Surface wave surveys for seismic site characterization of accelerometric stations in ITACA

This paper reports on site characterization for a set of accelerometric stations of the RAN (Italian accelerometric network) with specific attention to the shear wave velocity profile. The latter is indeed of primary importance for the usability of the accelerometric database. Surface wave analysis has been chosen as the primary investigation method since it offers the possibility of reaching the required accuracy with reasonable costs. A range of different techniques, both of the active-source and passive-source types, has been adopted to cope with the objectives of the characterization in relation to specific geological settings. Quality assessment of experimental data has been implemented to check the consistency of the measurements also with respect to the fundamental hypotheses of the method. Strategies to improve the reliability and robustness of the surface wave data inversion were exploited in order to mitigate problems arising from solution non-uniqueness and influence of higher modes in the propagation. Comparisons with independent borehole tests, available at some specific sites, confirm the reliability of the results. Although the research program covered only a subset of the network, the obtained results show the importance of specific experimental investigations aimed at estimating the shear wave velocity profile. Indeed the results lead to a re-classification of several sites with respect to the preliminary classification based on surface geology. Within this context, four selected case histories are reported in the present paper.     

The role of alternating outcrops of sediments and basaltic lavas on seismic urban scenario: the study case of Catania, Italy

Experimental data and numerical modelling were used to study the effect of local geology on the seismic response of the Catania area. The town extends on a marly clays bedrock and terraced deposits made up by coastal sands and alluvial conglomerates. This sedimentary substratum is deeply entrenched by paleo-valleys filled by lava flows and pyroclastics. Available borehole data and elastic parameters were used to reconstruct a geotechnical model in order to perfome 1D numerical modeling. Seismic urban scenarios were simulated considering destructive (M _w = 7.0), strong (M _w = 6.2) and moderate (M _w = 5.7) earthquakes to assess the shaking level of the different outcropping formations. For each scenario seven real accelerograms were selected from the European Strong Motion Database to assess the expected seismic input at the bedrock. PGA and spectral acceleration at different periods were obtained in the urban area through the equivalent linear numerical code EERA, and contour maps of different levels of shaking were drawn. Standard and horizontal-to-vertical spectral ratios were achieved making use of a dataset of 172 seismic events recorded at ten sites located on the main outcropping lithotypes. Spectral ratios inferred from earthquake data were compared with theoretical transfer functions. Both experimental and numerical results confirm the role of the geological and morphologic setting of Catania. Amplification of seismic motion mainly occurs in three different stratigraphic conditions: (a) sedimentary deposits mainly diffused in the south of the study area; (b) spots of soft sediments surrounded by lava flows; (c) intensely fractured and scoriaceous basaltic lavas.     

Local variability of the ground shaking during the 2009 L��Aquila earthquake (April 6, 2009��Mw 6.3): the case study of Onna and Monticchio villages

The 2009 Mw 6.3 L’Aquila event caused extensive damage in the city of L’Aquila and in some small towns in its vicinity. The most severe damage was recognized SE of L’Aquila town along the Aterno river valley. Although building vulnerability and near-source effects are strongly responsible for the high level of destruction, site effects have been invoked to explain the damage heterogeneities and the similarities between the 2009 macroseismic field with the intensities of historical earthquakes. The small village of Onna is settled on quaternary alluvium and suffered during the L’Aquila event an extremely heavy damage in the masonry structures with intensity IX–X on the Mercalli-Cancani-Sieberg (MCS) scale. The village of Monticchio, far less than 1.3 km from Onna, is mostly situated on Mesozoic limestone and suffered a smaller level of damaging (VI MCS). In the present paper, we analyze the aftershock recordings at seismic stations deployed in a small area of the middle-Aterno valley including Onna and Monticchio. The aim is to investigate local amplification effects caused by the near-surface geology. Because the seismological stations are close together, vulnerability and near-source effects are assumed to be constant. The waveform analysis shows that the ground motion at Onna is systematically characterized by large high-frequency content. The frequency resonance is varying from 2 to 3 Hz and it is related to alluvial sediments with a thickness of about 40 m that overlay a stiffer Pleistocene substrate. The ground motion recordings of Onna are well reproduced by the predictive equation for the Italian territory.     

Do small marinas drive habitat specific impacts? A case study from Mediterranean Sea

Many human activities add new structures to the marine landscape. Despite the fact that human structures cause some inevitable impacts, surprisingly little information exists on the effects of marina on natural marine assemblages. The aim of this paper is to assess habitat-specific response of benthic sessile organisms of rocky shores in relation to the presence of a small marina. Sampling was carried out at three coastal habitats (midshore, lowshore and subtidal) by means of visual censuses adopting an after-control-impact (ACI) experimental design. It appears that the marina affects the structure and composition of benthic communities of both the midshore and the lowshore. Little effect was evident on shallow subtidal assemblage structure. The results of the present study clearly show habitat-specific responses of coastal benthic assemblages to the presence of infrastructure.     

