Mantle Sources and the Highly Variable Role of Continental Lithosphere in Basalt Petrogenesis of the Kerguelen Plateau and Broken Ridge LIP: Results from ODP Leg 183

Ocean Drilling Program (ODP) Leg 183 was designed to investigatethe origin and evolution of the large igneous province composedof the Kerguelen Plateau and Broken Ridge. Of the eight sitesdrilled, basalt was recovered from seven, five on the plateauand two on Broken Ridge. We present results from four of thesesites, 1136, 1138, 1141 and 1142. Although this large igneousprovince is interpreted as being derived from the Kerguelenmantle plume, the geochemical characteristics of basalt fromsome parts of the province indicate a role for continental lithosphere.The 118–119 Ma basalt flows recovered in the SouthernKerguelen Plateau (Site 1136) have a more subtle continentalsignature than shown by basalt at Leg 119 Site 738. A continentalsignature is absent in the 100–101 Ma tholeiitic basaltsat Site 1138 in the Central Kerguelen Plateau (CKP); their age-correctedNd–Sr–Pb isotopic values and incompatible elementratios are similar to those estimated for primitive mantle.These flows may represent a major mantle source in the Kerguelenstarting-plume head. The 20 basalt units identified are a productof magma chamber replenishment, fractional crystallization,and resorption of crystallizing phases. The topmost unit, Unit1, is a dacite that evolved from a basalt magma similar to thoserepresented by Units 3–22; unlike the basalts the dacitemagma was probably influenced by continental material. MiddleCretaceous (     

Topography as a major factor in the development of arcuate thrust belts: insights from sandbox experiments

We have used sandbox experiments to investigate and to illustrate the effects of topography upon the development of arcuate thrust belts. In experiments where a sand pack shortened and thickened in front of an advancing rectilinear piston, the geometry of the developing thrust wedge was highly sensitive to variations in surface topography. In the absence of erosion and sedimentation, the surface slope tended to become uniform, as predicted by the theory of critical taper. Under these conditions, the wedge propagated by sequential accretion of new thrust slices. In contrast, where erosion or sedimentation caused the topographic profile to become irregular, thrusts developed out of sequence. For example, erosion throughout a hinterland caused underlying thrusts to remain active and inhibited the development of new thrusts in the foreland. Where initial topography was irregular in plan view, accreting thrusts tended to be arcuate. They were convex towards the foreland, around an initially high area; concave towards the foreland, around an initially low area. Initial plateaux tended to behave rigidly, while arcuate thrust slices accreted to them. Thrust motions were radial with respect to each plateau. Within transfer zones to each side, fault blocks rotated about vertical axes and thrust motions were oblique-slip. At late stages of deformation, the surface slope of the thrust wedge tended towards a uniform value. Initial mountains of conical shape (representing volcanoes) also escaped deformation, except at depth, where they detached. Arcuate thrust slices accreted to front and back. Where a developing thrust wedge was subject to local incision, accreting thrust slices dipped towards surrounding areas of high topography, forming Vs across valleys.Arcuate structural patterns are to be found around the three highest plateaux on Earth (Tibet, Pamirs and Altiplano) and around the Tromen volcanic ridge in the Neuquén Basin of northern Patagonia. We infer that these areas behaved in quasi-rigid fashion, protected as they were by their high topography.     

