Experimental determination of the temperature and pressure dependence of the Fe-Mg partition coefficient for coexisting garnet and clinopyroxene

An experimental study initiated to calibrate the distribution coefficient \(K_D = \frac{{({\text{FeO}}/{\text{MgO}})_{{\text{ga}}} }}{{{\text{(FeO}}/{\text{MgO)}}_{{\text{cpx}}} }}\) in eclogites as a geothermometer has been done on (a) a mineral mis, (b) a glass of the typical tholeiite composition and (c) a series of glasses of tholeiite compositions with \(6.2 < \frac{{100{\text{Mg}}}}{{{\text{Mg}} + {\text{Fe}}^{ + + } }} < 93.\) The mineral mix was found to be unsuitable as reactant due to incomplete equilibration but the minimum K _D of the mineral mix and the K _D from glass of tholeiite composition are identical within experimental uncertainty. These data constitute a reversal of the garnet/clinopyroxene partition relationship and provide justification of the use of glass as a reactant for the project. To eliminate any uncertainty in interpretation of mineral analyses due to possible variation in Fe⁺⁺⁺/Fe⁺⁺ between runs, experiments were carried out in iron capsules on the nine tholeiite glasses, thus maintaining iron as Fe⁺⁺. Microprobe analytical techniques yielded mineral analyses of comparable accuracy to analyses of natural phases for experiments within the temperature range from 600° C to 1500° C and a pressure range from 20 kb to 40 kb. It has been shown that for \(6.2 < \frac{{100{\text{Mg}}}}{{{\text{Mg}} + {\text{Fe}}^{ + + } }} < 85\) , the bulk chemical composition does not perceptibly affect the K _D value. At 30 kb the K _D value ranges from 18.0 at 600° C to 1.45 at 1400° C, defining the linear relationship in a ln K _D vs 1/T(°K) plot. The pressure dependence of the K _D -value has been shown to be greater than previously predicted. There is a straight line relationship in ln K _D vs Pressure (Kb) between 20 and 40 kb at constant temperature (1100°C). This enables us to determine K _D =fn (T, P) and \(T(^\circ {\text{K}}) = \frac{{3686 + 28.35 \times P({\text{Kb}})}}{{\ln K_D + 2.33}}\) . This expression uniquely determines the temperature of equilibration of natural eclogites of basaltic bulk composition when the K _D ^ga,cpx is known and a pressure estimate can be given.     

Lunar and solar daily variations of the geomagnetic field at Toolangi

Summary Mean hourly values of magnetic declination, horizontal intensity and vertical intensity observed at Toolangi during two ten year periods (1924–1933 and 1949–1958) have been analysed to determine their solar and luni-solar diurnal components. The results, showing the variations of the first four harmonic components with season, degree of magnetic activity and annual sunspot number, are tabulated and discussed. It is shown that there are marked differences in the dependence ofS andL on the various parameters and a tentative explanation of this phenomenon is given.     

Synthetic high-pressure micas compositionally intermediate between the dioctahedral and trioctahedral mica series

Intermediate-composition micas with octahedral occupancy 2.5 have been crystallized experimentally from natural phengite, 50% phengite+50% biotite, and synthetic basalt compositions in the pressure range 20–35 kb and temperatures of 800–1,000° C. Their compositions suggest a complete range of micas with octahedral occupancy between 3.0 and 2.5, but a very restricted range between 2.0 and 2.5. These 2.5-octahedral micas lie close to the new mica series proposed by Seifert and Schreyer (1965, 1971), with one end-member composition of K Mg_2.5 (Si₄O₁₀) (OH₂) which is extended by the present results into alumina-bearing members of the series (e. g. K Mg_1.5 Al_1.0 (Si₃Al_1.0O₁₀) (OH)₂). However, the possibility of interlayering of dioctahedral and trioctahedral micas to give an apparently intermediate composition cannot be ruled out. X-ray powder diffraction data on the critical 060 reflection for the phengite mix suggest a transitional change from a single phengite field, through a 2-phase phengite — 2.5-octahedral mica field to a single phase 2.5-octahedral mica field.Natural micas of similar composition have not so far been identified, due probably to the unlikelihood of obtaining a mineralogical record of an appropriate composition at the restricted pressure and temperature conditions apparently needed to stabilize the 2.5-octahedral mica phase. Nevertheless, such a phase may have an important role in mineral assemblages and melting reactions in the deep continental crust, subducted oceanic crust and in the upper mantle; evidence of its existence may be removed by later, lower-pressure reactions.     

