Fumarolic gases at Mombacho volcano (Nicaragua): presence of magmatic gas species and implications for volcanic surveillance

Mombacho is a deeply dissected volcano belonging to the Quaternary volcanic chain of Nicaragua. The southern, historic collapse crater (El Crater) currently hosts a fumarolic field with a maximum temperature of 121°C. Chemical and isotopic data from five gas-sampling field campaigns carried out in 2002, 2003 and 2005 highlight the presence of high-temperature gas components (e.g. SO₂, HCl and HF), which indicate a significant contribution of juvenile magmatic fluids to the hydrothermal system feeding the gas discharges. This is strongly supported by the mantle-derived helium and carbon isotopic signatures, although the latter is partly masked by either a sedimentary subduction-related or a shallow carbonate component. The observed chemical and isotopic composition of the Mombacho fluids seems to indicate that this volcanic system, although it has not experienced eruptive events during the last centuries, can be considered active and possibly dangerous, in agreement with the geophysical data recorded in the region. Systematic geochemical monitoring of the fumarolic gas discharges, coupled with a seismic and ground deformation network, is highly recommended in order to monitor a possible new eruptive phase.     

Role of TBO and ENSO scale ocean–atmosphere interaction in the Indo-Pacific region on Asian summer monsoon variability

Interannual variability of the Indian summer monsoon rainfall has two dominant periodicities, one on the quasi-biennial (2–3 year) time scale corresponding to tropospheric biennial oscillation (TBO) and the other on low frequency (3–7 year) corresponding to El Niño Southern Oscillation (ENSO). In the present study, the spatial and temporal patterns of various atmospheric and oceanic parameters associated with the Indian summer monsoon on the above two periodicities were investigated using NCEP/NCAR reanalysis data sets for the period 1950–2005. Influences of Indian and Pacific Ocean SSTs on the monsoon season rainfall are different for both of the time scales. Seasonal evolution and movement of SST and Walker circulation are also different. SST and velocity potential anomalies are southeast propagating on the TBO scale, while they are stationary on the ENSO scale. Latent heat flux and relative humidity anomalies over the Indian Ocean and local Hadley circulation between the Indian monsoon region and adjacent oceans have interannual variability only on the TBO time scale. Local processes over the Indian Ocean determine the Indian Ocean SST in biennial periodicity, while the effect of equatorial east Pacific SST is significant in the ENSO periodicity. TBO scale variability is dependent on the local factors of the Indian Ocean and the Indian summer monsoon, while the ENSO scale processes are remotely controlled by the Pacific Ocean.     

Analytical and experimental investigations on seismic performance of exterior beam–column subassemblages of existing RC‐framed building

Seismic performance of exterior beam–column subassemblages of reinforced concrete structure designed and detailed on the basis of the provisions of Eurocode and Indian Standards at different stages of their evolution is evaluated. Performance of the subassemblages designed and detailed according to the three different stages of codal evolution (gravity load design, ‘Nonductile’, and ‘Ductile’) is evaluated through analytical formulations and experimental investigations. In the ‘NonDuctile’ specimens, it has been observed that the shear distortion and degradation in stiffness and strength are significantly high. Performance of the ‘Ductile’ specimens based on Eurocode and Indian Standards is almost similar in terms of strength and stiffness degradation. Nevertheless, the specimen designed on the basis of Indian Standard shows higher energy dissipation at a given drift ratio. In the analytical study, shear and flexural failure of members of subassemblage and shear failure of the joint are considered as possible modes of failure of the beam–column subassemblage. For evaluating the shear strength of the joint region, a soften strut‐and‐tie model is used. Analytically obtained strengths based on the failure criteria of different components of the specimens have been first validated with experimental results and then used to determine the strength of the specimens. The investigation could indicate even the mode of failure at local level. It is utmost important to mention here that even the ductile specimens dissipate most of the energy through the development of damage in the joint region, which is neither desirable nor safe for the stability of whole structure. Copyright © 2013 John Wiley & Sons, Ltd.     