A Cordilleran model for the evolution of Avalonia

Striking similarities between the late Mesoproterozoic–Early Paleozoic record of Avalonia and the Late Paleozoic–Cenozoic history of western North America suggest that the North American Cordillera provides a modern analogue for the evolution of Avalonia and other peri-Gondwanan terranes during the late Precambrian. Thus: (1) The evolution of primitive Avalonian arcs (proto-Avalonia) at 1.2–1.0 Ga coincides with the amalgamation of Rodinia, just as the evolution of primitive Cordilleran arcs in Panthalassa coincided with the Late Paleozoic amalgamation of Pangea. (2) The development of mature oceanic arcs at 750–650 Ma (early Avalonian magmatism), their accretion to Gondwana at ca. 650 Ma, and continental margin arc development at 635–570 Ma (main Avalonian magmatism) followed the breakup of Rodinia at ca. 755 Ma in the same way that the accretion of mature Cordilleran arcs to western North America and the development of the main phase of Cordilleran arc magmatism followed the Early Mesozoic breakup of Pangea. (3) In the absence of evidence for continental collision, the diachronous termination of subduction and its transition to an intracontinental wrench regime at 590–540 Ma is interpreted to record ridge–trench collision in the same way that North America's collision with the East Pacific Rise in the Oligocene led to the diachronous initiation of a transform margin. (4) The separation of Avalonia from Gondwana in the Early Ordovician resembles that brought about in Baja California by the Pliocene propagation of the East Pacific Rise into the continental margin. (5) The Late Ordovician–Early Silurian sinistral accretion of Avalonia to eastern Laurentia emulates the Cenozoic dispersal of Cordilleran terranes and may mimic the paths of future terranes transferred to the Pacific plate.This close similarity in tectonothermal histories suggests that a geodynamic coupling like that linking the evolution of the Cordillera with the assembly and breakup of Pangea, may have existed between Avalonia and the late Precambrian supercontinent Rodinia. Hence, the North American Cordillera is considered to provide an actualistic model for the evolution of Avalonia and other peri-Gondwanan terranes, the histories of which afford a proxy record of supercontinent assembly and breakup in the late Precambrian.     

Geochemistry and sequence stratigraphy of regional Upper Cretaceous limestone units, offshore eastern Canada

Hydrocarbons occur in two regional, Upper Cretaceous limestone units—the Turonian-Coniacian Petrel Member, and the Santonian-Maastrichtian Wyandot Formation. The units form important seismic markers beneath the Scotian Shelf and the Grand Banks of Eastern Canada. They mainly consist of bioturbated chalk and minor amounts of calcareous mudstone. A search for source rock using the Δ log R technique showed intervals with source potential, but testing of core and cuttings by Rock-Eval analysis showed no source potential. Three issues are the main cause for the inconsistency: (1) unconsolidated shales that likely included organic material were lost during sample washing; (2) severe contamination by mud additives; and (3) presence of gas. The organic matter found on the shelf has been strongly oxidised, but the distal facies of these limestone units and condensed shale units above and below may yet have potential to form source rock, beyond the studied areas.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Electrons in feldspar II: a consideration of the influence of conduction band-tail states on luminescence processes

 Most natural feldspars contain many charged impurities, and display a range of bond angles, distributed about the ideal. These effects can lead to complications in the structure of the conduction band, giving rise to a tail of energy states (below the high-mobility conduction band) through which electrons can travel, but with reduced mobility: transport through these states is expected to be thermally activated. The purpose of this article is twofold. Firstly, we consider what kind of lattice perturbations could give rise to both localized and extended conduction band-tail states. Secondly, we consider what influence the band tails have on the luminescence properties of feldspar, where electrons travel through the sample prior to recombination. The work highlights the dominant role that 0.04–0.05-eV phonons play in both the luminescence excitation and emission processes of these materials. It also has relevance in the dating of feldspar sediments at elevated temperatures. Received: 11 May 2001 / Accepted: 6 September 2001     

Intercomparison of IRS-P4-MSMR derived geophysical products with DMSP-SSM/I and TRMM-TMI finished products

In this paper, MSMR geophysical products like Integrated Water Vapour (IWV), Ocean Surface Wind Speed (OWS) and Cloud Liquid Water (CLW) in different grids of 50, 75 and 150 kms are compared with similar products available from other satellites like DMSP-SSM/I and TRMMTMI. MSMR derived IWV, OWS and CLW compare well with SSM/I and TMI finished products. Comparison of MSMR derived CLW with that derived from TMI and SSM/I is relatively in less agreement. This is possibly due to the use of 37 GHz in SSM/I and TMI that is highly sensitive to CLW, while 37 GHz channels are not available on MSMR. Monthly comparison of MSMR geophysical products with those from TMI is all carried out for climatological purpose. The monthly comparisons were much better compared to instantaneous comparisons. In this paper, details of the data analysis and comparison results are presented. The usefulness of the MSMR vis-à-vis other sensors is also discussed.