Petrographic prediction of coking properties for the Curragh coals of Australia

Curragh Queensland Mining Limited, Australia, produces a high quality medium volatile bituminous coking coal from the Orion, Pollux and Castor seams from the upper Permian Rangal Coal Measures. It is one of the lowest ash, prime hard coking coal blends produced in Australia. It is also low in sulfur and produces very strong coke when carbonized alone and in blends. Early attempts to predict coking properties of the coals from petrographic data produced predicted coke stabilities that were significantly lower than those determined from coke tests. There is some question as to how much of the ‘inertinite’ in these and other southern hemisphere coals is truly inert during carbonization and how much is reactive. The current study characterized the Curragh coals in terms of physical, chemical and petrographic characteristics and also involved the production of test oven cokes for characterization and strength testing. As part of the work effort a series of suggested techniques for improving predictions of coke strength from petrographic data were examined and a new and improved technique was developed for the Curragh coals. How broadly the technique can be applied to other coals needs to be determined.     

General conservation equations for multi-phase systems: 3. Constitutive theory for porous media flow

Equations which describe single phase fluid flow and transport through an elastic porous media are obtained by applying constitutive theory to a set of general multiphase mass, momentum, energy, and entropy equations. Linearization of these equations yields a set of equations solvable upon specification of the material coefficients which arise. Further restriction of the flow to small velocities proves that Darcy's law is a special case of the general momentum balance.     

The isotopic composition of carbon in the Alberta oil sand

The carbon isotopic ratios obtained from Athabasca bitumen, asphaltene and maltene have the same value $\text{δ}{}^{13}\text{C}\text{= ?29.6}\text{per ml}$. The corresponding values in the Cold Lake deposits are ?30.6, ?30.0 and ?31.6 per ml. The ratios determined for methane collected from the oil sand and its fractions are about 15 per ml lower than the above values. It appears that the Athabasca and Cold Lake Reservoirs have similar histories.     

Cleavage-fold relationships and their implications for transected folds: an example from southwest Virginia,U.S.A.

A non-coaxial deformation involving pre-folding initiation of cleavage perpendicular to bedding is proposed to explain non-axial planar cleavage associated with mesoscopic folds in part of the Appalachian foreland thrust-belt of southwest Virginia. Folds are gently plunging, asymmetric, upright to slightly inclined, sinusoidal forms with non-axial fanning cleavage. They show extreme local variations in type and degree of transection and the consistency of transection direction. These relations are further complicated by hinge migration.Cleavage-fan angles, bedding-cleavage angles and δ transection values appear influenced by fold tightness, and in part by fold flattening strain. Fold flattening increments are considered simultaneous with folding. Axial surface traces, and not cleavage traces, coincide with the principal extension direction in fold profiles. Geometric modelling of cleavage fanning and bedding-cleavage angle variations for various theoretical folding modes suggest that folding in limestone and sandstone layers was by tangential longitudinal strain. Significant shape modification and change in bedding-cleavage relations occurred after limb dips of 40 and 50° were attained in limestone and sandstone respectively. Mud-rock class 1C folds with convergent cleavage fans show features transitional between buckling and flexural flow. Initiation of ‘cleavage’ fabrics during layer-parallel shortening prior to significant folding may be important for cleavage evolution in some deformed rocks.     

Neodymium-strontium isotopic evidence for extreme contamination in a layered basic intrusion

Neodymium and strontium isotopic analyses from the Kalka layered basic intrusion, central Australia, are arrayed parallel to the Sr-axis of a Nd-Sr isotopic correlation diagram and are removed from the normal basaltic field. Initial¹⁴³Nd/¹⁴⁴Nd ratios are almost constant and typical of continental basalts, whereas initial⁸⁷Sr/⁸⁶Sr ratios vary greatly and range to high values (0.7049–0.7088). Acidic granulites from the country rock lie upon the continuation of the Kalka trend at higher⁸⁷Sr/⁸⁶Sr ratios outlining a mixing system between granulite and normal basaltic magma. If average granulite acted as a contaminant, isotope dilution calculations show that amounts assimilated reached as high as 25%. Bulk contamination is confirmed petrologically by the abundance of orthopyroxene, particularly as basal orthopyroxenites and the restriction of olivine to less-contaminated levels. Analogies between Kalka and several other major layered intrusions, such as the Bushveld Complex, suggest that large-scale contamination was a significant aspect of their genesis.     

Microwave remote sensing of sea ice in the AIDJEX Main Experiment

During the AIDJEX Main Experiment, April 1975 through May 1976, a comprehensive microwave sensing program was performed on the sea ice of the Beaufort Sea. Surface and aircraft measurements were obtained during all seasons using a wide variety of active and passive microwave sensors. The surface program obtained passive microwave measurements of various ice types using four antennas mounted on a tracked vehicle. In three test regions, each with an area of approximately 1.5 × 10⁴ m², detailed ice crystallographic, dielectric properties, and brightness temperatures of first-year, multiyear, and first-year/multiyear mixtures were measured. A NASA aircraft obtained passive microwave measurements of the entire area of the AIDJEX manned station array (triangle) during each of 18 flights. This verified the earlier reported ability to distinguish first-year and multiyear ice types and concentration and gave new information on ways to observe ice mixtures and thin ice types. The active microwave measurements from aircraft included those from an X- and L-band radar and from a scatterometer. The former is used to study a wide variety of ice features and to estimate deformations, while both are equally usable to observe ice types. With the present data, only the scatterometer can be used to distinguish positively multiyear from first-year and various types of thin ice. This is best done using coupled active and passive microwave sensing.We dedicate this work to our beloved friend William NordbergHe pioneered in microwave ice observations, and his brilliance and enthusiasm inspired all of us.     

Determination of the 87Rb decay constant

The decay constant ⁸⁷Rb has been redetermined by measuring the amount of radiogenic ⁸⁷Sr produced over a period of 19 years, in 20 g samples of purified RbClO₄, using isotope dilution techniques. The rubidium sample was spiked with ⁸⁴Sr and the nanogram quantities of strontium separated by coprecipitation with Ba(NO₃)₂. Analyses were carried out on a 25cm, 90° sector mass spectrometer equipped with a Spiraltron electron multiplier. Measurement of three independent ratios permitted continuous monitoring of the ion beam fractionation. The average of nine determinations gives a value for the decay constant of $\text{1.419(±0.012) × 10}{}^{\mathrm{?11}}\text{yr}{}^{\mathrm{?1}}\text{(2σ)}$. [$\text{τ}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 4.89(±0.04) × 10}{}^{10}\text{yr}$.]