃)₂ domains about 10×35 nm in size. Zn-dolomite is sulfidized (replaced by ZnS) which is demonstrated by both reflected light and electron microscope methods. — CaZn (CO₃)₂ from the Navan ore has cell parameters: a₀=0.484±0.004 and c₀=1.608±0.012 nm and is rhombohedral. It forms close, tiny intergrowths with calcite. — Base metals at Navan were exhaled to form at least partly carbonate minerals which subsequently reverted to sulfides in the diagenetic environment. The reversion of base metals carbonates to sulfides is connected with reduction in volume. The reduction in volume allowed the ore zone to retain its permeability after lithification of the host rock. It allowed lateral flow of hydrothermal solutions, which deposited further generations of sulfides and increased the base metal content producing a high grade ore.     

Did a large impact reorient the Moon?

The Moon is currently locked in a spin–orbit resonance of synchronous rotation, of which one consequence is that more impacts should occur near the Moon's apex of motion (0° N, 90° W) than near its antapex of motion (0° N, 90° E). Several of the largest lunar impact basins could have temporarily unlocked the Moon from synchronous rotation, and after the re-establishment of this state the Moon would have been left in either its initial orientation, or one that was rotated 180° about its spin axis. We show that there is less than a 2% probability that the oldest lunar impact basins are randomly distributed across the lunar surface. Furthermore, these basins are preferentially located near the Moon's antapex of motion, and this configuration has less than a 0.3% probability of occurring by chance. We postulate that the current “near side” of the Moon was in fact its “far side” when the oldest basins formed. One basin with the required size and temporal characteristics to account for a 180° reorientation is the Smythii basin.     

Constraints on the composition of the martian south polar cap from gravity and topography

The polar caps of Mars have long been acknowledged to be composed of unknown proportions of water ice, solid CO₂ (dry ice), and dust. Gravity and topography data are here analyzed over the southern cap to place constraints on its density, and hence composition. Using a localized spectral analysis combined with a lithospheric flexure model of ice cap loading, the best fit density of the volatile-rich south polar layered deposits is found to be 1271 kg m⁻³ with 1-σ limits of 1166 and 1391 kg m⁻³. The best fit elastic thickness of this geologically young deposit is 140 km, though any value greater than 102 km can fit the observations. The best fit density implies that about 55% dry ice by volume could be sequestered in these deposits if they were completely dust free. Alternatively, if these deposits were completely free of solid CO₂, the dust content would be constrained to lie between about 14 and 28% by volume. The bulk thermal conductivity of the polar cap is not significantly affected by these maximum allowable concentrations of dust. However, even if a moderate quantity of solid CO₂ were present as horizontal layers, the bulk thermal conductivity of the polar cap would be significantly reduced. Reasonable estimates of the present day heat flow of Mars predict that dry ice beneath the thicker portions of the south polar cap would have melted. Depending on the quantity of solid CO₂ in these deposits today, it is even possible that water ice could melt where the cap is thickest. If independent estimates for either the dust or CO₂ content of the south polar cap could be obtained, and if radar sounding data could determine whether this polar cap is presently experiencing basal melting or not, it would be possible to use these observations to place tight constraints on the present day heat flow of Mars.