Trace metals (e.g. Ni, Zn) leached from industrial and agricultural processes are often simultaneously present in contaminated soils and sediments. Their mobility, bioavailability, and ecotoxicity are affected by sorption and cosorption at mineral/solution interfaces. Cosorption of trace metals has been investigated at the macroscopic level, but there is not a clear understanding of the molecular-scale cosorption processes due to lack of spectroscopic information. In this study, Ni and Zn cosorption to aluminum oxides (γ-Al2O3) in binary-sorbate systems were compared to their sorption in single-sorbate systems as a function of pH using both macroscopic batch experiments and synchrotron-based X-ray absorption fine structure spectroscopy. At pH 6.0, Ni and Zn were sorbed as inner-sphere surface complexes and competed for the limited number of reactive sites on γ-Al2O3. In binary-sorbate systems, Ni had no effect on Zn sorption, owning to its lower affinity for the metal oxide surface. In contrast, Zn had a higher affinity for the metal oxide surface and reduced Ni sorption. At pH 7.5, Ni and Zn were sorbed as mixed-metal surface precipitates, including Ni–Al layered double hydroxides (LDHs), Zn–Al LDHs, and likely Ni–Zn–Al layered triple/ternary hydroxides. Additionally, at pH 7.5, Ni and Zn do not exhibit competitive sorption effects in the binary system. Taken together, these results indicated that pH critically influenced the reaction products, and provides a crucial scientific basis to understand the potential mobility, bioavailability, and ecotoxicity of Ni and Zn in natural and contaminated geochemical environments.
Acta Geotechnica - Drying induced consolidation is ubiquitous in nature, yet no theoretical model is available to delineate this phenomenon. Fundamentally, this phenomenon is a multi-physical... 相似文献
Although hydraulic fracturing has been massively studied and applied as a key technique to enhance the gas production from tight formations, some problems and uncertainties exist to accurately predict and analyze the fracture behavior in complex reservoirs, especially in the naturally fractured reservoirs like shale reservoirs. This paper presents a full 3D numerical model (FLAC3D) to study hydraulic fracturing behavior under the impact of preexisting orthogonal natural fractures. In this numerical model, the hydraulic fracture propagation direction is assumed perpendicular to the minimum principal stress and activated only by tensile failure, whereas the preexisting natural fractures can be activated by tensile or shear failure or a combination of them, and only tensile failure can open the natural fracture as well. The newly developed model was used to study the impact of preexisting orthogonal natural fractures on hydraulic fracturing behavior, based on a multistage hydraulic fracturing operation in a naturally fractured reservoir from the Barnett Shale formation, northwest of Texas in USA. In this multistage operation, two more representative stages, i.e., stage 1 with a relatively large horizontal stress anisotropy of 3.3 MPa and stage 4 with a comparatively small one of 1.3 MPa, were selected to conduct the simulation. Based on the numerical results, one can observe that the interaction between hydraulic and natural fracture is driven mainly by induced stress around fracture tip. Besides, the horizontal stress anisotropy plays a key role in opening the natural fracture. Thus, no significant opened fracture is activated on natural fracture in stage 1, while in stage 4 an opened fracture invades to about 90 m into the first natural fracture. Conversely, the hydraulic fracture length in stage 1 is much longer than in stage 4, as some fluid volume is stored in the opened natural fracture in stage 4. In this work, the shear failure on natural fractures is treated as the main factor for inducing the seismic events. And the simulated seismic events, i.e., shear failure on natural fractures, are very comparable with the measured seismic events.
A Q-band two-beam cryogenic receiver for the Tianma Radio Telescope(TMRT)has been developed,and it uses the independently-developed key microwave and millimeter-wave components operating from 35 to 50 GHz with a fractional bandwidth of 35%.The Q-band receiver consists of three parts:optics,cold unit assembly and warm unit assembly,and it can receive simultaneously the lefthanded and right-handed circularly polarized waves.The cold unit assembly of each beam is composed of a feed horn,a noise injection coupler,a differential phase shifter,an orthomode transducer and two low-noise amplifiers,and it works at a temperature range near 20 K to greatly improve the detection sensitivity of the receiving system.The warm unit assembly includes four radio-frequency amplifiers,four radio-frequency high-pass filters,four waveguide biased mixers,four 4–12 GHz intermediate-frequency amplifiers and one 31–38 GHz frequency synthesizer.The measured Q-band four-channel receiver noise temperatures are roughly 30–40 K.In addition,the single-dish spectral line and international very long baseline interferometry(VLBI)observations between the TMRT and East Asia VLBI Network at the Q-band have been successfully carried out,demonstrating the advantages of the TMRT equipped with the state-of-the-art Q-band receiver. 相似文献
A plate submerged at a certain depth underneath the sea surface has been proposed as a structure type for different purposes, including motion response reduction, wave control, and wave energy harvesting. In the present study, the three-dimensional wave radiation problem is investigated in the context of the linear potential theory for a submerged ring plate in isolation or attached to a floating column as an appendage. In the latter case, the ring plate is attached at a certain distance above the column bottom. The structure is assumed to undergo a heave motion. An analytical model is developed to solve the wave radiation problem via the eigenfunction expansion method in association with the region-matching technique. With the velocity potential being available, the hydrodynamic coefficients, such as added mass and radiation damping, are obtained through the direct pressure integration. An alternative solution of radiation damping has also been developed in this study, in which the radiation damping is related to the Kochin function in the wave radiation problem. After validating the present model, numerical analysis is performed in detail to assess the influence of various plate parameters, such as the plate size and submergence depth. It is noted that the additional added mass due to the attached ring plate is larger than that when the plate is in isolation. Meanwhile, the radiation damping of the column for the heave motion can vanish at a specific wave frequency by attaching a ring plate, corresponding to a condition that there exist no progressive waves in the exterior region. 相似文献
