Dealing with drought: The challenge of using water system technologies to break dryland poverty traps

We explore strategies among farmers in semi-arid Tanzania to cope with drought, and investigate if access to a local supplemental irrigation system (the Ndiva system) can improve coping capacity. Results show high dependency on local ecosystem services when harvests fail, and indicate that farmers commonly exhaust asset holdings during droughts. Ndiva access did not have any direct effects on coping capacity, but seemed to have some indirect effects. Drawing on our findings we discuss the complexity of escaping persistent dryland poverty, and outline the circumstances under which small-scale water system technologies, such as Ndiva irrigation, may help.     

Diurnal thermal tides in a non-synchronized hot Jupiter

We perform a linear analysis to investigate the dynamical response of a non-synchronized hot Jupiter to stellar irradiation. In this work, we consider the diurnal Fourier harmonic of the stellar irradiation acting at the top of a radiative layer of a hot Jupiter with no clouds and winds. In the absence of the Coriolis force, the diurnal thermal forcing can excite internal waves propagating into the planet's interior when the thermal forcing period is longer than the sound crossing time of the planet's surface. When the Coriolis effect is taken into consideration, the latitude-dependent stellar heating can excite weak internal waves (g modes) and/or strong baroclinic Rossby waves (buoyant r modes) depending on the asynchrony of the planet. When the planet spins faster than its orbital motion (i.e. retrograde thermal forcing), these waves carry negative angular momentum and are damped by radiative loss as they propagate downwards from the upper layer of the radiative zone. As a result, angular momentum is transferred from the lower layer of the radiative zone to the upper layer and generates a vertical shear. We estimate the resulting internal torques for different rotation periods based on the parameters of HD 209458b.     

Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.     

Biogenic nanoparticulate UO2: Synthesis, characterization, and factors affecting surface reactivity

The surface reactivity of biogenic, nanoparticulate UO₂ with respect to sorption of aqueous Zn(II) and particle annealing is different from that of bulk uraninite because of the presence of surface-associated organic matter on the biogenic UO₂. Synthesis of biogenic UO₂ was accomplished by reduction of aqueous uranyl ions, by Shewanella putrefaciens CN32, and the resulting nanoparticles were washed using one of two protocols: (1) to remove surface-associated organic matter and soluble uranyl species (NAUO2), or (2) to remove only soluble uranyl species (BIUO2). A suite of bulk and surface characterization techniques was used to examine bulk and biogenic, nanoparticulate UO₂ as a function of particle size and surface-associated organic matter. The N₂-BET surface areas of the two biogenic UO₂ samples following the washing procedures are 128.63 m² g⁻¹ (NAUO2) and 92.56 m² g⁻¹ (BIUO2), and the average particle sizes range from 5-10 nm based on TEM imaging. Electrophoretic mobility measurements indicate that the surface charge behavior of biogenic, nanoparticulate UO₂ (both NAUO2 and BIUO2) over the pH range 3-9 is the same as that of bulk. The U L_III-edge EXAFS spectra for biogenic UO₂ (both NAUO2 and BIUO2) were best fit with half the number of second-shell uranium neighbors compared to bulk uraninite, and no oxygen neighbors were detected beyond the first shell around U(IV) in the biogenic UO₂. At pH 7, sorption of Zn(II) onto both bulk uraninite and biogenic, nanoparticulate UO₂ is independent of electrolyte concentration, suggesting that Zn(II) sorption complexes are dominantly inner-sphere. The maximum surface area-normalized Zn(II) sorption loadings for the three substrates were 3.00 ± 0.20 μmol m⁻² UO₂ (bulk uraninite), 2.34 ± 0.12 μmol m⁻² UO₂ (NAUO2), and 2.57 ± 0.10 μmol m⁻² UO₂ (BIUO2). Fits of Zn K-edge EXAFS spectra for biogenic, nanoparticulate UO₂ indicate that Zn(II) sorption is dependent on the washing protocol. Zn-U pair correlations were observed at 2.8 ± 0.1 Å for NAUO2 and bulk uraninite; however, they were not observed for sample BIUO2. The derived Zn-U distance, coupled with an average Zn-O distance of 2.09 ± 0.02 Å, indicates that Zn(O,OH)₆ sorbs as bidentate, edge-sharing complexes to UO₈ polyhedra at the surface of NAUO2 nanoparticles and bulk uraninite, which is consistent with a Pauling bond-valence analysis. The absence of Zn-U pair correlations in sample BIUO2 suggests that Zn(II) binds preferentially to the organic matter coating rather than the UO₂ surface. Surface-associated organic matter on the biogenic UO₂ particles also inhibited particle annealing at 90 °C under anaerobic conditions. These results suggest that surface-associated organic matter decreases the reactivity of biogenic, nanoparticulate UO₂ surfaces relative to aqueous Zn(II) and possibly other environmental contaminants.     

