A sulfur isotope study on pyrite deposits of Southern Tuscany,Italy

The S-isotope composition (δ³⁴S_CDT) of 213 samples of sulfides, sulfates and native sulfur from the pyrite mineralizations of southern Tuscany and associated country rocks were determined. The sulfur isotopic composition of pyrite is quite homogeneous and similar for all studied ore bodies, with an average δ³⁴S value near +9,5‰. Pyrite disseminated within the Filladi di Boccheggiano formation, and thought to be authigenic, shows a much larger range of δ³⁴S values (-13.1 to +14.5‰). The isotopic compositions of other sulfides associated with pyrite in the deposits show that isotopic equilibrium among sulfides was approached on a regional scale, but seldom fully attained. Isotopic data suggest that sedimentary marine sulfate was the ultimate source of sulfur in ores. Sulfates (mostly anhydrite) from the sulfate-carbonate lenses associated with both the Filladi di Boccheggiano and the Calcare Cavernoso formations also have similar and homogeneous compositions (average δ³⁴S=+15–16‰). Coexisting sulfates and sulfides are not in isotopic equilibrium. In the light of the isotopic data, among the many proposed genetic models for the largest stratabound pyrite bodies the two following alternatives appear the most likely: 1) in agreement with recently suggested hypotheses, the ore bodies are older than the emplacement of the Mio-Pliocenic granitoids in the area, and are probably hydrothermal-sedimentary in origin, coeval with associated country rocks; 2) the ore bodies were formed as a consequence of bacterial reduction of anhydrite in low-temperature convection systems related to the early stages of the Mio-Pliocenic thermal anomaly. In both cases, the emplacement of the Mio-Pliocenic granitoids caused metamorphism and remobilization of the pre-existing ores, producing smaller discordant mineralized bodies.     

Source parameters and stress release of seismic sequences occurred in the Friuli-Venezia Giulia region (Northeastern Italy) and in Western Slovenia

The source parameters of the major events of a swarm and of two seismic sequences, occurred in the Friuli area (Northeastern Italy) and in Western Slovenia, were estimated. The Claut swarm (C96) occurred since the end of January to June 1996, with a M_D 4.3 major shock and it appears composed of three sub-sequences. The two sequences are the Kobarid sequence (K98) started on April 12, 1998 with a M_D 5.6 mainshock and the M.te Sernio (S02) sequence caused by the February 14, 2002 earthquake (M_D = 4.9). Acceleration and velocity data recorded by the local seismic network of the Istituto Nazionale di Oceanografia e di Geofisica Sperimenale (OGS) and corrected for attenuation, were employed to estimate seismic moments and radiated energies. Source dimensions were inferred from the computed corner frequencies and the stress release was estimated from the Brune stress drop, the apparent stress and the RMS stress drop. On the whole, seismic moments range from 1.7 × 10¹² to 1.1 × 10¹⁷ N m, and radiated energies are in the range 10⁶–10¹³ J. Brune stress drops are scattered and do not show any evidence of a self-similarity breakdown for sources down to 130 m radius. The radiated seismic energy scales as a function of seismic moment, with a slope of the scaling relation that decreases for increasing seismic moments.The mechanism of stress release was analyzed by computing the ɛ parameter of Zuniga [Zuniga, R., 1993. Frictional overshoot and partial stress drop. Which one? Bull. Seismol. Soc. Am. 83, 939–944]. The K98 and S02 sequences are characterized by a wide range of the ɛ parameter with stress drop mechanism varying from partial locking to overshoot cases. The ɛ values of the C96 swarm are more homogeneous and close to the Orowan's condition. The radiated seismic energy and the ratio of stress drop between mainshock and aftershocks appear different among the analyzed cases. We therefore investigated the relationship between the stress parameters of the main shock and the energy radiated by the aftershock sequences. For this purpose, we also estimated the source parameters of two other sequences occurred in the area, with mainshocks of M_D 4.1 and 5.1, respectively. We found a positive correlation between the Brune stress drop of the mainshock and the ratio between the radiated energy of the mainshock and the summation of the energies radiated by the aftershocks.     

