Geological interpretation of combined SEABEAM,GLORIA and seismic data from Porto and Vigo Seamounts,Iberian continental margin

Long-range sidescan sonar (GLORIA) data over Porto and Vigo Seamounts collected in 1978 has been re-interpreted in the light of SEABEAM bathymetric surveys conducted in 1982. The application of quantitative bathymetric information enables the interpreter to allow for artefacts inherent in the GLORIA data and to separate topography-related primary backscattering variations on the sonographs from more subtle changes that result from textural, slope and outcrop effects. The distinctions are made easier when slant-range corrected GLORIA data are available.Use of the combined survey data to precisely locate seismic profiling tracks and to identify likely areas of outcrop has allowed refined geological maps of the seamounts to be drawn and regional fault trends detected. The overall outline of the seamounts appears strongly fault-controlled.Porto and Vigo Seamounts are made up of the same geological formations and have had a similar structural history since their uplift as continental fault blocks in the Late Cretaceous to Middle Eocene period. Ravines that dissect the presumably lithified scarps bounding the seamounts may be relict features but still appear to control sediment input to gulley and channel systems in the surrounding topography. Sedimentary ridges associated with the seamounts represent anomalously thick sequences of post-Eocene material and probably result from interaction of downslope sedimentary processes and contour-following boundary currents.Contribution No. 274 from the Groupe d'Etude de la Marge Continentale (ERA 605).     

Seasonal variations in dimethylsulfoniopropionate and dimethylsulfide concentrations in relation to the plankton community in the St. Lawrence Estuary

Weekly variations in total dimethylsulfoniopropionate (DMSPt) and dimethylsulfide (DMS) were investigated in relation to the phytoplankton assemblage from spring to fall 1994 at a coastal fixed station in the St. Lawrence Estuary. DMSPt and DMS concentrations showed a strong seasonality and were tightly coupled in time. Maximum concentrations of DMSPt and DMS were observed in July and August, during a period of warm water and low nutrient concentrations. Seasonal maxima of 365.4 nmol l⁻¹ for DMSPt and 14.2 nmol l⁻¹ for DMS in early August coincided with the presence of many phytoplankton species, such as Alexandrium tamarense, Dinophysis acuminata, Gymnodinium sp., Heterocapsa rotundata, Protoperidinium ovatum, Scrippsiella trochoidea, Chrysochromulina sp. (6 μm), Cryptomonas sp. (6 μm), a group of microflagellates smaller than 5 μm (mf < 5), many tintinnids, and Mesodinium rubrum. The abundance of mf < 5 followed the general trend of DMS concentrations. The temporal occurrence of high P. ovatum abundance and DMSPt concentrations suggests that this heterotrophic dinoflagellate can either synthesize DMSP or acquire it from DMSP-rich prey. The calculated sea-to-air DMS flux reached a maximum of 8.36 μmol ⁻² d⁻¹ on August 1. The estimated annual emission from the St. Lawrence Estuary is 77.2 tons of biogenic sulfur to the atmosphere.     

Continental Lithospheric Contribution to Alkaline Magmatism: Isotopic (Nd, Sr, Pb) and Geochemical (REE) Evidence from Serra de Monchique and Mount Ormonde Complexes

Isotopic results (Sr, Nd, Pb), as well as concentrations ofmajor and trace elements (REE) are reported for whole-rock samplesand mineral separates from the onland alkaline complex of Serrade Monchique (South Portugal) and the offshore alkali basaltvolcanic suite of Mount Ormonde (Gorringe Bank). These two geneticallyrelated alkaline complexes were emplaced at the east Atlanticcontinent–ocean boundary during the Upper Cretaceous,i.e. 66–72 m.y. ago. Taken together, Serra de Monchiqueand Mount Ormonde may be seen as one of the few examples ofwithin-plate magmatism that straddles the continent–oceanboundary. Major and trace element compositions fail to revealany significant differences between onland and offshore complexes.This is particularly true regarding less differentiated samples(mg-number 0.40) which show the same progressive and continuousenrichment of their trace element patterns, with no specificanomaly (e.g. negative Nb anomaly) being present in samplesfrom the onland complex. Initial Pb and Sr isotopic compositionsalso do not allow any distinction to be made between Serra deMonchique and Mount Ormonde samples. Initial Pb isotope ratiosare moderately high (19.1 < ²⁰⁶Pb/²⁰⁴Pb < 19.8; ²⁰⁷Pb/²⁰⁴Pb= 15.6) in both cases. Moreover, once the effects of Sr contaminationby seawater are taken into account and the most contaminatedsamples discarded using data from fresh clinopyroxene separatesand results of leaching experiments, the initial Sr isotopiccompositions of Mount Ormonde samples are found to be unradiogenic(⁸⁷Sr/⁸⁶Sr = 0.7031±1) and identical to those obtainedat Serra de Monchique (⁸⁷Sr/⁸⁶Sr = 0.7032±1). In contrast,a systematic mean difference of 2 _Nd units is observed betweenSerra de Monchique [_Nd(T) = +4.8] and Mount Ormonde [_Nd(T) =+6.6] whole-rock samples. Surprisingly, a variation is alsoobserved at Mount Ormonde between the whole-rock samples andone of the two analysed clinopyroxene separates. Whereas MountOrmonde whole-rock samples invariably yielded _Nd(T) = +6.6 (meanvalue), a value of +0.5 is obtained for one clinopyroxene separate,whereas another gives +6.0. The above geochemical and isotopicresults make it possible to assign respective roles to the asthenosphere,lithosphere and crust in the petrogenesis of Serra de Monchiqueand Mount Ormonde complexes. We propose that both complexesshare a common mantle source whose isotopic characteristicsare very similar to the source of oceanic island basalts. Continentalmantle lithosphere, already characterized isotopically by studiesof peridotite massifs within the Iberian peninsula, acts asa contaminant which is evident onland on the whole-rock scale,and also present offshore as discrete clinopyroxene xenocrysts.The continental crust appears to play no role in the petrogenesisof the Serra de Monchique alkaline rocks. KEY WORDS: alkaline complexes; continental lithosphere; isotope geochemistry; passive continental margin; within-plate volcanics     