Recent innovations in hazard and risk analysis

Air pollution has been a major transboundary problem and a matter of global concern for decades. Climate change and air pollution are closely coupled. Just as air pollution can have adverse effects on human health and ecosystems, it can also impact the earth’s climate. As we enter an era of rapid climate change, the implications for air quality need to be better understood, both for the purpose of air quality management and as one of the societal consequences of climate change. In this study, an attempt has been made to estimate the current air quality to forecast the air quality index of an urban station Kolkata (22.65°N, 88.45°E), India for the next 5 years with neural network models. The annual and seasonal variability in the air quality indicates that the winter season is mostly affected by the pollutants. Air quality index (AQI) is estimated as a geometric mean of the pollutants considered. Different neural network models are attempted to select the best model to forecast the AQI of Kolkata. The meteorological parameters and AQI of the previous day are utilized to train the models to forecast the AQI of the next day during the period from 2003 to 2012. The selection of the best model is made after validation with observation from 2013 to 2015. The radial basis functional (RBF) model is found to be the best network model for the purpose. The RBF model with various architectures is tried to obtain precise forecast with minimum error. RBF of 5:5-91-1:1 structure is found to be the best fit for forecasting the AQI of Kolkata.     

The genesis of the amethyst geodes at Artigas (Uruguay) and the paleohydrology of the Guaraní aquifer: structural, geochemical, oxygen, carbon, strontium isotope and fluid inclusion study

The amethyst-bearing geodes found in the flood basalts of the Arapey formation at Artigas (Uruguay) were formed as protogeodes by bubbles of CO₂-rich basalt-derived fluids. The formation of the celadonite rim and the lining of the geodes by agate followed by quartz and amethyst were driven by the artesian water of the Guaraní aquifer percolating the basalts from below. The temperature of the amethyst formation is estimated from fluid inclusion data to be between 50° and 120°C. Oxygen stable isotope data suggest a crystallization temperature of calcite of about only 24°C. The actual wellhead temperature of the water produced from the Guaraní aquifer in the study area is around 29°C.     

Cooling in rifting sequences during increasing burial depth due to heat flow decrease

Two case histories are presented to give evidences for sediment cooling during increasing burial depth due to heat flow decrease at the end of crustal stretching in extensional settings. The first refers to the Lower Cretaceous succession accumulated in a strongly subsiding trough within the Sirt Basin (Libya); the second relates to the Mesozoic succession of the Lombardian Basin (NW Italy) formed during Late Triassic–Early Jurassic rifting of the northern margin of the Adriatic microplate. In both cases, heat flow decreasing at the end of crustal stretching overbalanced the thermal effect of increasing burial depth causing a net cooling of rocks. These examples provide an alternative to exhumation for explaining cooling events recorded by rifting sedimentary sequences.     

NADPH: Phenanthrenequinone oxidoreductase in channel catfish (Ictalurus punctatus)

The toxicity of certain polycyclic aromatic hydrocarbons has been related to the phenomenon of oxidative stress. Recent studies in our laboratory have demonstrated that 9,10-phenanthrenequinone (PQ) is an efficient redox cycling agent in cytosols of several organs of the channel catfish (Ictalurus punctatus). Stomach cytosol demonstrated a high level of dicoumarol-sensitive PQ reduction which was at least tenfold greater than that seen in kidney, liver or gill. In the presence of stomach cytosol, PQ stimulated production of Superoxide union in-vitro at rates several fold higher than did menadione, a model redox active quinone. The active component from stomach cytosol has been purified, and is termed NADPH: phenanthrenequinone oxidoreductase, which the authors believe represents a novel quinone-reducing enzyme in this species.     

The evolution of the Western Ligurian Flysch Units and the role of mud diapirism in ancient accretionary prisms (Maritime Alps,Northwestern Italy)

The Western Ligurian Flysch Units represent an Upper Cretaceous to Paleogene accretionary prism overthrust onto the paleo-European continental margin during the collisional stages of the Alpine orogeny (Eocene). Their precollisional evolution has been reconsidered according to the data collected through extensive field mapping, the study of lowgrade metamorphism and by considering more strictly the processes documented in modern convergent zones.The proposed model involves chaotic facies produced by the flow of muddy sediments along decollement surfaces (diapiric melange) with the growth of mud volcanoes into an accreting wedge progressively shifting toward the European continental margin.

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Zusammenfassung Der westliche Ligurische Flysch repräsentiert die Entwicklung eines Akkretionskeiles während des Kreide-Paleogens, das auf den europäischen Kontinentalrand während der Kollisionsphase der alpidischen Orogenese (Eozän) überschoben wurde. Die Entwicklung vor der Kollision wird neu gedeutet auf der Basis ausgedehnter geologischer Felduntersuchungen, dem Studium der niedrig gradigen Metamorphose und anhand von Vergleichen mit heutigen konvergenten Zonen.Das vorgeschlagene Modell interpretiert das Erscheinen der chaotischen Fazies als Diapirismus von nur teilweise verfestigten Sedimenten und deren Umlagerung nahe Diskontinuitätsflächen im Inneren eines Akkretionprismas, das in Richtung des europäischen Kontinents wandert.

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Résumé Les flyschs de la Ligurie occidentale représentent un prisme d'accrétion du Crétacé-Paléogène charrié sur la marge continentale européenne pendant les phases de collision de l'orogenèse alpine (Eocène). Leur évolution anté-collision est reconsidérée sur la base de nouvelles données provenant du levé de terrain d'une vaste région, de l'étude du métamorphisme de degré faible et de l'application plus rigoureuse des enseignements fournis par les zones de convergence actuelles.Le modèle proposé envisage la production de facies à texture chaotique par flux diapirique de sédiments non consolidés le long de surfaces de décollement, à l'intérieur d'un prisme d'accrétion qui migre progressivement vers la marge continentale européenne.

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