Case study for investigating groundwater and the future of mountain spring discharges in Southern Italy

Groundwater extraction is used to alleviate drought in many habitats. However, widespread drought decreases spring discharge and there is a need to integrate climate change research into resource management and action. Accurate estimates of groundwater discharge may be valuable in improving decision support systems of hydrogeological resource exploitation. The present study performs a forecast for groundwater discharge in Aquifer?s Cervialto Mountains(southern Italy). A time series starting in 1883 was the basis for longterm predictions. An Ensemble Discharge Prediction(EDis P) was applied, and the progress of the discharge ensemble forecast was inferred with the aid of an Exponential Smoothing(ES) model initialized at different annual times. EDisP-ES hindcast model experiments were tested, and discharge plume-patterns forecast was assessed with horizon placed in the year 2044. A 46-year cycle pattern was identified by comparing simulations and observations, which is essential for the forecasting purpose. ED is P-ES performed an ensemble mean path for the coming decades that indicates a discharge regime within ± 1 standard deviation around the mean value of 4.1 m~3 s~(-1). These fluctuations are comparable with those observed in the period 1961-1980 and further back, with changepoints detectable around the years 2025 and 2035. Temporary drought conditions are expected after the year 2030.     

The role of structural inheritance in continental break-up and exhumation of Alpine Tethyan mantle(Canavese Zone,Western Alps)

The Canavese Zone(CZ)in the Western Alps represents the remnant of the distal passive margin of the Adria microplate,which was stretched and thinned during the Jurassic opening of the Alpine Tethys.Through detailed geological mapping,stratigraphic and structural analyses,we document that the continental break-up of Pangea and tectonic dismemberment of the Adria distal margin,up to mantle rocks exhumation and oceanization,did not simply result from the syn-rift Jurassic extension but was strongly favored by older structu ral inheritances(the Proto-Canavese Shear Zone),which controlled earlier lithospheric weakness.Our findings allowed to redefine in detail(i)the tectono-stratigraphic setting of the Variscan metamorphic basement and the Late Carbonife rous to Early Cretaceous CZ succession,(ii)the role played by inherited Late Carboniferous to Early Triassic structures and(iii)the significance of the CZ in the geodynamic evolution of the Alpine Tethys.The large amount of extensional displacement and crustal thinning occurred during different pulses of Late Carbonife rous-Early Triassic strike-slip tectonics is wellconsistent with the role played by long-lived regional-scale wrench faults(e.g.,the East-Variscan Shear Zone),suggesting a re-discussion of models of mantle exhumation driven by low-angle detachment faults as unique efficient mechanism in stretching and thinning continental crust.     

Revised seismotectonic model of NE Italy and W Slovenia based on focal mechanism inversion

The study is focusing on the stress and strain inversions from focal mechanisms in a revised seismotectonic zonation of northeastern Italy and western Slovenia. The recent increase of monitoring capability of the local seismic network, the updated geological-structural model of the area, and the novelties emerged from studies on the spatial organization of the seismicity allowed a redefinition of the seismotectonic zones. The stress and strain tensors inversion is inferred from 203 focal mechanisms, corresponding to earthquakes occurred between 1984 and 2016 with coda-duration magnitude range from 2.0 to 5.6. The inverted stress domains reveal an articulated picture of the interaction of the Adria microplate with the Eurasian plate. A dominant strike-slip stress field characterizes the eastern part of the area, while the seismotectonic zones of the central part are undergoing to thrusting regime. The stress pattern inferred in the western part of the study area outlines a complex picture with prevailing strike-slip regime and dominant compression only in a seismotectonic zone. The comparison of stress and strain tensor orientations evidences a relative uniformity of the crustal strength in the eastern and northwestern zones of the study area. The central and western zones appear to be characterized by planes of mechanical weakness not favorably oriented for failure with respect to the stress tensor.     

