Fe isotope systematics of coexisting amphibole and pyroxene in the alkaline igneous rock suite of the Ilímaussaq Complex,South Greenland

The Ilímaussaq intrusion, South Greenland, provides an exceptional test case for investigating the changes of stable Fe isotope fractionation of solidus phases with changes in the Fe³⁺/∑Fe ratio of an evolving melt. The intrusion comprises a sequence of four melt batches that were fed from the same parental alkali basaltic magma. Differentiation produced cumulate rocks that range from augite syenite (phase I) over peralkaline granite (phase II) to agpaitic syenites (phases IIIa and IIIb). Fe³⁺/∑Fe ratios in amphiboles increase substantially from phase I to phase II and III rocks and mark a major change in the parental magma composition from augite syenites to peralkaline granites and agpaitic syenites. Before this transition, olivine, clinopyroxene, and amphibole in augite syenite, the most primitive rock type in the Ilímaussaq Complex, have a uniform Fe isotope composition that is identical to that of the bulk of igneous crustal rocks and approximated by the average isotopic composition of basalts (δ^56/54Fe_IRMM-014 = 0.072 ± 0.046‰). After the transition, amphiboles in the peralkaline granites and agpaitic syenites yield significantly heavier Fe isotope compositions with δ^56/54Fe_IRMM-014 values ranging from 0.123 to 0.237‰. Contamination of the Ilímaussaq magma by ongoing crustal assimilation as cause for this increase can be excluded on the grounds of Nd isotope data. Large-scale metasomatic overprint with an external fluid can also be dismissed based on amphibole O and Li isotope systematics. Rather, the increase towards heavy Fe isotope compositions most likely reflects the change in chemical compositions of amphiboles (calcic in augite syenite to sodic in the agpaitic syenites) and their Fe³⁺/ΣFe ratios that mirror changes in the chemical composition of the melt and its oxygen fugacity. A sensitive adjustment of equilibrium Fe isotope fractionation factors to amphibole ferric/ferrous ratios is also supported by beta-factors calculated from Mössbauer spetroscopy data. Comparison of the measured isotope fractionation between clinopyroxene and amphibole with that predicted from Mössbauer data reveal Fe isotope systematics close to equilibrium in augite syenites but Fe isotopic disequilibrium between these two phases in phase IIIa agpaitic syenites. These results are in agreement with O and Li isotope systematics. While amphiboles in all Ilímaussaq lithologies crystallized at temperatures between 650 and 850 °C, textural evidence reveals later clinopyroxene crystallization at temperatures as low as 300–400 °C. Therefore, isotopic equilibrium at crystallization conditions between these two phases can not be expected, but importantly, subsolidus reequilibration can also be dismissed.     

Sedimentary patterns and geometries of the Bahamian outer carbonate ramp (Miocene–Lower Pliocene, Great Bahama Bank)

Core, logging and high-resolution seismic data from ODP Leg 166 were used to analyse deposits of the Neogene (Miocene–Lower Pliocene) Bahamian outer carbonate ramp. Ramp sediments are cyclic alternations of light- and dark-grey wackestones/packstones with interbedded calciturbidite packages and minor slumps. Cyclicity was driven by high-frequency sea-level changes. Light-grey layers containing shallow-water bioclasts were formed when the ramp exported material, whereas the dark-grey layers are dominantly pelagic. Calciturbidites are arranged into mounded lobes with feeder channels. Internal bedding of the lobes shows a north-directed shingling as a result of the asymmetrical growth of these bodies. Calciturbidite packages occur below and above sequence boundaries, indicating that turbidite shedding occurred during third-order sea-level highstands and lowstands. Highstand turbidites contain shallow-water components, such as green algal debris and epiphytic foraminifera, whereas lowstand turbidites are dominated by abraded bioclastic detritus. Gravity flow depocentres shifted from an outer ramp position during the early Miocene to a basin floor setting during the late Miocene to early Pliocene. This change was triggered by an intensification of the strength of bottom currents during the Tortonian, which was also responsible for shaping the convex morphology of the outer ramp. The Miocene and Lower Pliocene of the leeward flank of Great Bahama Bank provides an example of the poorly known depositional setting of the outer part of distally steepened carbonate ramps. The contrast between its sedimentary patterns and the well-known Upper Pliocene–Quaternary slope facies associations of the flat-topped Great Bahama Bank shows the strong control that the morphology of a carbonate platform exerts on the depositional architecture of the adjacent slope and base-of-slope successions.     

Coordinated monitoring of the eccentric O-star binary Iota Orionis: optical spectroscopy and photometry

With the objective of investigating the windwind collision phenomenon and supporting contemporaneous X-ray observations, we have organized a large-scale, coordinated optical monitoring campaign of the massive, highly eccentric O9 III+B1 III binary Iota Orionis. Successfully separating the spectra of the components, we refine the orbital elements and confirm the rapid apsidal motion in the system. We also see strong interaction between the components during periastron passage and detect phase-locked variability in the spectrum of the secondary star. However, we find no unambiguous signs of the bow shock crashing on the surface of the secondary, despite the predictions of hydrodynamic simulations. Combining all available photometric data, we find rapid, phase-locked variations and model them numerically, thus restricting the orbital inclination to 50° i 70°.     