Hydrocarbons generated by hydropyrolysis of suspended marine particulate organic matter: Relationship to the oceanography of the Black Sea and the Rhodes Gyre

The suspended particulate organic matter, SPOM, in the autumnal Black Sea has been characterised using catalytic hydropyrolysis (HyPy) of the total (bound plus free) lipid material. The technique, which generates maximum yields of volatile products from sediments, kerogens and phytoplankton, was followed using gas chromatography and gas chromatography/mass spectrometry. The generated alkanes were dominated by n-C₁₈, hypothesised to arise predominantly from unsaturated C₁₈ fatty acids. Steranes were generated from reductive conversion of free and bound sterols. The generation of branched alkanes and especially of hopanes provided formal evidence for the participation of bacteria in the mineralisation of the SPOM. Whereas similar distributions of n-alkanes were generated from SPOM sampled from different depths of the comparatively well-stirred Rhodes Gyre (eastern Mediterranean), mineralisation of the SPOM at each depth of the central Black Sea produced characteristic changes in the composition and concentration of the HyPy products. Depth profiles of the n-alkanes generated from SPOM in the region of the Rim Current were affected by the local hydrography. Polynuclear aromatic hydrocarbons (PAHs) of anthropogenic origin were present in the surface waters of the central Black Sea. Some methyl benzenes, thiophenes and pyrroles were also generated.     

Babbling brook to thunderous torrent: Using sound to monitor river stage

The passive, ambient sound above the water from a river has previously untapped potential for determining flow characteristics such as stage. Measuring sub-aerial sound could provide a new, efficient way to continuously monitor river stage, without the need for in-stream infrastructure. Previous published work has suggested that there might be a relationship between sound and river stage, but the analysis has been restricted to a narrow range of flow conditions and river morphologies. We present a method to determine site suitability and the process of how to record and analyse sound. Data collected along a 500 m length of the River Washburn during July 2019 is used to determine what makes a site suitable for sound monitoring. We found that sound is controlled by roughness elements in the channel, such as a boulder or weir, which influences the sound produced. On the basis of these findings, we collect audio recordings from six sites around the northeast of England, covering a range of flow conditions and different roughness elements, since 2019. We use data from those sites collected during storms Ciara and Dennis to produce a relationship between this sound and river stage. Our analysis has shown a positive relationship between an R² of 0.73 and 0.99 in all rivers, but requires careful site selection and data processing to achieve the best results. We introduce a filter that is capable of isolating a river's sound from other environmental sound. Future work in examining the role of these roughness elements is required to understand the full extent of this technique. By demonstrating that sound can operate as a hydrometric tool, we suggest that sound monitoring could be used to provide cost-effective monitoring devices, either to detect relative change in a river or, after more research, a reliable stage measurement.     