Fragility functions and floor spectra of RC masonry infilled frames: influence of mechanical properties of masonry infills

A wide number of experimental studies conducted in latest years pointed out the high influence of the mechanical properties of masonry units and mortar bed joints on lateral strength and stiffness of masonry panels. This feature significantly modifies the global response of infilled frames under seismic actions as well as the local interaction phenomena. Despite a wide investigation on the influence of the infills on global behaviour of reinforced concrete (RC) frames has already been provided, different features characterizing the seismic performances of buildings suggest the need of accurately evaluating local interaction phenomena as well as the influence of the panel on specific and relevant aspects, as the accelerations transferred to non-structural components. This study provides a parametrical analysis of the influence of shear strength and elastic modulus of masonry infills on the seismic behaviour of RC frames originally designed for gravity loads. Regular buildings with different height were analysed using the Incremental Dynamic Analysis in order to provide fragility curves, investigate on the collapse mechanisms and define the floor spectra depending on the properties of the infills. Results obtained pointed out the high influence of the considered parameters on the fragility of existing RC frames, often characterized by inadequate transversal reinforcement of columns, which may lead to brittle failure due to the interaction with the infills. Floor response spectra are also significantly affected by the influence of masonry infills both in terms of shape and maximum spectral accelerations. Lastly, on the basis of the observed failure mechanisms, a parameter defining the ductility of the frames depending on the properties of the infills was also provided (Capacity Design Factor). The correlation between the mechanical properties of the infills and this parameter suggests its reliability in the simplified vulnerability analysis of existing buildings as well as for the design of new buildings.     

Conceptualization and Calibration of Anisotropic Alluvial Systems: Pitfalls and Biases

Physical properties of alluvial environments typically feature a high degree of anisotropy and are characterized by dynamic interactions between the surface and the subsurface. Hydrogeological models are often calibrated under the assumptions of isotropic hydraulic conductivity fields and steady-state conditions. We aim at understanding how these simplifications affect predictions of the water table using physically based models and advanced calibration and uncertainty analysis approaches based on singular value decomposition and Bayesian analysis. Specifically, we present an analysis of the information content provided by steady-state hydraulic data compared to transient data with respect to the estimation of aquifer and riverbed hydraulic properties. We show that assuming isotropy or fixed anisotropy may generate biases both in the estimation of aquifer and riverbed parameters as well as in the predictive uncertainty of the water table. We further demonstrate that the information content provided by steady-state hydraulic heads is insufficient to jointly estimate the aquifer anisotropy together with the aquifer and riverbed hydraulic conductivities and that transient data can help to reduce the predictive uncertainty to a greater extent. The outcomes of the synthetic analysis are applied to the calibration of a dynamic and anisotropic alluvial aquifer in Switzerland (The Rhône River). The results of the synthetic and real world modeling and calibration exercises documented herein provide insight on future data acquisition as well as modeling and calibration strategies for these environments. They also provide an incentive for evaluation and estimation of commonly made simplifying assumptions in order to prevent underestimation of the predictive uncertainty.     

Complexity‐reduction modelling for assessing the macro‐scale patterns of historical soil moisture in the Euro‐Mediterranean region