Sensitivity of Spatial Analysis Neural Network Training and Interpolation to Structural Parameters

A Spatial Analysis Neural Network (SANN) algorithm was applied for the analysis of geospatial data, on the basis of nonparametric statistical analysis and the concepts of traditional Artificial Neural Networks. SANN consists of a number of layers in which the neurons or nodes between layers are interconnected successively in a feed-forward direction. The Gaussian Kernel Function layer has several nodes, and each node has a transfer or an activation function that only responds (or activates) when the input pattern falls within its receptive field, which is defined by its smoothing parameter or width. The activation widths are functions of the model structural parameters, including the number of the nearest neighbor points P and a control factor F. The estimation method is based on two operational modes, namely, a training-validation mode in which the model structure is constructed and validated, and an interpolation mode. In this paper we discuss the effect of varying F and P upon the accuracy of the estimation in a two-dimensional domain for different input field sizes, using spatial data of wheat crop yield from Eastern Colorado. Crop yield is estimated as a function of the two-dimensional Cartesian coordinates (easting and northing). The results of the research led to the conclusion that optimal values of F and P depend on the sample size, i.e., for small data sets F=1.5 and P=7 while for large data sets F=2.5 and P=9. In addition, the accuracy of the interpolated field varies with the sample size. As expected for small sample sizes, the interpolated field and its variability may be significantly underestimated.     

Effect of macrophyte spatial variability on channel resistance

Aquatic macrophytes can severely retard flow rates in the river channels that they occupy. Consequently, there is a need to improve our ability to model vegetation resistance, to aid flood prediction and allow for better-informed channel management. An empirical model is developed to calculate flow resistance (Manning’s resistance coefficient) of channels containing the submergent macrophyte Ranunculus (water-crowfoot). Blockage factors (the proportion of a cross-section blocked by vegetation) were determined for up to nine cross-sections at each of 35 river sites. These were used to create blockage-factor percentiles, which were regressed against vegetation resistance. An exponential best-fit relation involving the 69th blockage-factor percentile gave the best results. A parameter relating the length of the vegetated/solid boundary in contact with the open channel to the length of the conventionally-defined wetted perimeter improved the model fit by acting as a pseudo-measure of the turbulent-energy losses generated within the unvegetated stream by the macrophytes. The model was tested on three additional sites containing different macrophyte species and much higher vegetation blockages, and was found to work well.     

Using a Large-Aperture Scintillometer to Measure Absorption and Refractive Index Fluctuations

The contributions of refraction and absorption fluctuations to the measured scintillations are observed for a near-infrared absorption region using a NOAA designed large-aperture scintillometer. The logarithmic amplitude spectra are shown to decay with frequency as f^-8/3 for both the absorption and scattering mechanisms. For the absorption mechanism this is in line with similar observations made at microwave and infrared frequencies. However, for finite transmitting and receiving apertures, theory predicts a stronger decay of the scattering mechanism due to aperture averaging. The spectral shape is characterised by a region of low frequency absorption, higher frequency refraction and separated by a flattish transition zone. The upper observed corner frequency (f_C2) compares well with values calculated using the measured transverse windspeed (v) for a known aperture radius. The lower corner frequency (f_C1) position is shown to be sensitive to the ratio of the real and imaginary part of the refractive index structure parameter, (C _nR ² /C _nI ² )^3/8, and v. The part of the spectrum associated with the absorption scintillations is observed to be much less than that due to refraction through the day until evening, when decreasing C _nR ² causes C _nR ² /C _nI ² to decrease and absorption to become significant. If absorption is ignored, this may have consequences for calculating nocturnal surface fluxes. During unstable, daytime conditions the large aperture scintillometer is most sensitive to refractive scintillations despite having an infrared source transmitting in a lossy atmosphere. But also under these conditions, the low frequency absorption part of the spectrum is observable.     

