Assessing the ecological status of the North-western Adriatic Sea within the European Water Framework Directive: a comparison of Bentix, AMBI and M-AMBI methods

In this paper we looked for the most suitable method for benthic ecological quality status (EcoQS) assessment of the North-western Adriatic Sea. Taking into account the historical and present information, we inter-compared our expectations in terms of EcoQS, with the Bentix, AMBI and M-AMBI classification metrics results, and investigated the sensitivity of these indices to the spatial, seasonal and inter-annual variability of benthic communities. The sampling sites were located at increasing distances with respect to the Po River mouth, along an (inverse) gradient of eutrophication. Moreover, a 2-year monthly monitoring plan (October 2004–September 2006) was carried out at the CEBEB site, located in a central position with respect to the investigated area. The results highlighted that the three indices differed in the sensitivity to spatial and temporal variability of the benthic communities. The strong seasonal and inter-annual changes in the benthic communities had a significant effect on the Bentix, whereas no relevant modifications were observed on the EcoQS assignation obtained using the M-AMBI and AMBI methods. The environmental quality ratios (EQR) values and EcoQS classification obtained by the Bentix and AMBI did not match expectations, as they were not inversely correlated with the site distances with respect to the Po mouth, whereas the M-AMBI clearly discriminated the most and the least eutrophicated sites. It thus appears that the M-AMBI could be considered to be the most valuable method for the ecological-status assessment of the North-western Adriatic Sea benthic ecosystem.     

Malleable disc base for direct infiltration measurements using the tension infiltrometry technique

The correct use of the tension disc infiltrometer requires the membrane of the disc base to be completely in contact with the soil surface. To achieve this contact, a thick layer of sand is commonly placed between the soil surface and the disc base. This paper presents an alternative disc (M_DB), which, by incorporating a malleable membrane, allows direct infiltration measurements without using a contact sand layer. Infiltration curves obtained with this new design in a soil under three different tillage management treatments were compared with the corresponding curves obtained with a conventional disc (C_DB) that uses a contact sand layer. The cumulative infiltration curves measured with C_DB were analysed by the differentiated linearization (DL) method, and the corresponding curves obtained with M_DB were analysed using both the DL and the cumulative linearization (CL) models. The values of hydraulic conductivity (K₀) and sorptivity (S₀) estimated with C_DB were also compared with those obtained with M_DB. Finally, the cumulative infiltration curves measured with C_DB and M_DB were compared with the corresponding modelled function for the respective K₀ and S₀ values calculated with the CL and DL models. The results show that, compared with C_DB without a contact sand layer, M_DB allows complete soil surface wetting even when non‐smoothed soil surfaces are used. The C_DB, which yielded average K₀ values 18% lower than those estimated with M_DB, gave the highest values of standard error for the hydraulic parameters calculated. Furthermore, the subjective method employed in the C_DB‐DL technique, which requires the first points of the differential infiltration line corresponding to the sand layer to be manually removed, introduces additional uncertainties in estimating S₀ and K₀. Comparison between the modelled and measured infiltration curves demonstrates that the DL or CL methods applied to M_DB gave excellent estimates of S₀ and K₀. Copyright © 2012 John Wiley & Sons, Ltd.     

Hydrological response of a humid agroforestry catchment at different time scales

Using data collected at the Mero catchment during three hydrological years (2005/06–2007/08), an analysis of rainfall–runoff relationships was performed at annual, seasonal, monthly, and event scales. At annual scale, the catchment showed low runoff coefficients (23–35%), due to high water storage capacity soils as well as high runoff inter‐annual variability. Rainfall variability was the main responsible for the differences in the inter‐annual runoff. At seasonal and monthly scales, there was no simple relationship between rainfall and runoff. Seasonal dynamics of rainfall and potential evapotranspiration in conjunction with different rainfall distribution during the study years could be the key factors explaining the complex relationship between rainfall and runoff at monthly and seasonal scale. At the event scale, the results revealed that the hydrological response was highly dependent on initial conditions and, to a lesser extent, on rainfall amount. The shapes of the different hydrographs, regardless of the magnitude, presented similar characteristics: a moderate rise and a prolonged recession, suggesting that subsurface flow was the dominant process in direct runoff. Moreover, all rainfall–runoff events had a higher proportion of baseflow than of direct runoff. A cluster‐type analysis discriminated three types of events differentiated mainly by rainfall amount and antecedent rainfall conditions. The study highlights the role of the antecedent rainfall and the need for caution in extrapolating relationships between rainfall amount and hydrological response of the catchment. Copyright © 2013 John Wiley & Sons, Ltd.     

Relating nitrogen export patterns from a mixed land use catchment in NW Spain with rainfall and streamflow

The temporal variability in nitrogen (N) transport in the Corbeira agroforestry catchment (NW Spain) was analysed from October 2004 to September 2008. Nitrate (NO₃–N) and total Kjeldahl nitrogen (TKN) loads and concentrations were determined at various timescales (annual, seasonal and event). The results revealed a strong intra‐annual and inter‐annual variability in N transport influenced by weather patterns and consequently by the hydrological regime. Mean annual export of total N in the catchment was 5.5 kg ha^?1 year^?1, with NO₃–N being the dominant form. Runoff events comprised 10% of the study period but contributed 40 and 61% of the total NO₃–N and TKN loads, respectively. The NO₃–N and TKN concentrations were higher during runoff events than under baseflow conditions, pointing to diffuse sources of N. The mobilization of TKN during runoff events was attributed to surface runoff, while NO₃–N might be related to subsurface and groundwater flow. Runoff events were characterized by high variability in N loads and concentrations. Higher variability was observed in N loads than in N concentrations, indicating that event magnitude plays an important role in N transport in this catchment; event magnitude explained approximately 96% of the NO₃–N load. However, a combination of variables related to runoff event intensity (rainfall, discharge increase and kinetic energy) explained only 66% of the TKN load. Copyright © 2014 John Wiley & Sons, Ltd.     