Oxygen isotopic constraints on the origin of magnesian chondrules and on the gaseous reservoirs in the early Solar System

We report in situ ion microprobe analyses of the oxygen isotopic composition of the major silicate phases (olivine, low-Ca pyroxene, silica, and mesostasis) of 37 magnesian porphyritic (type I) chondrules from CV (Vigarano USNM 477-2, Vigarano UH5, Mokoia, and Efremovka) and CR (EET 92042, EET 92147, EET 87770, El Djouf 001, MAC 87320, and GRA 95229) carbonaceous chondrites. In spite of significant variations of the modal proportions of major mineral phases in CR and CV chondrules, the same isotopic characteristics are observed: (i) olivines are isotopically homogeneous at the ‰ level within a chondrule although they may vary significantly from one chondrule to another, (ii) low-Ca pyroxenes are also isotopically homogeneous but systematically ¹⁶O-depleted relative to olivines of the same chondrule, and (iii) all chondrule minerals analyzed show ¹⁶O-enrichments relative to the terrestrial mass fractionation line, enrichments that decrease from olivine (±spinel) to low-Ca pyroxene and to silica and mesostasis. The observation that, in most of the type I chondrules studied, the coexisting olivine and pyroxene crystals and glassy mesostasis have different oxygen isotopic compositions implies that the olivine and pyroxene grains are not co-magmatic and that the glassy mesostasis is not the parent liquid of the olivine. The δ¹⁸O and δ¹⁷O values of pyroxene and olivine appear to be strongly correlated for all the studied CR and CV chondrules according to:

     

Competition in a Precambrian world: palaeoecology of Ediacaran fronds

Leaf‐shaped Ediacaran fronds are among the most widespread and readily recognized members of the terminal Neoproterozoic Ediacara Biota. Ediacaran fronds gathered nutrients from the water column through filter feeding or direct nutrient absorption, resulting in the onset of modern‐style ecological competition complete with denizens occupying distinct tiers in the water column. It is believed that the frond shape most likely represents a common need to elevate a feeding apparatus higher in the water‐column to feed from the upper (> 20 cm) tiers. Therefore, the frond shape represents a shared ecology, not ancestry.     

The migration of plate boundaries in SE Sicily: Influence on the large-scale kinematic model of the African promontory in southern Italy

A detailed field mapping, coupled with structural analyses and morphological investigation, has been carried out along the northern and western borders of the Hyblean Plateau (SE Sicily), in order to define the nature and the kinematics of a major Quaternary fault belt. This, here designed as the Scicli Line Fault Belt, is composed of two N50 oriented extensional basins that, linked by a regional N10 trending transfer zone, originated during the Early Pleistocene and experienced, since the Late Quaternary, a positive tectonic inversion. In both the two stages of deformation, the Scicli Line Fault Belt has been characterised by displacement-rate comparable with the relative velocities measured between the distinct plates composing the central Mediterranean region. In the period going from 1.5–1.2 to 0.85 Ma, the fault belt accommodated the entire divergence between Adria and Nubia. At present, the Scicli Line Fault Belt absorbs most of the Nubia–Eurasia convergence, while the western divergent margin of the Adria microplate has jumped to the eastern and the southern margins of the Hyblean Plateau, along the Late Quaternary Siculo–Calabrian Rift Zone. The off-shore prolongation of the two tectonic boundaries of the Hyblean Plateau has been recognised in the Sicily Channel, where they are both interrupted by a WNW-ESE oriented dextral fault. According to our reconstruction, the Hyblean Plateau represents an isolated lithospheric block, whose evolution can be related to the propagation of the western divergent margin of the Adria microplate, accompanied with the southward migration of the triple junction between Eurasia, Nubia and Adria. In this new large-scale kinematic picture, the GPS velocity measured in the Hyblean region, at the permanent site of NOTO, is actually representative of the local kinematics, rather than of the entire African promontory of southern Italy. This implies a correction of previous regional kinematic models based on combination of GPS vectors. In particular, our data constrain a new interpretation both for the kinematics along the E–W oriented Nubia–Eurasia margin, dominated by prevalent dextral deformation rather than reverse motions, and for the intraplate deformation in the Sicily Channel, within the Africa promontory, which would be dominated by a roughly N110° oriented extension. This conclusion has implication also on the mechanism and the origin of the Pantelleria–Linosa–Malta Rift that is here interpreted as a transtensive feature developed along a major transform fault, rather than the result of passive rifting induced by the Nubia–Eurasia collision, as it is currently interpreted.     