The importance of interactions for mass loss from satellite galaxies in cold dark matter haloes

We investigate the importance of interactions between dark matter substructures for the mass loss they suffer whilst orbiting within a sample of high-resolution galaxy cluster mass cold dark matter (CDM) haloes formed in cosmological N -body simulations. We have defined a quantitative measure that gauges the degree to which interactions are responsible for mass loss from substructures. This measure indicates that interactions are more prominent in younger systems when compared to older more relaxed systems. We show that this is due to the increased number of encounters a satellite experiences and a higher mass fraction in satellites. This is in spite of the uniformity in the distributions of relative distances and velocities of encounters between substructures within the different host systems in our sample.
Using a simple model to relate the net force felt by a single satellite to the mass loss it suffers, we show that interactions with other satellites account for ∼30 per cent of the total mass loss experienced over its lifetime. The relation between the age of the host and the importance of interactions increases the scatter about this mean value from ∼25 per cent for the oldest to ∼45 per cent for the youngest system we have studied. We conclude that satellite interactions play a vital role in the evolution of substructure in dark matter haloes and that a significant fraction of the tidally stripped material can be attributed to these interactions.     

Staurolite as an isotopic U–Pb geochronometer

A new approach is suggested for measuring the real U–Pb and Pb–Pb ages of rock-forming metamorphic staurolite. Previously, two approaches have been used for this purpose: (1) measurement of the lead isotopic compositions, uranium and lead contents in leach substance as a product of the step-leaching technique; age is calculated by plotting the Pb–Pb leaching isochron; and (2) lead and uranium isotopic compositions are measured in completely dissolved mineral material without leaching. In both cases, it is assumed a priori that inclusions, overgrowths, secondary phases, and the host mineral are cogenetic. This assumption may lead to errors in the measured age. The technique suggested in this paper uses various reagents (acids) to purify staurolite from the above-mentioned secondary phases while obtaining a staurolite “pure culture,” its subsequent disolution, introduction of the mixed spike, separation of lead and uranium compounds, and, finally, estimation of a real staurolite age using several samples to plot the monomineralic Pb–Pb isochron or by plotting measured Pb/U ratios in the diagram with concordia. The data can be used then to reconstruct the P–T–t evolution of metamorphism.     

Revised age of proximal deposits in the Zagros foreland basin and implications for Cenozoic evolution of the High Zagros

The regionally extensive, coarse-grained Bakhtiyari Formation represents the youngest synorogenic fill in the Zagros foreland basin of Iran. The Bakhtiyari is present throughout the Zagros fold-thrust belt and consists of conglomerate with subordinate sandstone and marl. The formation is up to 3000 m thick and was deposited in foredeep and wedge-top depocenters flanked by fold-thrust structures. Although the Bakhtiyari concordantly overlies Miocene deposits in foreland regions, an angular unconformity above tilted Paleozoic to Miocene rocks is expressed in the hinterland (High Zagros).

The Bakhtiyari Formation has been widely considered to be a regional sheet of Pliocene–Pleistocene conglomerate deposited during and after major late Miocene–Pliocene shortening. It is further believed that rapid fold growth and Bakhtiyari deposition commenced simultaneously across the fold-thrust belt, with limited migration from hinterland (NE) to foreland (SW). Thus, the Bakhtiyari is generally interpreted as an unmistakable time indicator for shortening and surface uplift across the Zagros. However, new structural and stratigraphic data show that the most-proximal Bakhtiyari exposures, in the High Zagros south of Shahr-kord, were deposited during the early Miocene and probably Oligocene. In this locality, a coarse-grained Bakhtiyari succession several hundred meters thick contains gray marl, limestone, and sandstone with diagnostic marine pelecypod, gastropod, coral, and coralline algae fossils. Foraminiferal and palynological species indicate deposition during early Miocene time. However, the lower Miocene marine interval lies in angular unconformity above ~ 150 m of Bakhtiyari conglomerate that, in turn, unconformably caps an Oligocene marine sequence. These relationships attest to syndepositional deformation and suggest that the oldest Bakhtiyari conglomerate could be Oligocene in age.