Lensing, reddening and extinction effects of Mg ii absorbers from z= 0.4 to 2

Using a sample of almost 7000 strong Mg  ii absorbers with   W ₀ > 1 Å  and  0.4 < z < 2.2  detected in the SDSS DR4 data set, we investigate the gravitational lensing and dust extinction effects they induce on background quasars. After carefully quantifying several selection biases, we isolate the reddening effects as a function of redshift and absorber rest equivalent width, W ₀. We find the amount of dust to increase with cosmic time as  τ( z ) ∝ (1 + z )^−1.1±0.4  , following the evolution of cosmic star density or integrated star formation rate. We measure the reddening effects over a factor of 30 in E ( B − V ) and we find that  τ∝ ( W ₀)^1.9±0.1  , providing us with an important scaling for theoretical modelling of metal absorbers. We also measure the dust-to-metal ratio and find it similar to that of the Milky Way. In contrast to previous studies, we do not detect any gravitational magnification by Mg  ii systems. We measure the upper limit  μ < 1.10  and discuss the origin of the discrepancy. Finally, we estimate the fraction of absorbers missed due to extinction effects and show that it rises from 1 to 50 per cent in the range  1 < W ₀ < 6 Å  . We parametrize this effect and provide a correction for recovering the intrinsic  ∂ N /∂ W ₀  distribution.     

Post‐impact alteration of surficial suevites in Ries crater,Germany: Hydrothermal modification or weathering processes?

Abstract— Alteration of surficial suevites at Ries crater, Germany was studied by means of X‐ray diffraction and scanning electron microscopy. Here, we discuss the origin of hydrous silicate (clay) phases in these suevites that have been previously interpreted as resulting from post‐impact hydrothermal processes. The results of this study indicate that the dominant alteration phases are dioctahedral Al‐Fe montmorillonite and halloysite, which are typical low temperature clay minerals. We suggest that the surficial suevites are not altered by hydrothermal processes and that alteration occurred by low temperature subsurface weathering processes. If the surficial suevites were indeed hydrothermally modified during the early stages of post‐impact cooling, then the alteration was of limited character and is completely masked by later weathering.     

Detection of C2HD and the D/H ratio on Titan

We report here the first detection of mono-deuterated acetylene (acetylene-d1, C₂HD) in Titan's atmosphere from the presence of two of its emission bands at 678 and 519 cm⁻¹ as observed in CIRS spectral averages of nadir and limb observations taken between July 2004 and mid-2007. By using new laboratory spectra for this molecule, we were able to derive its abundance at different locations over Titan's disk. We find the C₂HD value () to be roughly constant with latitude from the South to about 45° N and then to increase slightly in the North, as is the case for C₂H₂. Fitting the 678 cm⁻¹ν₅ band simultaneously with the nearby C₂H₂ 729 cm⁻¹ν₅ band, allows us to infer a D/H ratio in acetylene on Titan with an average of the modal values of 2.09±0.45×¹⁰⁻⁴ from the nadir observations, the uncertainties being mainly due to the vertical profile used for the fit of the acetylene band. Although still subject to significant uncertainty, this D/H ratio appears to be significantly larger than the one derived in methane from the CH₃D band (upper limit of 1.5×¹⁰⁻⁴; Bézard, B., Nixon, C.A., Kleiner, I., Jennings, D.E., 2007. Icarus, 191, 397-400; Coustenis, A., Achterberg, R., Conrath, B., Jennings, D., Marten, A., Gautier, D., Bjoraker, G., Nixon, C., Romani, P., Carlson, R., Flasar, M., Samuelson, R.E., Teanby, N., Irwin, P., Bézard, B., Orton, G., Kunde, V., Abbas, M., Courtin, R., Fouchet, Th., Hubert, A., Lellouch, E., Mondellini, J., Taylor, F.W., Vinatier, S., 2007. Icarus 189, 35-62). From the analysis of limb data we infer D/H values of (at 54° S), (at 15° S), (at 54° N) and (at 80° N), which average to a mean value of 1.63±0.27×¹⁰⁻⁴.