Diffraction imaging of sub‐vertical fractures and karst with full‐resolution 3D Ground‐Penetrating Radar

Vertical fractures with openings of less than one centimetre and irregular karst cause abundant diffractions in Ground‐Penetrating Radar (GPR) records. GPR data acquired with half‐wavelength trace spacing are uninterpretable as they are dominated by spatially undersampled scattered energy. To evaluate the potential of high‐density 3D GPR diffraction imaging a 200 MHz survey with less than a quarter wavelength grid spacing (0.05 m × 0.1 m) was acquired at a fractured and karstified limestone quarry near the village of Cassis in Southern France. After 3D migration processing, diffraction apices line up in sub‐vertical fracture planes and cluster in locations of karstic dissolution features. The majority of karst is developed at intersections of two or more fractures and is limited in depth by a stratigraphic boundary. Such high‐resolution 3D GPR imaging offers an unprecedented internal view of a complex fractured carbonate reservoir model analogue. As seismic and GPR wave kinematics are similar, improvements in the imaging of steep fractures and irregular voids at the resolution limit can also be expected from high‐density seismic diffraction imaging.     

Electron Transfer Between Sulfide and Humic Acid: Electrochemical Evaluation of the Reactivity of Sigma-Aldrich Humic Acid Toward Sulfide

Little is known of potential reactivity and redox properties of reduced dissolved organic matter (DOM), although DOM in anoxic environments, e.g., groundwater, peat soils, or lake sediments, can be expected to differ from DOM of oxidized environments. We therefore investigated the impact of electrochemical and wet chemical [hydrogen (H₂)/Pd catalyst] reduction in Sigma-Aldrich humic acid (HA) as a model DOM for high salinity, high ionic strength, or iron-rich systems on its reactivity toward sulfide. Mediated electrochemical measurement showed that the reactivity of HA toward sulfide decreased in the order non-reduced HA > electrochemically reduced (?0.1 V) HA > H₂/Pd-reduced HA > electrochemically reduced (?0.4 V) HA. Results indicated that measured initial values of electron-accepting capacities of HA had a strongly positive correlation with the sulfide transformation, except for the H₂/Pd treatment of HA. This latter treatment obviously changed HA structures and lead to a different reactivity toward sulfide, limiting a direct comparison to electrochemically reduced organic matter. Our result confirmed that reduced HA was still reactive toward sulfide, although to a lower extent compared with oxidized HA. Compared to electrochemical reduction, H₂/Pd pre-treatment of HA alters redox properties and reactivity of organic matter and may therefore lead to results that cannot be transferred to natural systems.     

P-T-X-controlled element transport through granulite-facies ternary feldspar from Lofoten,Norway

Fluid transport on the grain-scale controls many rock properties and governs chemical exchange. Charnockites from Lofoten indicate fluid penetration into ternary alkali feldspars controlled by their microtextures. In a process of fluid infiltration at granulite-facies conditions (∼600°C and 8–11 kbar), tiny pyroxenes enclosed in alkali feldspar reacted to amphiboles, which are always spatially connected to perthitic albite. Investigation of these microtextures by TEM imaging of Focused Ion Beam (FIB) prepared foils revealed that pyroxenes in contact with albite lamellae show dissolution features. An amorphous Fe- and Cl-bearing material interpreted to be a residuum of the percolating fluid was found within albite lamellae. Textures and mineral compositions indicate that a Cl-rich aqueous fluid attacked the lamellae, which then provided pathways for further fluid flow. A correspondence was found between feldspar compositions, their microtexture and their degree of alteration as a result of their permeability for fluids at specific temperatures. Hence, in addition to pressure and temperature, small variations of feldspar composition can strongly influence the fluid permeability of feldspathic rocks under lower crustal conditions.     

Factors contributing to the development of extreme North Atlantic cyclones and their relationship with the NAO

The occurrence of extreme cyclones is analysed in terms of their relationship to the NAO phase and the dominating environmental variables controlling their intensification. These are latent energy (equivalent potential temperature 850 hPa is used as an indicator), upper-air baroclinicity, horizontal divergence and jet stream strength. Cyclones over the North Atlantic are identified and tracked using a numerical algorithm, permitting a detailed analysis of their life cycles. Extreme cyclones are selected as the 10% most severe in terms of intensity. Investigations focus on the main strengthening phase of each cyclone. The environmental factors are related to the NAO, which affects the location and orientation of the cyclone tracks, thus explaining why extreme cyclones occur more (less) frequently during strong positive (negative) NAO phases. The enhanced number of extreme cyclones in positive NAO phases can be explained by the larger area with suitable growth conditions, which is better aligned with the cyclone tracks and is associated with increased cyclone life time and intensity. Moreover, strong intensification of cyclones is frequently linked to the occurrence of extreme values of growth factors in the immediate vicinity of the cyclone centre. Similar results are found for ECHAM5/OM1 for present day conditions, demonstrating that relationships between the environment factors and cyclones are also valid in the GCM. For future climate conditions (following the SRES A1B scenario), the results are similar, but a small increase of the frequency of extreme values is detected near the cyclone cores. On the other hand, total cyclone numbers decrease by 10% over the North Atlantic. An exception is the region near the British Isles, which features increased track density and intensity of extreme cyclones irrespective of the NAO phase. These changes are associated with an intensified jet stream close to Europe. Moreover, an enhanced frequency of explosive developments over the British Isles is found, leading to more frequent windstorms affecting Europe.