Coincidence or not? Interconnected gas/fluid migration and ocean–atmosphere oscillations in the Levant Basin

A growing number of studies on shallow marine gas/fluid systems from across the globe indicate their abundance throughout geological epochs. However, these episodic events have not been fully integrated into the fundamental concepts of continental margin development, which are thought to be dictated by three elements: tectonics, sedimentation and eustasy. The current study focuses on the passive sector of the Levant Basin on the eastern Mediterranean continental margin where these elements are well constrained, in order to isolate the contribution of gas/fluid systems. Single-channel, multichannel and 3D seismic reflection data are interpreted in terms of variance, chaos, envelope and sweetness attributes. Correlation with the Romi-1 borehole and sequence boundaries constrains interpretation of seismic stratigraphy. Results show a variety of fluid- or gas-related features such as seafloor and subsurface pockmarks, volumes of acoustic blanking, bright spots, conic pinnacle mounds, gas chimneys and high sweetness zones that represent possible secondary reservoirs. It is suggested that gas/fluid migrate upwards along lithological conduits such as falling-stage systems tracts and sequence boundaries during both highstands and lowstands. In all, 13 mid-late Pleistocene sequence boundaries are accompanied by independent evidence of 13 eustatic sea-level drops. Whether this connection is coincidental or not requires further research. These findings fill gaps between previously reported sporadic appearances throughout the Levant Basin and margin and throughout geological time from the Messinian until the present day, and create a unified framework for understanding the system as a whole. Repetitive appearance of these features suggests that their role in the morphodynamics of continental margins is more important than previously thought and thus may constitute one of the key elements of continental margin development.     

A method to map riparian exotic vegetation (Salix spp.) area to inform water resource management

Hydrological processes within riparian environments worldwide are impacted when introduced species invade. Monitoring and management at substantial expense, are subsequently required to combat deleterious effects on the environment and stream hydrology. Willow species (Salicaceae: Salix spp.) introduced into Australia have spread throughout many riparian systems causing adverse environmental impacts, with high rates of water extraction when located within stream beds (in‐stream willows) thus altering hydrology. Strategies exist to manage willows; however, simpler, more cost‐effective methods are required to map and monitor spatial and temporal distributions. A method is presented to discriminate willow stands from surrounding native riparian vegetation using a single, very high 2 m resolution multispectral WorldView‐2 satellite image. A combination of spectral bands ‘coastal blue’ (400–450 nm), ‘red’ (630–690 nm), ‘red edge’ (705–745 nm) and ‘near infrared2’ (860–1040 nm), minimum noise fraction transformation, median filtering and maximum likelihood supervised classification provided the highest discriminatory power within a 25 km² study area. Of the spectral bands, coastal blue, red edge and near infrared2 are new bands that are not available in other multispectral sensors. These bands proved critical to the success of discriminating willows from other land cover categories (overall accuracy of 97%). Stream channels were defined by incorporating a LiDAR‐derived digital elevation model to discriminate between willows on stream banks and within stream beds. Canopy area estimates of in‐stream willows, coupled with water savings estimates from willow removal, suggest removal of 10.4 ha of Salix fragilis canopy from within river channels in the study area will potentially return 41 ML year^?1 to the environment. The method presented improves our understanding of willow impacts on hydrology and aids decisions regarding willow removal for water resource management. Copyright © 2013 John Wiley & Sons, Ltd.     

Nitrile gas chemistry in Titan’s atmosphere

This work presents the first study of the gaseous products resulting from the partial dissociation of methane and nitrogen in the PAMPRE experimental setup simulating Titan’s atmospheric chemistry.Using cryogenic trapping, the gaseous products generated from the chemical reactions occurring in the reactor have been trapped. Analyses of these products by gas chromatography coupled to mass spectrometry have allowed the detection and identification of more than 30 reaction products. Most of them are identified as nitrile species, accompanied by aliphatic hydrocarbons and a few aromatics compounds. The observed species are in agreement with the data from the recent Cassini-Huygens mission as well as from other laboratory setups capable of dissociating nitrogen and methane. This work emphasizes the probable importance of nitrogen-bearing compounds in the chemistry taking place in Titan’s atmosphere.Furthermore, a quantification of mono-nitriles with saturated alkyl chains has been performed relatively to hydrogen cyanide and shows a power law dependence in their concentration. This dependence is consistent with the Cassini-INMS data and Titan’s photochemical models.An empirical relationship has been extracted from our experimental data: [C_xH_2x−1N] = 100x⁻⁵, where x is the number of carbon atoms in the nitrile molecule. This relationship can be directly used in order to foretell the concentration of heavier nitriles induced by chemistry in Titan’s atmosphere.