Complexity‐reduction modelling can be useful for increasing the understanding of how the climate affects basin soil moisture response upon historical times not covered by detailed hydrological data. For this purpose, here is presented and assessed an empirical regression‐based model, the European Soil Moisture Empirical Downscaling (ESMED), in which different climatic variables, easily available on the web, are addressed for simplifying the inherent complexity in the long‐time studies. To accommodate this simplification, the Palmer Drought Severity Index, the precipitation, the elevation and the geographical location were used as input data in the ESMED model for predicting annual soil moisture budget. The test area was a large region including central Europe and Mediterranean countries, and the spatial resolution was initially set at 50 km. ESMED model calibration was made according to the soil moisture values retrieved from the Terrestrial Water Budget Data archive by selecting randomly 285 grid points (out of 2606). Once parameterized, ESMED model was performed at validation stage both spatially and temporally. The spatial validation was made for the grid points not selected in the calibration stage while the comparison with the soil moisture outputs of the Global Land Data Assimilation System–NOAH10 simulations upon the period 1950–2010 was carried out for the temporal validation. Moreover, ESMED results were found to be in good agreement with a root‐zone soil moisture product obtained from active and passive microwave sensors from various satellite missions. ESMED model was thus found to be reliable for both the temporal and spatial validations and, hence, it might represent a useful tool to characterize the long‐term dynamics of soil moisture–weather interaction. Copyright © 2013 John Wiley & Sons, Ltd.     

Tectonic significance of different block-in-matrix structures in exhumed convergent plate margins: examples from oceanic and continental HP rocks in Inner Western Alps (northwest Italy)

In the Inner Western Alps, three different types of block-in-matrix structures (BIMs) formed sequentially through time at a convergent plate margin. These show the superposition of progressive deformation from (i) subduction to eclogite-facies depths, (ii) collision, accretion, and exhumation of oceanic crust, represented by the Monviso Meta-ophiolite Complex, to (iii) collision, accretion, and exhumation of the continental Dora Maira units. The Type 1 occurs in the metasedimentary cover of the Dora Maira Unit and consists of a map-scale broken formation with boudinaged ‘native’ blocks of marble (Early Jurassic) in a calcschist matrix. It results from the tectonic overprinting of exhumation-related folding (D2-stage) on an earlier subduction-related dismembered succession (D1-stage). Type 1 also includes ‘non-mappable’ BIMs with ‘exotic’ blocks, resulting from the gravitational collapse of the Triassic carbonate platform of European Continental Margin, triggered by the Early Jurassic rifting. In the Monviso Meta-ophiolite Complex, Types 2 and 3 represent tectonically induced broken and dismembered formations, respectively. They differ from each other in the degree of stratal disruption of primary interbedded horizons of mafic metabreccia (Type 3) and mafic metasandstone (Types 2 and 3) sourced by the Late Jurassic–Early Cretaceous denudation of an oceanic core complex. Dismembered interbeds (Type 2) and isolated blocks were mixed together (Type 3) by the overlap of D2 tectonics and late- to post-exhumation extensional shearing (D3-stage). Development of these types of BIMs may be common in many exhumed convergent plate margins, where severe tectonics and metamorphic recrystallization under high-pressure conditions normally prevent the reconstruction of BIMs or mélange-forming processes. Our findings show that documenting the mode and time of the processes forming BIMs is highly relevant in order to reconstruct the oceanic seafloor morphology and composition of associated stratigraphic successions, and their control in the evolution of those convergent plate margins.     

How the aggressiveness of rainfalls in the Mediterranean lands is enhanced by climate change

Rainfall and overland flow are fundamental processes for Earth’s ecosystems but can also be land disturbing forces, particularly when triggered by extreme hydro-meteorological events. Examples of these extremes are rainstorms and related phenomena due to rainfall aggressiveness. They produce high-impact land processes such as soil erosion and nutrient losses. Economic and social consequences of these processes can be quite severe. However, hydrological extremes and their environmental implications are still poorly understood, particularly if analyzed in the context of climate change. Here, we analyze a 300 year long times series of historical rainfall patterns across the Mediterranean in the last three centuries and we investigate changes in the erosive forcing as related to climate changes. Our results show that the erosive forcing increased towards the end of the Little Ice Age (~1850) over western and central Mediterranean and that has been increasing in the recent warming period at low Mediterranean latitudes, due to a higher frequency of intensive storms. Such increased concentrated precipitation may lead to an intensification of land degradation processes triggered by soil erosion and transport across a range of scales from hillslopes to small catchments.