The new age information constrains the timing of initial foreland-basin development and proximal Bakhtiyari deposition in the Zagros hinterland. These findings reveal that structural evolution of the High Zagros was underway by early Miocene and probably Oligocene time, earlier than commonly envisioned. The age of the Bakhtiyari Formation in the High Zagros contrasts significantly with the Pliocene–Quaternary Bakhtiyari deposits near the modern deformation front, suggesting a long-term (> 20 Myr) advance of deformation toward the foreland.     

Application of remote sensing technology for Impact Assessment of Watershed Development Programme

The current study was taken up to investigate the utility of remote sensing and GIS tools for evaluation of Integrated Wasteland Development Programme (IWDP) implemented during 1997–2001 in Katangidda Nala watershed, Chincholi taluk, Gulbarga district, Karnataka. The study was carried out using IRS 1C, LISS III data of December 11, 1997 (pre-treatment) and November 15, 2002 (post-treatment) covering the watershed to assess the changes in land use / land cover and biomass that have changed over a period of five years (1997–2002). The images were classified into different land use/land cover categories using supervised classification by maximum likelihood algorithm. They were also classified into different biomass levels using Normalized Difference Vegetation Index (NDVI) approach. The results indicated that the area under agriculture crops and forest land were increased by 671 ha (5.7%) and 1,414 ha (11.94%) respectively. This is due to the fact that parts of wastelands and fallow lands were brought into cultivation. This increase in the area may be attributed to better utilization of surface and ground waters, adoption of soil and water conservation practices and changes in cropping pattern. The area under waste lands and fallow lands decreased by 1,667 ha (14.07%) and 467 ha (3.94%), respectively. The vegetation vigour of the area was classified into three classes using NDVI. Substantial increase in the area under high and low biomass levels was observed (502 ha and 19 ha respectively). The benefit-cost analysis indicates that the use of remote sensing and GIS was 2.2 times cheaper than the conventional methods. Thus, the repetitive coverage of the satellite data provides an excellent opportunity to monitor the land resources and evaluate the land cover changes through comparison of images for the watershed at different periods.     

Forecasting of cyclone Viyaru and Phailin by NWP-based cyclone prediction system (CPS) of IMD – an evaluation

An objective NWP-based cyclone prediction system (CPS) was implemented for the operational cyclone forecasting work over the Indian seas. The method comprises of five forecast components, namely (a) Cyclone Genesis Potential Parameter (GPP), (b) Multi-Model Ensemble (MME) technique for cyclone track prediction, (c) cyclone intensity prediction, (d) rapid intensification, and (e) predicting decaying intensity after the landfall. GPP is derived based on dynamical and thermodynamical parameters from the model output of IMD operational Global Forecast System. The MME technique for the cyclone track prediction is based on multiple linear regression technique. The predictor selected for the MME are forecast latitude and longitude positions of cyclone at 12-hr intervals up to 120 hours forecasts from five NWP models namely, IMD-GFS, IMD-WRF, NCEP-GFS, UKMO, and JMA. A statistical cyclone intensity prediction (SCIP) model for predicting 12 hourly cyclone intensity (up to 72 hours) is developed applying multiple linear regression technique. Various dynamical and thermodynamical parameters as predictors are derived from the model outputs of IMD operational Global Forecast System and these parameters are also used for the prediction of rapid intensification. For forecast of inland wind after the landfall of a cyclone, an empirical technique is developed. This paper briefly describes the forecast system CPS and evaluates the performance skill for two recent cyclones Viyaru (non-intensifying) and Phailin (rapid intensifying), converse in nature in terms of track and intensity formed over Bay of Bengal in 2013. The evaluation of performance shows that the GPP analysis at early stages of development of a low pressure system indicated the potential of the system for further intensification. The 12-hourly track forecast by MME, intensity forecast by SCIP model and rapid intensification forecasts are found to be consistent and very useful to the operational forecasters. The error statistics of the decay model shows that the model was able to predict the decaying intensity after landfall with reasonable accuracy. The performance statistics demonstrates the potential of the system for improving operational cyclone forecast service over the Indian seas.     

Sicilian serpentinite xenolihs conaining abioic organics wih nanodiamond clusers ans key model for prebioic processes

Rock fragments from the deepest parts of a buried hydrothermal system belonging to the Mesozoic Tethys Oceanentered as xenoliths in a Miocenic diatreme. hence b...