Marine geochemistry—2: scavenging redux

Inorganic surfaces sorb dissolved and particulate phases from seawater onto organic films from a variety of sources. Heavy metals such as Au, Pt, Mn and Cd come to the coatings primarily from particulate phases. This observation confirms a previous finding of this laboratory for the uptake of U, Pu and Po. With depth in the open ocean there are greater contributions from the dissolved phases. Microbial and photochemical processes can enrich surfaces in some metals through reduction reactions. Copper and Mn enrichments in the films are attributed to the photo-reductions of Cu(II) to Cu(I) and manganese oxides to Mn(II), respectively, while the uptake of Mo is a consequence of the reduction, mediated by organisms, of molybdate to Mo(V) or Mo(IV). Cadmium, on the other hand, appears to be bioaccumulated in the films.     

Flexibility and adaptation: some cues for social systems from nature

Complex socioecological systems exist amid great uncertainty. Indeed, much information concerning the environments within which such systems function is likely to remain unknowable. However, over an evolutionary timespan, successful systems develop strategies and tactics for coping with such uncertainty. The present paper describes some of these coping strategies and then extends them to the decision-making process for human-centred socioecological systems to derive an alternative approach to dealing with uncertainty which differs significantly from that encountered in traditional decision analysis.     

Late quaternary environmental history of the southern Levant

The Late Quaternary history of northern Sinai and the western Negev is inferred from a number of stratigraphic sequences rich in prehistoric and archaeologic remains. Exposures are abundant along the wadi courses which drain the highlands westward to the Mediterranean. Earliest deposition is represented by coarse, well rounded gravels containing Middle Paleolithic artifacts and is dated to ca. 90,000 to 70,000 B.P. These are overlain by finer grained sands, silts, and clays, ultimately of eolian origin, but re-deposited by low energy stream flows under marshy conditions. These contain in situ Upper Paleolithic (ca. 40,000 to 22,000 B.P.) and Epi-Paleolithic (ca. 15,000 to 12,000 B.P.) sites; commonly an erosional phase (ca. 22,000 to 15,000 years ago) separates the two groups of industries. In areas closer to the coast, temporally equivalent deposits are predominantly sandy, reflecting their proximity to the source in western and northern Sinai. The Holocene is generally characterized by downcutting but deposition of fluviatile and eolian silts is well documented during the Chalcolithic (ca. 6,000 B.P.). The last depositional event is the accumulation of 3–4 m of fluviatile silts containing Byzantine artifacts and radiocarbon dated between ca. 1750–600 B.P.). Whereas most of the sequences can be explained in climatic terms, the Byzantine or “Historical Fill” may have an anthropogenic origin.     

Contact metamorphic P–T–t paths from Sm–Nd garnet ages, phase equilibria modelling and thermobarometry: Garnet Ledge, south-eastern Alaska, USA

Sm–Nd garnet‐whole rock geochronology, phase equilibria, and thermobarometry results from Garnet Ledge, south‐eastern Alaska, provide the first precisely constrained P–T–t path for garnet zone contact metamorphism. Garnet cores from two crystals and associated whole rocks yield a four point isochron age for initial garnet growth of 89.9 ± 3.6 Ma. Garnet rims and matrix minerals from the same samples yield a five point isochron age for final garnet growth of 89 ± 1 Ma. Six size fractions of zircon from the adjacent pluton yield a concordant U–Pb age of 91.6 ± 0.5 Ma. The garnet core and rim, and zircon ages are compatible with single‐stage garnet growth during and/or after pluton emplacement. All garnet core–whole rock and garnet rim‐matrix data from the two samples constrain garnet growth duration to ≤5.5 my. A garnet mid‐point and the associated matrix from one of the two garnet crystals yield an age of 90.0 ± 1.0 Ma. This mid‐point result is logically younger than the 90.7 ± 5.6 Ma core–whole rock age and older than the 88.4 ± 2.5 Ma rim‐matrix age for this sample. A MnNaCaKFMASH phase diagram (P–T pseudosection) and the garnet core composition are used to predict that cores of garnet crystals grew at 610 ± 20 °C and 5 ± 1 kbar. This exceeds the temperature of the garnet‐in reaction by c. 50 °C and is compatible with overstepping of the garnet growth reaction during contact metamorphism. Intersection of three reactions involving garnet‐biotite‐sillimanite‐plagioclase‐quartz calculated by THERMOCALC in average P–T mode, and exchange thermobarometry were used to estimate peak metamorphic conditions of 678 ± 58 °C at 6.1 ± 0.9 kbar and 685 ± 50 °C at 6.3 ± 1 kbar, respectively. Integration of pressure, temperature, and age estimates yields a pressure‐temperature‐time path compatible with near isobaric garnet growth over an interval of c. 70 °C and c. 2.3 my.     

Solar abundance determination from ultraviolet emission lines

The intensities of far ultraviolet emission lines from the solar corona are analyzed to determine relative coronal abundances for oxygen, silicon, and iron. Dielectronic recombination is included in the formulation of ionization equilibrium. Observations of solar radio emission are used to obtain abundances relative to hydrogen. The absolute coronal abundances appear to be in agreement with their respective photospheric values. General properties of the structure of the chromosphere and corona are deduced from the analysis of observed emission in the ultraviolet and radio wavelength regions.     

Studies of multiple stellar systems – IV. The triple-lined spectroscopic system Gliese 644

We present a radial velocity study of the triple-lined system Gliese 644 and derive spectroscopic elements for the inner and outer orbits with periods of 2.965 5 and 627 d. We also utilize old visual data, as well as modern speckle and adaptive optics observations, to derive a new astrometric solution for the outer orbit. These two orbits together allow us to derive masses for each of the three components in the system: M _A=0.410±0.028 (6.9 per cent), M _Ba=0.336±0.016 (4.7 per cent), and M _Bb=0.304±0.014 (4.7 per cent) M_⊙. We suggest that the relative inclination of the two orbits is very small. Our individual masses and spectroscopic light ratios for the three M stars in the Gliese 644 system provide three points for the mass–luminosity relation near the bottom of the main sequence, where the relation is poorly determined. These three points agree well with theoretical models for solar metallicity and an age of 5 Gyr. Our radial velocities for Gliese 643 and vB 8, two common proper motion companions of Gliese 644, support the interpretation that all five M stars are moving together in a physically bound group. We discuss possible scenarios for the formation and evolution of this configuration, such as the formation of all five stars in a sequence of fragmentation events leading directly to the hierarchical configuration now observed, versus formation in a small N cluster with subsequent dynamical evolution into the present hierarchical configuration.     

A pollution history of Chesapeake Bay

Present day anthropogenic fluxes of some heavy metals to central Chesapeake Bay appear to be intermediate to those of the southern California coastal region and those of Narragansett Bay. The natural fluxes, however, are in general higher. On the bases of Pb-210 and Pu-239 + 240 geochronologies and of the time changes in interstitial water compositions, there is a mixing of the upper 30 or so centimeters of the sediments in the mid-Chesapeake Bay area through bioturbation by burrowing mollusks and polychaetes. Coal, coke and charcoal levels reach one percent or more by dry weight in the deposits, primarily as a consequence of coal mining operations.