Bimodal wave spectra in lower Chesapeake Bay, sea bed energetics and sediment transport during winter storms

The transition zone separating estuarine environments from the coastal ocean is characterized not only by distinctive morphological and sedimentary trends but by unique hydrodynamic forces as well. Lower Chesapeake Bay, a large coastal estuary within the Mid-Atlantic Bight of the U.S. East Coast, experiences complex wave and current-induced forces produced during winter storms. Wave and current measurements made near Thimble Shoal Light over five winter seasons show that most storms simultaneously produce both ocean and bay-generated wave trains that appear as distinct bimodal peaks in directional spectra. Analysis of selected storm wave records reveal that lower-frequency ocean waves, although nominally lower in amplitude than higher-frequency bay waves, are roughly equivalent to bay waves in terms of energy expended on beds of fine- to medium-grained sand at either end of the Thimble Shoal Channel. Grain-friction energy dissipation estimates calculated for waves and currents suggest that waves provide more net energy capable of transporting bottom sediment than currents, although strong barotropic flows briefly encountered during a major storm on 13–14 March 1993, exceeded wave energy expended at the bed by almost an order of magnitude. From analyses of wave orbital velocity spectra, it is shown that dual wave trains characterized by differences in peak frequency and direction may assist each other through interactions that increase their combined contribution to frictional energy dissipation and inferred sediment transport at the bed.     

Gender-specific local labour market areas in England and Wales

Local labour market areas (LLMAs) are usually defined on the basis of total commuting flows between constituent ‘building block’ areas. Indeed the 1984 revision of Travel-To-Work Areas (TTWAs) was based on aggregate flows between 1981 Census wards. It is widely recognized, however, that various sub-groups of the population have distinctive commuting patterns. TTWAs therefore represent the outcome of an ‘averaging’ of the journey-to-work patterns of different gender, socio-economic and occupational groups. In this preliminary review, the self-containment of TTWAs in England and Wales, which have been generated using aggregate data, is assessed at the simplest level of disaggregation of the commuting data: disaggregation by gender. In accordance with expectations, it is found that TTWAs defined on the basis of total commuting flows are generally more self-contained for females than for males, and that those TTWAs which are insufficiently self-contained to be considered as LLMAs for males are overwhelmingly concentrated in the most urbanized regions. These findings are reinforced by the results of re-running the TTWA regionalization algorithm against 1981 flow data for males and females in order to create gender-specific TTWAs; disparities between Male and Female TTWAs are greatest in the most urbanized regions. Such differences are investigated in greater detail for two Metropolitan Regions (MRs): the combined Liverpool and Manchester MRs in the north-west and the London MR in the south-east.     

Microfossils from silicified stromatolitic carbonates of the Upper Proterozoic Limestone-Dolomite 'Series', central East Greenland

Silicified flake conglomerates and in situ stratiform stromatolites of the Upper Proterozoic (c. 700-800 Ma) Limestone-Dolomite 'Series', central East Greenland, contain well preserved microfossils. Five stratigraphic horizons within the 1200 m succession contain microbial mat assemblages, providing a broad palaeontological representation of late Proterozoic peritidal mat communities. Comparison of assemblages demonstrates that the taxonomy and diversity of mat builder, dweller, and allochthonous populations all vary considerably within and among horizons. The primary mat builder in most assemblages is Siphonophycus inornatum, a sheath-forming prokaryote of probable but not unequivocally established cyanobacterial affinities. An unusual low diversity unit in Bed 17 is dominated by a different builder, Tenuofilum septatum, while a thin cryptalgal horizon in Bed 18 is built almost exclusively by Siphonophycus kestron. Although variable taphonomic histories contribute to observed assemblage variation, most differences within and among horizons appear to reflect the differential success or failure of individual microbial populations in colonizing different tidal flat microenvironments. Twenty-two taxa are recognized, of which two are described as new: Myxococcoides stragulescens n.sp. and Scissilisphaera gradata n. sp.