A new probabilistic seismic hazard study of Spain

In this paper, we present a probabilistic seismic hazard analysis (PSHA) for mainland Spain that takes into account recent new results in seismicity, seismic zoning, and strong ground attenuation not considered in the latest PSHA of the Spanish Building Code. Those new input data have been obtained as a three-step project carried out in order to improve the existing hazard map for mainland Spain. We have produced a new earthquake catalogue for the area, in which the earthquakes are given in moment magnitude through specific deduced relationships for our territory based on intensity data (Mezcua et al. in Seismol Res Lett 75:75–81, 2004). In addition, we included a new seismogenetic zoning based on the recent partial zoning studies performed by different authors. Finally, as we have developed a new strong ground motion model for the area García Blanco (2009), it was considered in the hazard calculation together with other attenuations gathered from different authors using data compatible with our region. With this new data, a logic tree process is defined to quantify the epistemic uncertainty related to those parts of the process. A sensitivity test has been included in order to analyze the different models of ground motion and seismotectonic zonation used in this work. Finally, after applying a weighting scheme, a mean hazard map for PGA, based on rock type condition for 10% exceedance probability in 50 years, is presented, including 15th and 85th percentile hazard maps. The main differences with the present official building code hazard map are analyzed.     

Chemical and physical characterization of iron-intercalated vermiculite compounds

Herein we report on synthetic iron-intercalated vermiculites prepared from a Mg-vermiculite mineral from Santa Olalla, Huelva, Spain, by means of an ion exchange process from aqueous solutions of FeCl₂ and FeCl₃. Thermogravimetric, X-ray diffraction, magnetic susceptibility and Mössbauer spectral studies have been used to characterize the synthetic iron-intercalated vermiculites. The results suggest that the intercalation process employed induces modifications in both the interlayer spacing and in the octahedral sheet; the disordered structure of the Mg-vermiculite mineral is not altered. The presence of solvated Fe(H₂O) _n ²⁺ ions has been shown by the Mössbauer spectroscopy. No magnetic order has been observed between 2 and 300 K neither in the Mg-vermiculite mineral nor in the two synthetic iron-intercalated vermiculites.     

Bloom of the Yessotoxin producing dinoflagellate Protoceratium reticulatum (Dinophyceae) in Northern Chile

Potential spawning habitat is defined as the area where environmental conditions are suitable for spawning to occur. Spawning adult data from the first quarter (January–March) of the International Bottom Trawl Survey have been used to study the inter-annual variability of the potential spawning habitat of North Sea plaice from 1980 to 2007. Generalised additive models (GAM) were used to create a model that related five environmental variables (depth, bottom temperature and salinity, seabed stress and sediment type) to presence–absence and abundance of spawning adults. Then, the habitat model was applied each year from 1970 to 2007 to predict inter-annual variability of the potential spawning habitat. Predicted responses obtained by GAM for each year were mapped using kriging. A hierarchical classification associated with a correspondence analysis was performed to cluster spawning suitable areas and to determine how they evolved across years. The potential spawning habitat was consistent with historical spawning ground locations described in the literature from eggs surveys. It was also found that the potential spawning habitat varied across years. Suitable areas were located in the southern part of the North Sea and along the eastern coast of England and Scotland in the eighties; they expanded further north from the nineties. Annual survey distributions did not show such northward expansion and remained located in the southern North Sea. This suggests that this species' actual spatial distribution remains stable against changing environmental conditions, and that the potential spawning habitat is not fully occupied. Changes in environmental conditions appear to remain within plaice environmental ranges, meaning that other factors may control the spatial distribution of plaice spawning habitat.     

Microencapsulation of okadaic acid as a tool for studying the accumulation of DSP toxins in mussels

The possibility and effectiveness of microencapsulation of okadaic acid (OA) in gelatin-acacia microcapsules has been studied. The encapsulation efficiency was higher than 33%. The microcapsules were shown to be very stable, not leaching more than 9% of the encapsulated OA in a 20-h period. OA from the microcapsules was absorbed by the mussels very efficiently, accumulating--after 3 days of feeding and one of depuration--65% of the OA in microcapsules and 22% of the total OA used at the beginning of the microencapsulation process. These efficiencies and the possibility of encapsulating single DSP toxins and derivatives constitute a valuable tool for the study of the accumulation and biotransformation of DSP toxins in bivalves.     

Extreme surface and near-bottom currents in the northwest Atlantic

This study presents a methodology for estimating extreme current speeds from numerical model results using extremal analysis techniques. This method is used to estimate the extreme near-surface and near-bottom current speeds of the northwest Atlantic Ocean with 50-year return periods from 17?years of model output. The non-tidal currents produced by a three-dimensional ocean circulation model for the 1988?C2004 period were first used to estimate and map the 17-year return period extreme current speeds at the surface and near the bottom. Extremal analysis techniques (i.e., fitting the annual maxima to the Type I probability distribution) are used to estimate and map the 50-year extreme current speeds. Tidal currents are dominant in some parts of the northwest Atlantic, and a Monte Carlo-based methodology is developed to take into account the fact that large non-tidal extrema may occur at different tidal phases. The inclusion of tidal currents in this way modifies the estimated 50-year extreme current speeds, and this is illustrated along several representative transects and depth profiles. Seasonal variations are examined by calculating the extreme current speeds for fall-winter and spring?Csummer. Finally, the distribution of extreme currents is interpreted taking into account (1) variability about the time-mean current speeds, (2) wind-driven Ekman currents, and (3) flow along isobaths.